Titanium-Catalyzed Vinylic and Allylic CF Bond Activation-Scope, Limitations and Mechanistic Insight
Published 2012 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
Titanium-Catalyzed Vinylic and Allylic CF Bond Activation-Scope, Limitations and Mechanistic Insight
Authors
Keywords
-
Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 18, Issue 34, Pages 10701-10714
Publisher
Wiley
Online
2012-07-09
DOI
10.1002/chem.201201125
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- A New Approach towards the Asymmetric Fluorination of Alkenes Using Anionic Phase-Transfer Catalysts
- (2012) Ulrich Hennecke ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon-Fluorine Bond Activation
- (2012) Moritz F. Kuehnel et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Selective Continuous Flow Processes Using Fluorine Gas
- (2012) Christopher B. McPake et al. ORGANIC PROCESS RESEARCH & DEVELOPMENT
- Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C–F Bond Formation and Catalytic C–F Bond Activation Reactions
- (2012) David Breyer et al. ORGANOMETALLICS
- Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry
- (2012) Felicia L. Taw et al. ORGANOMETALLICS
- An Update on Recent Stoichiometric and Catalytic C–F Bond Cleavage Reactions by Lanthanide and Group 4 Transition-Metal Complexes
- (2012) Marcus Klahn et al. ORGANOMETALLICS
- Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]
- (2012) Peter Fischer et al. ORGANOMETALLICS
- Exploration of the Mechanism of Platinum(II)-Catalyzed C–F Activation: Characterization and Reactivity of Platinum(IV) Fluoroaryl Complexes Relevant to Catalysis
- (2012) Tongen Wang et al. ORGANOMETALLICS
- C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales
- (2011) Eric Clot et al. ACCOUNTS OF CHEMICAL RESEARCH
- Catalytic Hydrodefluorination of Pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: A Nucleophilic Attack by a Metal-Bound Hydride Ligand Explains an Unusual ortho-Regioselectivity
- (2011) Julien A. Panetier et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Nickel-Catalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride (Lithium Triethylborohydride)
- (2011) Jingjing Wu et al. ChemCatChem
- Transition metal catalysis and nucleophilic fluorination
- (2011) Charlotte Hollingworth et al. CHEMICAL COMMUNICATIONS
- Aromatic Trifluoromethylation with Metal Complexes
- (2011) Olesya A. Tomashenko et al. CHEMICAL REVIEWS
- C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis
- (2011) Thomas Braun et al. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Exploration of the Scope of Pt-Catalyzed C-F Activation
- (2011) Lauren Keyes et al. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Exhaustive Chlorination of [B12H12]2−without Chlorine Gas and the Use of [B12Cl12]2−as a Supporting Anion in Catalytic Hydrodefluorination of Aliphatic C−F Bonds
- (2011) Weixing Gu et al. INORGANIC CHEMISTRY
- Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds
- (2011) Masato Ohashi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Nickel-Catalyzed Suzuki–Miyaura Reaction of Aryl Fluorides
- (2011) Mamoru Tobisu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalysis for fluorination and trifluoromethylation
- (2011) Takeru Furuya et al. NATURE
- Nickel-Catalyzed Selective Defluorination to Generate Partially Fluorinated Biaryls
- (2011) Alex D. Sun et al. ORGANIC LETTERS
- Disilylfluoronium Ions—Synthesis, Structure, and Bonding
- (2011) Nicole Lühmann et al. ORGANOMETALLICS
- Breaking C–F Bonds via Nucleophilic Attack of Coordinated Ligands: Transformations from C–F to C–X Bonds (X= H, N, O, S)
- (2011) Ainara Nova et al. ORGANOMETALLICS
- Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations
- (2011) Christopher B. Caputo et al. ORGANOMETALLICS
- Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes
- (2011) O. Allemann et al. SCIENCE
- Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes
- (2011) Jean-François Paquin SYNLETT
- ZnCl2-catalyzed hydrodefluorination of gem-difluoromethylene derivatives with lithium aluminum hydride
- (2011) Jianhang Cheng et al. TETRAHEDRON LETTERS
- Ruthenium-catalyzed arylation of fluorinated aromatic ketones via ortho-selective carbon–fluorine bond cleavage
- (2011) Keisuke Kawamoto et al. TETRAHEDRON LETTERS
- Recent Advances in Catalytic Enantioselective Fluorination Reactions
- (2010) Sylvain Lectard et al. ADVANCED SYNTHESIS & CATALYSIS
- A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation
- (2010) Michael Teltewskoi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Titanium-Catalyzed C-F Activation of Fluoroalkenes
- (2010) Moritz F. Kühnel et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- CF Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity
- (2010) Simon Duttwyler et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A catalytic CC bond-forming reaction between aliphatic fluorohydrocarbons and arylsilanes
- (2010) Nicole Lühmann et al. APPLIED ORGANOMETALLIC CHEMISTRY
- Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and in C6H5Cl Solution
- (2010) Dmitry G. Gusev et al. CHEMISTRY-A EUROPEAN JOURNAL
- Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine
- (2010) David Breyer et al. DALTON TRANSACTIONS
- Cross coupling reactions of polyfluoroarenes via C–F activation
- (2010) Alex D. Sun et al. DALTON TRANSACTIONS
- Mechanistic investigation of vinylic carbon–fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF
- (2010) Bradley M. Kraft et al. JOURNAL OF FLUORINE CHEMISTRY
- Pt(II)Cl2(DMSO)2-catalyzed cross-coupling of polyfluoroaryl imines
- (2010) Alex D. Sun et al. JOURNAL OF FLUORINE CHEMISTRY
- Palladium-Catalyzed C−F Activation of Polyfluoronitrobenzene Derivatives in Suzuki−Miyaura Coupling Reactions
- (2010) Matthew R. Cargill et al. JOURNAL OF ORGANIC CHEMISTRY
- Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis
- (2010) Christos Douvris et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Highly regioselective nickel-catalyzed hydrodefluorination of pentafluoroacetanilide
- (2010) Sergey A. Prikhod’ko et al. MENDELEEV COMMUNICATIONS
- The first example of the ortho-directing effect of the weakly coordinating substituent [–BF3]– in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion
- (2010) Nicolay Yu. Adonin et al. MENDELEEV COMMUNICATIONS
- Mechanism of the Catalytic Hydrodefluorination of Pentafluoropyridine by Group Six Triangular Cluster Hydrides Containing Phosphines: A Combined Experimental and Theoretical Study
- (2010) Tomás F. Beltrán et al. ORGANOMETALLICS
- Amino- and hydrodefluorination of polyfluoroaromatic amines with aqueous ammonia in a steel autoclave. Synthesis of highly pure tetrafluorophenylenediamines
- (2010) S. Z. Kusov et al. RUSSIAN CHEMICAL BULLETIN
- Reaction of pentafluoroacetanilide with zinc catalyzed by nickel complexes
- (2010) S. A. Prikhod’ko et al. RUSSIAN CHEMICAL BULLETIN
- Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Unactivated Fluoro(hetero)arenes
- (2010) Lutz Ackermann et al. SYNLETT
- Carbon-Fluorine Bond Formation for the Synthesis of Aryl Fluorides
- (2010) Tobias Ritter et al. SYNTHESIS-STUTTGART
- The ionic liquid [bmim]Br as an alternative medium for the catalytic cleavage of aromatic C–F and C–Cl bonds
- (2010) Sergey A. Prikhod’ko et al. TETRAHEDRON LETTERS
- Niobium-Catalyzed Activation of Aryl Trifluoromethyl Groups and Functionalization of CH Bonds: An Efficient and Convergent Approach to the Synthesis of N-Heterocycles
- (2009) Tom G. Driver ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Expedient Synthesis of N-Fused Indoles: A CF Activation and CH Insertion Approach
- (2009) Kohei Fuchibe et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups
- (2009) Gregor Meier et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene
- (2009) Thomas Braun et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Activation of Allylic CF bonds: Palladium-Catalyzed Allylic Amination of 3,3-Difluoropropenes
- (2009) Xavier Pigeon et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Preparation of benzoyl fluoride from benzotrifluoride catalyzed by niobium oxide
- (2009) Joseph Zakzeski et al. APPLIED CATALYSIS A-GENERAL
- C−F Bond Activation in Organic Synthesis
- (2009) Hideki Amii et al. CHEMICAL REVIEWS
- Hydrometalation of fluoroallenes
- (2009) Moritz F. Kühnel et al. DALTON TRANSACTIONS
- Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds
- (2009) Russell P. Hughes EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation
- (2009) Naohiko Yoshikai et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes
- (2009) Steven P. Reade et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- C−F Bond-Cleavage Reactions of Fluoroalkanes with Magnesium Reagents and without Metal Catalysts
- (2009) Kouki Matsubara et al. ORGANIC LETTERS
- Phosphinorhodium-Catalyzed Dehalogenation of Chlorinated and Fluorinated Ethylenes: Distinct Mechanisms with Triethylsilane and Dihydrogen
- (2009) Alicia A. Peterson et al. ORGANOMETALLICS
- User-Friendly Precatalyst for the Methylation of Polyfluoroaryl Imines
- (2009) Heather L. Buckley et al. ORGANOMETALLICS
- A New Departure in Fluorination Chemistry
- (2009) V. Gouverneur SCIENCE
- Reduction of Alkyl Halides by Triethylsilane Based on a Cationic Iridium Bis(phosphinite) Pincer Catalyst: Scope, Selectivity and Mechanism
- (2008) Jian Yang et al. ADVANCED SYNTHESIS & CATALYSIS
- Methylation of arenes via Ni-catalyzed aryl C–O/F activation
- (2008) Bing-Tao Guan et al. CHEMICAL COMMUNICATIONS
- Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions
- (2008) Jun-An Ma et al. CHEMICAL REVIEWS
- CC Coupling Reactions of Superstrong CF3Groups with C(sp2)-H Bonds: Reactivity and Synthetic Utility of Zero-Valent Niobium Catalyst
- (2008) Kohei Fuchibe et al. Chemistry-An Asian Journal
- Preparation of the hydrocarbon-soluble trifluoro complex LTiF3 with a β-diketiminato ligand
- (2008) Grigory B. Nikiforov et al. JOURNAL OF FLUORINE CHEMISTRY
- Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides:p-Orientation in the Polyarylthiolation of Polyfluorobenzenes
- (2008) Mieko Arisawa et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations
- (2008) Thomas Schaub et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Insight into the Mechanism of Platinum-Catalyzed Cross-Coupling of Polyfluoroaryl Imines
- (2008) Tongen Wang et al. ORGANOMETALLICS
- Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts
- (2008) C. Douvris et al. SCIENCE
- Understanding organofluorine chemistry. An introduction to the C–F bond
- (2007) David O'Hagan CHEMICAL SOCIETY REVIEWS
Find the ideal target journal for your manuscript
Explore over 38,000 international journals covering a vast array of academic fields.
SearchAsk a Question. Answer a Question.
Quickly pose questions to the entire community. Debate answers and get clarity on the most important issues facing researchers.
Get Started