Redox-Active Ligands in Catalysis

Knölker’s Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines

(2012) Anastassiya Pagnoux-Ozherelyeva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium Complexes of a Chelating Ligand with Imidazol-2-ylidene and Pyridin-2-ylidene Donors: The Effect of C-Metalation of Nicotinamide Groups on Uptake of Hydride Ion

(2012) Alex McSkimming et al.   INORGANIC CHEMISTRY

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Five-Coordinate Iron Center in the Active Site of [Fe]-Hydrogenase: Hints from a Model Study

(2011) Dafa Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of OO Bond Formation in Tanaka’s Water Oxidation Catalyst

(2011) Soumya Ghosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Redox Properties of Tanaka’s Water Oxidation Catalyst: Redox Noninnocent Ligands Dominate the Electronic Structure and Reactivity

(2011) Soumya Ghosh et al.   INORGANIC CHEMISTRY

Manifestations of Noninnocent Ligand Behavior

(2011) Wolfgang Kaim   INORGANIC CHEMISTRY

Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å

(2011) Yasufumi Umena et al.   NATURE

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

The Third Hydrogenase: A Ferracyclic Carbamoyl with Close Structural Analogy to the Active Site of Hmd

(2010) Peter J. Turrell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Hydride ion-carrier ability in Rh(i) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand

(2010) Alex McSkimming et al.   DALTON TRANSACTIONS

A Unifying Structural and Electronic Concept for Hmd and [FeFe] Hydrogenase Active Sites

(2010) Martin T. Stiebritz et al.   INORGANIC CHEMISTRY

Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene

(2010) Andrew G. Tennyson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Making Oxygen with Ruthenium Complexes

(2009) Javier J. Concepcion et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Electron transfer in peptides and proteins

(2009) Meike Cordes et al.   CHEMICAL SOCIETY REVIEWS

1,1′-Bis(N-benzimidazolylidene)ferrocene: synthesis and study of a novel ditopic ligand and its transition metal complexes

(2009) C. Daniel Varnado Jr et al.   DALTON TRANSACTIONS

Characterization of Redox States of Ru(OH2)(Q)(tpy)2+(Q = 3,5-di-tert-butyl-1,2-benzoquinone, tpy = 2,2′:6′,2″-terpyridine) and Related Species through Experimental and Theoretical Studies

(2009) Ming-Kang Tsai et al.   INORGANIC CHEMISTRY

Iron-Catalyzed, Hydrogen-Mediated Reductive Cyclization of 1,6-Enynes and Diynes: Evidence for Bis(imino)pyridine Ligand Participation

(2009) Kevin T. Sylvester et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

(2008) Julio Piera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of New Hybrid Hydroquinone/Cobalt Schiff Base Catalysts: Efficient Electron-Transfer Mediators in Aerobic Oxidation

(2008) Byron W. Purse et al.   CHEMISTRY-A EUROPEAN JOURNAL

Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal

(2008) James T. Muckerman et al.   INORGANIC CHEMISTRY

π•−π•Bonding Interactions Generated by Halogen Oxidation of Zirconium(IV) Redox-Active Ligand Complexes

(2008) Nicole A. Ketterer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine

(2008) Karen J. Blackmore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster

(2008) Arti S. Pandey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds

(2007) Christine Sui-Seng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand

(2007) Mark R. Ringenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY