Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance

Regioselective Hydrocarbamoylation of 1-Alkenes

(2012) Yosuke Miyazaki et al.   CHEMISTRY LETTERS

Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

(2012) Adrian B. Chaplin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarbonylation of Aliphatic Aldehydes by a TpMe2Ir(III) Metallacyclopentadiene

(2012) Arián E. Roa et al.   ORGANOMETALLICS

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts

(2012) Kian Tan et al.   SYNLETT

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

(2011) Akkattu T. Biju et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch

(2011) Carlos González-Rodríguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes

(2011) Fan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Decarbonylation of 5-(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide

(2011) Frank M. A. Geilen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Alkyne Hydroacylation Route to Highly Substituted Furans

(2011) Philip Lenden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes

(2011) Isabel Piel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system

(2011) Nicolas R. Vautravers et al.   CHEMICAL COMMUNICATIONS

Novel Reactivity of N-Bridged Diiron Phthalocyanine in the Activation of CH Bonds: Hydroacylation of Olefins as an Example of the Efficient Formation of CC Bonds

(2011) Leonardo X. Alvarez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism and Origins of Regio- and Enantioselectivities in RhI-Catalyzed Hydrogenative Couplings of 1,3-Diynes and Activated Carbonyl Partners: Intervention of a Cumulene Intermediate

(2011) Peng Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Umpolung Catalysis in Benzoin-type and Stetter-type Reactions: From Enzymatic Performances to Bio-mimetic Organocatalytic Concepts

(2011) Pablo Dominguez de Maria et al.   CURRENT ORGANIC CHEMISTRY

N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes

(2011) Xavier Bugaut et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regioselective Intermolecular Hydroacylations of Enamides with Salicylaldehydes

(2011) Hui-Jun Zhang et al.   ORGANIC LETTERS

Catalytic Hydroacylation as an Approach to Homoaldol Products

(2011) Stephen K. Murphy et al.   ORGANIC LETTERS

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions

(2011) Carlos González-Rodríguez et al.   PURE AND APPLIED CHEMISTRY

Intermolecular N-Heterocyclic Carbene Catalyzed Hydroacylation of Arynes

(2010) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalysed Intermolecular Alkyne Hydroacylation: The Enantioselective Synthesis of α- and β-Substituted Ketones by Kinetic Resolution

(2010) Carlos González-Rodríguez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides

(2010) Matthew M. Coulter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation

(2010) Diem H. T. Phan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes

(2010) Tetsuaki Fujihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes

(2010) Akkattu T. Biju et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroacylation of α,β-unsaturated esters via aerobic C–H activation

(2010) Vijay Chudasama et al.   Nature Chemistry

Nickel(0)-Catalyzed Formation of Oxaaluminacyclopentenes via an Oxanickelacyclopentene Key Intermediate: Me2AlOTf-Assisted Oxidative Cyclization of an Aldehyde and an Alkyne with Nickel(0)

(2010) Masato Ohashi et al.   ORGANOMETALLICS

Synthesis of γ-ketophosphonates via aerobic hydroacylation of vinyl phosphonates

(2010) Vijay Chudasama et al.   TETRAHEDRON LETTERS

Asymmetric Rh-Catalyzed Intermolecular Hydroacylation of 1,5-Hexadiene with Salicylaldehyde

(2009) Yasuhiro Inui et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

Hydrogen generation from formic acid and alcohols using homogeneous catalysts

(2009) Tarn C. Johnson et al.   CHEMICAL SOCIETY REVIEWS

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 2-Alkynes Leading to Hydroacylation Products

(2009) Shintaro Hatanaka et al.   CHEMISTRY-A EUROPEAN JOURNAL

anti-Aminoallylation of Aldehydes via Ruthenium-Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols

(2009) Eduardas Skucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C−C Bond-Forming Transfer Hydrogenation

(2009) Ryan L. Patman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarbamoylation of Unsaturated Bonds by Nickel/Lewis-Acid Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ESI-MS, DFT, and Synthetic Studies on the H2-Mediated Coupling of Acetylene: Insertion of C═X Bonds into Rhodacyclopentadienes and Brønsted Acid Cocatalyzed Hydrogenolysis of Organorhodium Intermediates

(2009) Vanessa M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes

(2009) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds

(2009) Keiichi Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

(2009) Yasushi Obora et al.   ORGANIC LETTERS

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of β,γ-unsaturated ketones

(2009) Helen E. Randell-Sly et al.   TETRAHEDRON

Hydroacylation of 2-butyne from the alcohol or aldehyde oxidation level via ruthenium catalyzed C–C bond forming transfer hydrogenation

(2009) Vanessa M. Williams et al.   TETRAHEDRON

The iridium-catalyzed decarbonylation of aldehydes under mild conditions

(2008) Tomohiro Iwai et al.   CHEMICAL COMMUNICATIONS

Intermolecular Alkene and Alkyne Hydroacylation with β-S-Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P-O-P Ligand

(2008) Gemma L. Moxham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Intermolecular Hydroacylation: Rhodium-Catalyzed Combination of β-S-Aldehydes and 1,3-Disubstituted Allenes

(2008) James D. Osborne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C−C Bond-Forming Transfer Hydrogenation: Synthesis of β,γ-Unsaturated Ketones

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Hydride-Catalyzed Addition of Aldehydes to Dienes Leading to β,γ-Unsaturated Ketones

(2008) Sohei Omura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of unsymmetrical ketonesvia simple C–H activation of aldehydes and concomitant hydroacylation of vinyl sulfonates

(2008) Richard J. Fitzmaurice et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Heterocyclic carbene catalyzed intramolecular nucleophilic addition of carbonyl anion equivalents to enol ethers

(2008) Jinmei He et al.   TETRAHEDRON