Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies

Computed CH Acidity of Biaryl Compounds and Their Deprotonative Metalation by Using a Mixed Lithium/Zinc-TMP Base

(2013) Raghu Ram Kadiyala et al.   CHEMISTRY-A EUROPEAN JOURNAL

ortho-Lithiations Reassessed: the Advantages of Deficiency Catalysis in Hydrocarbon Media

(2013) D. W. Slocum et al.   ORGANOMETALLICS

Amidocuprates for DirectedorthoCupration: Structural Study, Mechanistic Investigation, and Chemical Requirements

(2012) Shinsuke Komagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine

(2012) David M Hodgson et al.   Beilstein Journal of Organic Chemistry

What’s Going on with These Lithium Reagents?

(2012) Hans J. Reich   JOURNAL OF ORGANIC CHEMISTRY

Efficient synthesis of (R)-ochratoxin alpha, the key precursor to the mycotoxin ochratoxin A

(2012) Cesar Antonio Lenz et al.   TETRAHEDRON LETTERS

Divergent reaction pathways for phenol arylation by arynes: synthesis of helicenes and 2-arylphenols

(2012) Thanh Truong et al.   Chemical Science

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pure α-Metallated Benzyllithium from a Single-Crystal-to-Single-Crystal Transition

(2011) Tanja Tatic et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crossing Organolithium Compounds with Organolithium Compounds: Molecular Squares and a Cage-Encapsulating Reaction

(2011) Andrew A. Fyfe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

(2011) Sharon E. Baillie et al.   CHEMICAL COMMUNICATIONS

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethylpiperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Deprotonative Metalation of Chloro- and Bromopyridines Using Amido-Based Bimetallic Species and Regioselectivity-Computed CH Acidity Relationships

(2011) Katia Snégaroff et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bis-ortho-metalation/silylation of unprotected o-phthalic acids. Straightforward access to new silylated N-hydroxyphthalimide (NHPI) analogs

(2011) Jérôme Michaux et al.   TETRAHEDRON LETTERS

Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities

(2010) David R. Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The first asymmetric organolithium tetramers with simple ether donor bases

(2010) Tanja Tatic et al.   CHEMICAL COMMUNICATIONS

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC–H vs.Si–O bond cleavage

(2009) Eva Hevia et al.   CHEMICAL COMMUNICATIONS

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)

(2008) Deyu Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Structural and Computational Study of Synthetically Important Alkali-Metal/Tetramethylpiperidide (TMP) Amine Solvates

(2008) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Optimization of Organolithium Reactions

(2008) Terry ‘Li’ Rathman et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Determining accurate molecular sizes in solution through NMR diffusion spectroscopy

(2007) Alceo Macchioni et al.   CHEMICAL SOCIETY REVIEWS

Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP−Zn−ate):  New Approaches to Multisubstituted Benzenes

(2007) Masanobu Uchiyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY