New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

(2011) Eva Hevia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification of a Higher-Order Organozincate Intermediate Involved in Negishi Cross-Coupling Reactions by Mass Spectrometry and NMR Spectroscopy

(2011) Howard N. Hunter et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross coupling reactions

(2011) Victoria L. Blair et al.   TETRAHEDRON LETTERS

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

(2010) David R. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reaction of Arylzinc Reagents with N-Aromatic Heterocycles: A Straightforward Approach to C−H Bond Arylation of Electron-Deficient Heteroaromatic Compounds

(2009) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

(2009) A. R. Kennedy et al.   SCIENCE

Direct Zincation of Functionalized Aromatics and Heterocycles by Using a Magnesium Base in the Presence of ZnCl2

(2008) Zhibing Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Interpretation of the Reaction Pathway of Deprotonative Metalation with TMP−Zn-ate/TMEDA Complex [TMEDA·Na(μ-tBu)(μ-TMP)Zn(tBu)]

(2008) Daisuke Nobuto et al.   JOURNAL OF ORGANIC CHEMISTRY

Functionalization of diazines and benzo derivatives through deprotonated intermediates

(2007) Floris Chevallier et al.   CHEMICAL SOCIETY REVIEWS

Deprotonative Metalation of Five-Membered Aromatic Heterocycles Using Mixed Lithium−Zinc Species

(2007) Jean-Martial L'Helgoual'c et al.   JOURNAL OF ORGANIC CHEMISTRY