Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic

(2013) Yang Li et al.   Nature Chemistry

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations

(2012) Christopher R. Waidmann et al.   Energy & Environmental Science

Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins

(2012) Manolis M. Roubelakis et al.   Energy & Environmental Science

Successive Heterolytic Cleavages of H2 Achieve N2 Splitting on Silica-Supported Tantalum Hydrides: A DFT Proposed Mechanism

(2012) Xavier Solans-Monfort et al.   INORGANIC CHEMISTRY

Unification of reaction pathway and kinetic scheme for N2 reduction catalyzed by nitrogenase

(2012) D. Lukoyanov et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Radical SAM-Dependent Carbon Insertion into the Nitrogenase M-Cluster

(2012) J. A. Wiig et al.   SCIENCE

Ammonia and Dinitrogen Activation by Surface Organometallic Chemistry on Silica-Grafted Tantalum Hydrides

(2011) Catherine Chow et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coordination of a Complete Series of N2 Reduction Intermediates (N2H2, N2H4, and NH3) to an Iron Phosphine Scaffold

(2011) Justin L. Crossland et al.   INORGANIC CHEMISTRY

Heterolytic cleavage of ammonia N–H bond by bifunctional activation in silica-grafted single site Ta(V) imido amido surface complex. Importance of the outer sphere NH3 assistance

(2011) Eric Gouré et al.   NEW JOURNAL OF CHEMISTRY

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

The hydride route to the preparation of dinitrogen complexes

(2010) Joachim Ballmann et al.   CHEMICAL COMMUNICATIONS

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Impact of surface chemistry

(2010) G. A. Somorjai et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

(2009) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex

(2009) Donald J. Knobloch et al.   Nature Chemistry

H/D Exchange on Silica-Grafted Tantalum(V) Imido Amido [(≡SiO)2Ta(V)(NH)(NH2)] Synthesized from Either Ammonia or Dinitrogen: IR and DFT Evidence for Heterolytic Splitting of D2

(2009) Priscilla Avenier et al.   TOPICS IN CATALYSIS

Side-on End-on Bound Dinitrogen: An Activated Bonding Mode That Facilitates Functionalizing Molecular Nitrogen

(2008) Michael D. Fryzuk   ACCOUNTS OF CHEMICAL RESEARCH

Energetics and Mechanism of Dinitrogen Cleavage at a Mononuclear Surface Tantalum Center: A New Way of Dinitrogen Reduction

(2008) Jun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture)

(2008) Gerhard Ertl   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Principles Investigation of the Schrock Mechanism of Dinitrogen Reduction Employing the Full HIPTN3N Ligand

(2008) Stephan Schenk et al.   INORGANIC CHEMISTRY

Energetics and Mechanism of Ammonia Synthesis through the Chatt Cycle: Conditions for a Catalytic Mode and Comparison with the Schrock Cycle

(2007) Gerald C. Stephan et al.   CHEMISTRY-A EUROPEAN JOURNAL