Trifluorodiazoethane (CF3CHN2) in the Uncatalyzed Cyclopropanation of 3-Arylmethylenebenzofuran-2(3 H)-ones

Copper-triggered three-component reaction of CF3CHN2, nitriles, and aldehydes: highly diastereoselective synthesis of CF3-substituted oxazolines and vicinal amino alcohols

(2015) Ai-Jie Cai et al.   CHEMICAL COMMUNICATIONS

[3 + 2] Cycloaddition of arynes with CF 3 CHN 2 : Access to 3-trifluoromethyl-1 H -indazoles

(2015) Long Sun et al.   JOURNAL OF FLUORINE CHEMISTRY

Three-component synthesis of fluorinated pyrazoles from fluoroalkylamines, NaNO2 and electron-deficient alkynes

(2015) Pavel K. Mykhailiuk   ORGANIC & BIOMOLECULAR CHEMISTRY

Brine-Stabilized 2,2,2-Trifluorodiazoethane and Its Application in the Synthesis of CF3–Substituted Cyclopropane α-Amino Acids

(2015) Chuan-Le Zhu et al.   ORGANIC LETTERS

Highly modular dipeptide-like organocatalysts for direct asymmetric aldol reactions in brine

(2015) Xiao-Mu Hu et al.   RSC Advances

Silver-catalyzed [3 + 2] cycloaddition of isocyanides with diazo compounds: new regioselective access to 1,4-disubstituted-1,2,3-triazoles

(2015) Shuai Wang et al.   Organic Chemistry Frontiers

Zinc-catalyzed synthesis of 2-alkenylfurans via cross-coupling of enynones and diazo compounds

(2014) Jesús González et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products

(2014) Heng-Ying Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic One-Pot Synthesis of Highly Substituted Pyridazines from Morita-Baylis-Hillman Carbonates and Diazo Compounds

(2014) Haibin Mao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Switchable 2,2,2-Trifluoroethylation andgem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane

(2014) Guojiao Wu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Trifluoromethyl-Substituted 3-Azabicyclo[n.1.0]alkanes: Advanced Building Blocks for Drug Discovery

(2014) Olexiy S. Artamonov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of CF3-Containing 3,3′-Cyclopropyl Spirooxindoles by Sequential [3 + 2] Cycloaddition/Ring Contraction of Ylideneoxindoles with 2,2,2-Trifluorodiazoethane

(2014) Tian-Ren Li et al.   JOURNAL OF ORGANIC CHEMISTRY

A Direct Copper-Promoted Three-Component Entry to Trifluoromethylketoximes

(2014) Shuai Wang et al.   ORGANIC LETTERS

Regioselective Cycloaddition of Trifluorodiazoethane with Electron-Deficient Allenic Esters and Ketones: Access to CF3-Substituted Pyrazolines and Pyrazoles

(2014) Fa-Guang Zhang et al.   ORGANIC LETTERS

Synthesis and Applications of α-Trifluoromethylated Alkylboron Compounds

(2013) O. Andreea Argintaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Cycloaddition of Alkynes with CF3CHN2: Highly Regioselective Synthesis of 3-Trifluoromethylpyrazoles

(2013) Feng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The influence of fluorine in asymmetric catalysis

(2013) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Expedient Stereoselective Synthesis of Spirocyclopropyl Oxindoles from Indolin-2-One/N-Protected Indolin-2-Ones and Bromonitroalkenes

(2013) Suparna Roy et al.   JOURNAL OF THE CHINESE CHEMICAL SOCIETY

Synthesis of Trifluoromethylated Isoxazolidines: 1,3-Dipolar Cycloaddition of Nitrosoarenes, (Trifluoromethyl)diazomethane, and Alkenes

(2013) Gary A. Molander et al.   ORGANIC LETTERS

Homologative Trifluoromethylation of Acetals

(2013) Erick Carreira et al.   SYNTHESIS-STUTTGART

A Facile Parallel Synthesis of Trifluoroethyl-Substituted Alkynes

(2012) Cui-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid-catalyzed diastereo- and enantioselective synthesis of CF3-substituted aziridines

(2012) Zhuo Chai et al.   CHEMICAL COMMUNICATIONS

Preparation of Trifluoromethyl-Substituted Aziridines with in Situ Generated CF3CHN2

(2012) Stefan A. Künzi et al.   ORGANIC LETTERS

Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

(2011) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Preparation of Trifluoromethyl Substituted Vinyl- and Alkynylcyclopropanes

(2011) Bill Morandi et al.   ORGANIC LETTERS

Expedient Preparation of Trifluoromethyl-Substituted Benzofuranols

(2011) Bill Morandi et al.   ORGANIC LETTERS

Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Cyclopropenation of Alkynes: Synthesis of Trifluoromethyl-Substituted Cyclopropenes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 2-Azabicyclo[4.1.0]heptanes through Stereoselective Cyclopropanation Reactions

(2010) Irene Suárez del Villar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Trifluoromethyl-substituted cyclopropanes

(2010) Oleksandr O. Grygorenko et al.   TETRAHEDRON

Iron-Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane

(2009) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dibutyl 2-(trifluoromethyl)cyclopropylboronate as a useful (trifluoromethyl)cyclopropyl donor: application to antagonists of TRPV1

(2009) Matthew A.J. Duncton et al.   TETRAHEDRON LETTERS

Synthesis of Trifluoromethyl‐Substituted Proline Analogues as19F NMR Labels for Peptides in the Polyproline II Conformation

(2008) Pavel K. Mykhailiuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS