Synthesis and Applications of α-Trifluoromethylated Alkylboron Compounds

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

(2013) Zhi-Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3

(2013) Xinyue Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols

(2013) Xiaowu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

(2013) Satoshi Mizuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Trifluoroethylation of Terminal Alkynes with 1,1,1-Trifluoro-2-iodoethane

(2013) Yi-Si Feng et al.   ORGANIC LETTERS

Rh-catalyzed Addition of β-Carbonyl Pinacol Alkylboronates to Aldehydes: Asymmetric Synthesis of γ-Butyrolactones

(2013) Changwan Zhang et al.   ORGANIC LETTERS

Photocatalytic Synthesis of Allylic Trifluoromethyl Substituted Styrene Derivatives in Batch and Flow

(2013) Lukas M. Kreis et al.   ORGANIC LETTERS

Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

(2013) Dale J. Wilger et al.   Chemical Science

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

(2012) Benjamin M. Partridge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Allylsilanes

(2012) Ryo Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids

(2012) Jun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tamed Arene and Heteroarene Trifluoromethylation

(2012) Tatiana Besset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereodivergent Synthesis of Trisubstituted Alkenes through Protodeboronation of Allylic Boronic Esters: Application to the Synthesis of the Californian Red Scale Beetle Pheromone

(2012) Matthew J. Hesse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Weinreb amide approach to the synthesis of trifluoromethylketones

(2012) DiAndra M. Rudzinski et al.   CHEMICAL COMMUNICATIONS

The palladium-catalyzed cross-coupling reactions of trifluoroethyl iodide with aryl and heteroaryl boronic acid esters

(2012) Apeng Liang et al.   CHEMICAL COMMUNICATIONS

Trifluoromethylation of Allylsilanes under Copper Catalysis

(2012) Satoshi Mizuta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

(2012) Scott N. Mlynarski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Simple Method for Asymmetric Trifluoromethylation of N-Acyl Oxazolidinones via Ru-Catalyzed Radical Addition to Zirconium Enolates

(2012) Aaron T. Herrmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation

(2012) Lingling Chu et al.   ORGANIC LETTERS

Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

(2011) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters

(2011) Yanchuan Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds

(2011) Phong V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation

(2011) Jun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents

(2011) Václav Matoušek et al.   ORGANIC LETTERS

Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents

(2011) Hiroyuki Kawai et al.   ORGANIC LETTERS

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Cyclopropenation of Alkynes: Synthesis of Trifluoromethyl-Substituted Cyclopropenes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine

(2010) Viktor Bagutski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidation of Alkyl Trifluoroborates: An Opportunity for Tin-Free Radical Chemistry

(2010) Geoffroy Sorin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers

(2010) Stefan Nave et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complete Stereoretention in the Rhodium-Catalyzed 1,2-Addition of Chiral Secondary and Tertiary Alkyl Potassium Trifluoroborate Salts to Aldehydes

(2009) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane

(2009) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates

(2009) David M. Knapp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration

(2009) Daisuke Imao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylation and Vinylation of α-Diazocarbonyl Compounds with Boroxines

(2009) Cheng Peng et al.   ORGANIC LETTERS

Synthesis of 2-aryl-3,3,3-trifluoropropanoic acids using electrochemical carboxylation of (1-bromo-2,2,2-trifluoroethyl)arenes and its application to the synthesis of β,β,β-trifluorinated non-steroidal anti-inflammatory drugs

(2009) Yusuke Yamauchi et al.   TETRAHEDRON

Nucleophilic trifluoromethylation of arylidene Meldrum’s acids

(2009) Artem A. Zemtsov et al.   TETRAHEDRON LETTERS

α-Trifluoromethylated Carbanion Synthons

(2008) Kenji Uneyama et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS