Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements

Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives

(2017) Daniel S. Müller et al.   ORGANIC LETTERS

Terminal-Selective Functionalization of Alkyl Chains by Regioconvergent Cross-Coupling

(2016) Stéphanie Dupuy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Additive Definition of Molecular Complexity

(2016) Thomas Böttcher   Journal of Chemical Information and Modeling

Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers

(2016) Harshkumar H. Patel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Long-Range Deconjugative Isomerization of Highly Substituted α,β-Unsaturated Carbonyl Compounds

(2016) Luqing Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereodivergent combined carbometalation/zinc homologation/C–C fragmentation reaction as an efficient tool to prepare acyclic allylic quaternary carbon stereocenters

(2016) Sudipta Raha Roy et al.   Chemical Science

Brook Rearrangement as a Trigger for the Ring Opening of Strained Carbocycles

(2015) Fa-Guang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclopropene Derivatives as Precursors to Enantioenriched Cyclopropanols andn-Butenals Possessing Quaternary Carbon Stereocenters

(2015) Marwan Simaan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

(2015) Laetitia Souillart et al.   CHEMICAL REVIEWS

Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters

(2015) Chun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol

(2015) Alexandre Vasseur et al.   Chemical Science

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols

(2014) Margaret J. Hilton et al.   JOURNAL OF ORGANIC CHEMISTRY

A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities

(2014) Yanfeng Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism in Palladium-Catalyzed Isomerizations of Highly Substituted Allylic, Homoallylic, and Alkenyl Alcohols

(2014) Evgeny Larionov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

(2014) Liping Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly-line synthesis of organic molecules with tailored shapes

(2014) Matthew Burns et al.   NATURE

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All-Carbon Quaternary Stereogenic Centers in Acyclic Systems

(2013) Pierre-Olivier Delaye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes

(2013) Dorian Didier et al.   CHEMISTRY-A EUROPEAN JOURNAL

Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds

(2013) Lei Jiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Merging allylic carbon–hydrogen and selective carbon–carbon bond activation

(2013) Ahmad Masarwa et al.   NATURE

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Diversity-oriented synthesis: producing chemical tools for dissecting biology

(2012) Cornelius J. O' Connor et al.   CHEMICAL SOCIETY REVIEWS

Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

(2012) Klaus Ruhland   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Aiming for the Ideal Synthesis

(2010) Tanja Gaich et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A New Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons

(2010) Samah Simaan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes: New Access to Building Blocks with an Acyclic Quaternary Stereogenic Center

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Function-Oriented Synthesis, Step Economy, and Drug Design

(2007) Paul A. Wender et al.   ACCOUNTS OF CHEMICAL RESEARCH