Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates

Palladium-catalyzed oxidative carbamoylation of isoquinoline N-oxides with formylamides by means of dual C–H oxidative coupling

(2015) Bo Yao et al.   CHEMICAL COMMUNICATIONS

Concise synthesis of cyclic carbonyl compounds from haloarenes using phenyl formate as the carbonyl source

(2015) Hideyuki Konishi et al.   CHEMICAL COMMUNICATIONS

C–H activation dependent Pd-catalyzed carbonylative coupling of (hetero)aryl bromides and polyfluoroarenes

(2015) Zhong Lian et al.   CHEMICAL COMMUNICATIONS

Palladium-catalysed carbonylative α-arylation of nitromethane

(2015) Zhong Lian et al.   CHEMICAL COMMUNICATIONS

Carbonylative Synthesis of Phthalimides and Benzoxazinones by Using Phenyl Formate as a Carbon Monoxide Source

(2015) Sujit P. Chavan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 4-Quinolones via a Carbonylative Sonogashira Cross-Coupling Using Molybdenum Hexacarbonyl as a CO Source

(2015) Linda Åkerbladh et al.   JOURNAL OF ORGANIC CHEMISTRY

General Method for the Preparation of Active Esters by Palladium-Catalyzed Alkoxycarbonylation of Aryl Bromides

(2015) Angelina M. de Almeida et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydroformylation of olefins and reductive carbonylation of aryl halides with syngas formed ex situ from dehydrogenative decarbonylation of hexane-1,6-diol

(2015) Stig Holden Christensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Acyl Carbamates via Four Component Pd-Catalyzed Carbonylative Coupling of Aryl Halides, Potassium Cyanate, and Alcohols

(2015) Hongfei Yin et al.   ORGANIC LETTERS

Asymmetric Pauson–Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis

(2015) Takuma Furusawa et al.   TETRAHEDRON

Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

(2014) Xiao-Feng Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Palladium-Catalyzed Carbonylative-Deacetylative Sequence to 1,3-Keto Amides

(2014) Dennis U. Nielsen et al.   ADVANCED SYNTHESIS & CATALYSIS

1,2,4- and 1,3,4-Oxadiazole Synthesis by Palladium-Catalyzed Carbonylative Assembly of Aryl Bromides with Amidoximes or Hydrazides

(2014) Thomas L. Andersen et al.   ADVANCED SYNTHESIS & CATALYSIS

Aryl Formate as Bifunctional Reagent: Applications in Palladium-Catalyzed Carbonylative Coupling Reactions Using In Situ Generated CO

(2014) Haoquan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylative α-Arylation of 2-Oxindoles with (Hetero)aryl Bromides: Efficient and Complementary Approach to 3-Acyl-2-oxindoles

(2014) Zhong Lian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters

(2014) Kishore Natte et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbonylations of Alkenes with CO Surrogates

(2014) Lipeng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource

(2014) Bo Yu et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Carbonylative Coupling of (2-Azaaryl)methyl Anion Equivalents with (Hetero)Aryl Bromides

(2014) Xavier Jusseau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Carbonylative [3+2+1] Annulation ofN-Aryl-Pyridine-2-Amines with Internal Alkynes by CH Activation: Facile Synthesis of 2-Quinolinones

(2014) Jianbin Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Vinyl- and Aryl-Acyl Sulfonimidamides Through Pd-Catalyzed Carbonylation Using Mo(CO)6as ex situ CO Source

(2014) Prasad B. Wakchaure et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A convenient palladium-catalyzed carbonylative synthesis of 4(3H)-quinazolinones from 2-bromoformanilides and organo nitros with Mo(CO)6 as a multiple promoter

(2014) Lin He et al.   GREEN CHEMISTRY

Palladium-Catalyzed Thiocarbonylation of Aryl, Vinyl, and Benzyl Bromides

(2014) Mia N. Burhardt et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Carbonylative Synthesis of Benzoxazinones from N-(o-Bromoaryl)amides Using Paraformaldehyde as the Carbonyl Source

(2014) Wanfang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel(0)-Catalyzed [2 + 2 + 1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to γ-Lactams

(2014) Yoichi Hoshimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Fluoride-Catalyzed Conversion of CO2 to CO at Room Temperature

(2014) Camille Lescot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

(2014) Stig D. Friis et al.   ORGANIC LETTERS

Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Bromides Using Near Stoichiometric Carbon Monoxide

(2014) Karoline T. Neumann et al.   ORGANIC LETTERS

Carbonylative Suzuki Couplings of Aryl Bromides with Boronic Acid Derivatives under Base-Free Conditions

(2014) Klaus M. Bjerglund et al.   ORGANIC LETTERS

Palladium-Catalyzed Carbonylation of Aryl Bromides with N-Substituted Cyanamides

(2014) Anders Lindhardt et al.   SYNLETT

Rhodium(I)-Catalyzed Carbonylative Arylation of Alkynes with Arylboronic Acids Using Formaldehyde as a Carbonyl Source

(2014) Tsumoru Morimoto et al.   SYNLETT

Formic Acid Derivatives as Practical Carbon Monoxide Surrogates for Metal-Catalyzed Carbonylation Reactions

(2014) Kei Manabe et al.   SYNLETT

One-Pot Direct Synthesis of Weinreb Amides from Aryl and Hetero Aryl Halides Using Co2(CO)8as an Effective CO Source Under Conventional Thermal Heating

(2014) Poongavanam Baburajan et al.   SYNTHETIC COMMUNICATIONS

Convenient method for the synthesis of phthalazinones via carbonylation of 2-bromobenzaldehyde using Co2(CO)8 as a CO source

(2014) A. Sivalingam Suresh et al.   TETRAHEDRON LETTERS

One pot direct synthesis of β-ketoesters via carbonylation of aryl halides using cobalt carbonyl

(2014) Poongavanam Baburajan et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C–C Bond Cleavage

(2014) Hyo-Soon Park et al.   ACS Catalysis

WCl6/DMF as a new reagent system for the phosphine-free Pd(0)-catalyzed aminocarbonylation of aryl halides

(2014) Nasser Iranpoor et al.   RSC Advances

Palladium-Catalyzed Carbonylative Synthesis of Phthalimides from 1,2-Dibromoarenes with Molybdenum Hexacarbonyl as Carbon Monoxide Source

(2013) Xiao-Feng Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Access to β-Keto Esters by Palladium-Catalyzed Carbonylative Coupling of Aryl Halides with Monoester Potassium Malonates

(2013) Signe Korsager et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Reductive Carbonylation of Aryl Halides withN-Formylsaccharin as a CO Source

(2013) Tsuyoshi Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Carbonylative α-Arylation of Aryl Bromides: Scope and Mechanistic Studies

(2013) Dennis U. Nielsen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Route to 1,3-Diketones by Palladium-Catalyzed Carbonylative Coupling of Aryl Halides with Acetylacetone

(2013) Signe Korsager et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Convenient Palladium-Catalyzed Carbonylative Synthesis of 2-Aminbenzoxazinones from 2-Bromoanilines and Isocyanates

(2013) Xiao-Feng Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Oxidative Carbonylation Reactions

(2013) Xiao-Feng Wu et al.   ChemSusChem

Diarylated Ethanones from Mo(CO)6-Mediated and Microwave-Assisted Palladium-Catalysed Carbonylative Negishi Cross-Couplings

(2013) Hitesh V. Motwani et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Aminocarbonylation of 4-Iodo-1H-imidazoles with an Amino Acid Amide Nucleophile: Synthesis of Constrained H-Phe-Phe-NH2 Analogues

(2013) Anna Skogh et al.   JOURNAL OF ORGANIC CHEMISTRY

Reductive Carbonylation of Aryl Halides Employing a Two-Chamber Reactor: A Protocol for the Synthesis of Aryl Aldehydes Including 13C- and D-Isotope Labeling

(2013) Signe Korsager et al.   JOURNAL OF ORGANIC CHEMISTRY

An Air-Tolerant Approach to the Carbonylative Suzuki–Miyaura Coupling: Applications in Isotope Labeling

(2013) Andreas Ahlburg et al.   JOURNAL OF ORGANIC CHEMISTRY

Effective Palladium-Catalyzed Hydroxycarbonylation of Aryl Halides with Substoichiometric Carbon Monoxide

(2013) Signe Korsager et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt carbonyl as an effective CO source in one-pot synthesis of esters from aryl halides

(2013) P. Baburajan et al.   NEW JOURNAL OF CHEMISTRY

Modernized Low Pressure Carbonylation Methods in Batch and Flow Employing Common Acids as a CO Source

(2013) Célia Brancour et al.   ORGANIC LETTERS

Synthesis of Novel Aryl and Heteroaryl Acyl Sulfonimidamides via Pd-Catalyzed Carbonylation Using a Nongaseous Precursor

(2013) Sanjay R. Borhade et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of Aromatic Carboxylic Acids with Silacarboxylic Acids

(2013) Stig D. Friis et al.   ORGANIC LETTERS

Pd-Catalyzed Thiocarbonylation with Stoichiometric Carbon Monoxide: Scope and Applications

(2013) Mia N. Burhardt et al.   ORGANIC LETTERS

Palladium-Catalyzed Fluorocarbonylation Using N-Formylsaccharin as CO Source: General Access to Carboxylic Acid Derivatives

(2013) Tsuyoshi Ueda et al.   ORGANIC LETTERS

Palladium-catalyzed carbonylative synthesis of N-(2-cyanoaryl)benzamides and sequential synthesis of quinazolinones

(2013) Xiao-Feng Wu et al.   TETRAHEDRON

Microwave assisted palladium-catalyzed synthesis of phthalazinones and pyridopyridazinones

(2013) K. Penta Rao et al.   TETRAHEDRON LETTERS

Palladium-catalyzed carbonylative synthesis of N-cyanobenzamides from aryl iodides/bromides and cyanamide

(2013) Rajendra S. Mane et al.   TETRAHEDRON LETTERS

Co2(CO)8 as a convenient in situ CO source for the direct synthesis of benzamides from aryl halides (Br/I) via aminocarbonylation

(2013) Poongavanam Baburajan et al.   TETRAHEDRON LETTERS

Recent developments in palladium catalysed carbonylation reactions

(2013) Sandip T. Gadge et al.   RSC Advances

Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

(2012) Tetsuaki Fujihara et al.   CHEMICAL COMMUNICATIONS

Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations

(2012) Xiao-Feng Wu et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Dehydrogenative Decarbonylation of Primary Alcohols with the Liberation of Syngas

(2012) Esben P. K. Olsen et al.   CHEMISTRY-A EUROPEAN JOURNAL

14Carbon monoxide made simple - novel approach to the generation, utilization, and scrubbing of14carbon monoxide

(2012) Anders T. Lindhardt et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

Palladium-Catalyzed N-Acylation of Monosubstituted Ureas Using Near-Stoichiometric Carbon Monoxide

(2012) Klaus Bjerglund et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(I)-Catalyzed Asymmetric Synthesis of 3-Substituted Isoindolinones through CO Gas-Free Aminocarbonylation

(2012) Masahiko Fujioka et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Double Carbonylation Using Near Stoichiometric Carbon Monoxide: Expedient Access to Substituted 13C2-Labeled Phenethylamines

(2012) Dennis U. Nielsen et al.   JOURNAL OF ORGANIC CHEMISTRY

Isotope-Labeling of the Fibril Binding Compound FSB via a Pd-Catalyzed Double Alkoxycarbonylation

(2012) Mia N. Burhardt et al.   JOURNAL OF ORGANIC CHEMISTRY

Aminocarbonylations Employing Mo(CO)6 and a Bridged Two-Vial System: Allowing the Use of Nitro Group Substituted Aryl Iodides and Aryl Bromides

(2012) Patrik Nordeman et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate

(2012) Tsuyoshi Ueda et al.   ORGANIC LETTERS

Trichlorophenyl Formate: Highly Reactive and Easily Accessible Crystalline CO Surrogate for Palladium-Catalyzed Carbonylation of Aryl/Alkenyl Halides and Triflates

(2012) Tsuyoshi Ueda et al.   ORGANIC LETTERS

Palladium Catalyzed Carbonylative Heck Reaction Affording Monoprotected 1,3-Ketoaldehydes

(2012) Thomas M. Gøgsig et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Cyclocarbonylation of Enynes with Glyceraldehyde: An Available Carbonyl Source Derived from Sugar Alcohols

(2012) Tsumoru Morimoto et al.   SYNLETT

Molybdenum Hexacarbonyl Mediated CO Gas-Free Carbonylative Reactions

(2012) Luke Odell et al.   SYNLETT

Palladium-Catalyzed Carbonylation with Mo(CO)6 for the Synthesis of Benzoylacetonitriles

(2012) Sunwoo Lee et al.   SYNTHESIS-STUTTGART

Metal-catalyzed amidation

(2012) Sudipta Roy et al.   TETRAHEDRON

Preparation of α,β-unsaturated esters and amides via external-CO-free palladium-catalyzed carbonylation of alkenyl tosylates

(2012) Tsuyoshi Ueda et al.   TETRAHEDRON LETTERS

Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance

(2012) Joyce C. Leung et al.   Chemical Science

Palladium-Catalyzed Hydroesterification of Alkynes Employing Aryl Formates without the Use of External Carbon Monoxide

(2011) Yuko Katafuchi et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Carbonylative α-Arylation for Accessing 1,3-Diketones

(2011) Thomas M. Gøgsig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

(2011) Xiao-Feng Wu et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Acylation of Arylpyridines with Acyl Chlorides viaortho-Selective C–H Bond Cleavage

(2011) Takuya Kochi et al.   CHEMISTRY LETTERS

Bis(cyclopentadienyldicarbonyliron) as a Convenient Carbon Monoxide Source in Palladium-catalyzed Carbonylative Coupling of Aryl Iodides with Amines, Alcohols, and Thiols

(2011) Ryotaro Nakaya et al.   CHEMISTRY LETTERS

Carbon Monoxide-Free One-Step Synthesis of Isoindole-1,3-diones by Cycloaminocarbonylation of o-Haloarenes Using Formamides

(2011) Dinesh N. Sawant et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Silicadiphenyl phosphinite (SDPP)/Pd(0) nanocatalyst for efficient aminocarbonylation of aryl halides with POCl3 and DMF

(2011) Nasser Iranpoor et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Palladium-Catalyzed Carbon-Monoxide-Free Aminocarbonylation of Aryl Halides Using N-Substituted Formamides as an Amide Source

(2011) Dinesh N. Sawant et al.   JOURNAL OF ORGANIC CHEMISTRY

Silacarboxylic Acids as Efficient Carbon Monoxide Releasing Molecules: Synthesis and Application in Palladium-Catalyzed Carbonylation Reactions

(2011) Stig D. Friis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenative [4 + 2] Cycloaddition of Formamides with Alkynes through Double C−H Activation

(2011) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ex Situ Generation of Stoichiometric and Substoichiometric 12CO and 13CO and Its Efficient Incorporation in Palladium Catalyzed Aminocarbonylations

(2011) Philippe Hermange et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Method for the Preparation of Tertiary Esters by Palladium-Catalyzed Alkoxycarbonylation of Aryl Bromides

(2011) Zhuo Xin et al.   ORGANIC LETTERS

Palladium-Catalyzed Approach to Primary Amides Using Nongaseous Precursors

(2011) Dennis U. Nielsen et al.   ORGANIC LETTERS

New Reactivity of Oxaziridine: Pd(II)-Catalyzed Aromatic C–H Ethoxycarbonylation via C–C Bond Cleavage

(2011) Xingao Peng et al.   ORGANIC LETTERS

Carbonylative Heck Reactions Using CO Generatedex Situin a Two-Chamber System

(2011) Philippe Hermange et al.   ORGANIC LETTERS

N-Formylsaccharin: A New Formylating Agent

(2011) Janine Cossy et al.   SYNLETT

Rhodium-Catalyzed Pauson-Khand-Type Reaction Using Alcohol as a Source of Carbon Monoxide

(2010) Ji Hoon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Utilization of Aldoses as a Carbonyl Source in Cyclocarbonylation of Enynes

(2010) Keiichi Ikeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes

(2010) Tetsuaki Fujihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-catalysed carbonylations: versatile technology for discovery and process chemists

(2010) Ronald Grigg et al.   TETRAHEDRON

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylation Reactions of Alkenes and Alkynes

(2009) Anne Brennführer et al.   ChemCatChem

Copper(i) scorpionate complexes and their application in palladium-mediated [11C]carbonylation reactions

(2009) Steven Kealey et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives

(2009) Youngshin Jo et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydrocarbamoylation of Unsaturated Bonds by Nickel/Lewis-Acid Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C−H Bond Cleavage

(2009) Takuya Kochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde

(2009) Tsumoru Morimoto et al.   ORGANIC LETTERS

Microwave‐Assisted Rhodium‐Complex‐Catalyzed Cascade Decarbonylation and Asymmetric Pauson–Khand‐Type Cycli­zations

(2008) Hang Wai Lee et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxidative Ethoxycarbonylation of Aromatic C−H Bond with Diethyl Azodicarboxylate

(2008) Wing-Yiu Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed CarbonylationA Reaction Come of Age

(2008) Christopher F. J. Barnard   ORGANOMETALLICS

Pd/C: an efficient, heterogeneous and reusable catalyst for carbon monoxide-free aminocarbonylation of aryl iodides

(2008) Pawan J. Tambade et al.   TETRAHEDRON LETTERS