C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis

A catalytic CC bond-forming reaction between aliphatic fluorohydrocarbons and arylsilanes

(2010) Nicole Lühmann et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Metallophosphoranes: The hidden face of transition metal–phosphine complexes

(2010) Jenni Goodman et al.   COORDINATION CHEMISTRY REVIEWS

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine

(2010) David Breyer et al.   DALTON TRANSACTIONS

Fluorinated dienes in transition-metal chemistry – the rich chemistry of electron-poor ligands

(2010) Moritz F. Kühnel et al.   DALTON TRANSACTIONS

Cross coupling reactions of polyfluoroarenes via C–F activation

(2010) Alex D. Sun et al.   DALTON TRANSACTIONS

Imine-assisted C–F bond activation using low-valent cobalt compounds supported by trimethylphosphine ligands and formation of novel organic fluorides

(2010) Zhe Lian et al.   DALTON TRANSACTIONS

Fluorine as a ligand substituent in organometallic chemistry: A second chance and a second research career

(2010) Russell P. Hughes   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed C−F Activation of Polyfluoronitrobenzene Derivatives in Suzuki−Miyaura Coupling Reactions

(2010) Matthew R. Cargill et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of anchoring group and valent of cobalt center on the competitive cleavage of C–F or C–H bond activation

(2010) Tingting Zheng et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Bridged Binding Mode as a New, Versatile Template for the Selective Activation of Carbon−Fluorine Bonds in Fluoroolefins: Activation of Trifluoroethylene

(2010) Michael E. Slaney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly regioselective nickel-catalyzed hydrodefluorination of pentafluoroacetanilide

(2010) Sergey A. Prikhod’ko et al.   MENDELEEV COMMUNICATIONS

Selective Activation of theorthoC−F Bond in Pentafluoropyridine by Zerovalent Nickel: Reaction via a Metallophosphorane Intermediate Stabilized by Neighboring Group Assistance from the Pyridyl Nitrogen

(2010) Ainara Nova et al.   ORGANOMETALLICS

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Synthesis of rhodium(i) and rhodium(iii) perfluoroalkyl complexes from [Rh(μ-OH)(COD)]2

(2009) José Vicente et al.   DALTON TRANSACTIONS

Activation of ethylene and ammonia at iridium: C–H versus N–H oxidative addition

(2009) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds

(2009) Russell P. Hughes   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of bis(polyfluoroalkylated)imidazolium salts as key intermediates for fluorous NHC ligands

(2009) Martin Skalický et al.   JOURNAL OF FLUORINE CHEMISTRY

Fluxionality of [(Ph3P)3Rh(X)]: The Extreme Case of X = CF3

(2009) Jenni Goodman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exceptional Sensitivity of Metal−Aryl Bond Energies toortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M−C/H−C Bond Energy Correlations

(2009) Eric Clot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Fluorination of Functionalized Aryl Stannanes

(2009) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes

(2009) Steven P. Reade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Combined Experimental and Computational Study of Unexpected C−F Bond Activation Intermediates and Selectivity in the Reaction of Pentafluorobenzene with a (PEt3)2Ni Synthon

(2009) Samuel A. Johnson et al.   ORGANOMETALLICS

Dual Behavior of Cationic Palladium Pentafluorophenyl Complexes as Catalysts for the Homopolymerization of Acrylates and of Nonpolar Olefins

(2009) Raquel López-Fernández et al.   ORGANOMETALLICS

Phosphinorhodium-Catalyzed Dehalogenation of Chlorinated and Fluorinated Ethylenes: Distinct Mechanisms with Triethylsilane and Dihydrogen

(2009) Alicia A. Peterson et al.   ORGANOMETALLICS

Synergistic Effect of a Low-Valent Cobalt Complex and a Trimethylphosphine Ligand on Selective C−F Bond Activation of Perfluorinated Toluene

(2009) Tingting Zheng et al.   ORGANOMETALLICS

Selective Platinum-Catalyzed C−F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

(2009) Heather L. Buckley et al.   ORGANOMETALLICS

User-Friendly Precatalyst for the Methylation of Polyfluoroaryl Imines

(2009) Heather L. Buckley et al.   ORGANOMETALLICS

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

C–F Activation of hydrofluorocarbons (HFCs) mediated by aluminum reagents

(2009) Majeid Ali et al.   TETRAHEDRON LETTERS

CC Coupling Reactions of Superstrong CF3Groups with C(sp2)-H Bonds: Reactivity and Synthetic Utility of Zero-Valent Niobium Catalyst

(2008) Kohei Fuchibe et al.   Chemistry-An Asian Journal

Iridium derivatives of fluorinated aromatics by C–H activation: isolation of classical and non-classical hydrides

(2008) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

The fluorolytic sol–gel route to metal fluorides—a versatile process opening a variety of application fields

(2008) Stephan Rüdiger et al.   DALTON TRANSACTIONS

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unexpected Intermediates and Products in the C−F Bond Activation of Tetrafluorobenzenes with a Bis(triethylphosphine)Nickel Synthon: Direct Evidence of a Rapid and Reversible C−H Bond Activation by Ni(0)

(2008) Samuel A. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides:p-Orientation in the Polyarylthiolation of Polyfluorobenzenes

(2008) Mieko Arisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Study of the Reaction of C6F6with [IrMe(PEt3)3]: Identification of a Phosphine-Assisted C−F Activation Pathway via a Metallophosphorane Intermediate

(2008) Stefan Erhardt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competing C−F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition

(2008) Ainara Nova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Cp*Ir(CO)2 with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution

(2008) Pek Ke Chan et al.   ORGANOMETALLICS

Dehydrofluorination of Hydrofluorocarbons by Titanium Alkylidynes via Sequential C−H/C−F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination

(2008) Alison R. Fout et al.   ORGANOMETALLICS

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Xenon Difluoride Induced Aryl Iodide Reductive Elimination:  a Simple Access to Difluoropalladium(II) Complexes

(2007) Ariela W. Kaspi et al.   INORGANIC CHEMISTRY