A New Golden Age for Donor-Acceptor Cyclopropanes

A one-pot septanoside formation and glycosylation of acyclic dithioacetals derived from 1,2-cyclopropanated sugars

(2014) Patteti Venukumar et al.   CHEMICAL COMMUNICATIONS

Synthesis of Functionalizedtrans-A2B2-Porphyrins Using Donor-Acceptor Cyclopropane-Derived Dipyrromethanes

(2013) M. Hassan Beyzavi et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor-Acceptor Cyclopropanes: Accessing3a-Hydroxy [n.3.0]Carbobicycles

(2013) Hao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Triggered Ring Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal Allenylidene Intermediates

(2013) Yoshihiro Miyake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Straightforward and highly diastereoselective synthesis of 2,2-di-substituted perhydrofuro[2,3-b]pyran (and furan) derivatives promoted by BiCl3

(2013) Xiaofeng Ma et al.   CHEMICAL COMMUNICATIONS

A bioinspired route to indanes and cyclopentannulated hetarenes via (3+2)-cyclodimerization of donor–acceptor cyclopropanes

(2013) Olga A. Ivanova et al.   CHEMICAL COMMUNICATIONS

Ni-Catalyzed [8+3] cycloaddition of tropones with 1,1-cyclopropanediesters

(2013) Rubén Tejero et al.   CHEMICAL COMMUNICATIONS

Intramolecular donor–acceptor cyclopropane ring-opening cyclizations

(2013) Marchello A. Cavitt et al.   CHEMICAL SOCIETY REVIEWS

Duality of Donor-Acceptor Cyclopropane Reactivity as a Three-Carbon Component in Five-Membered Ring Construction: [3+2] Annulation Versus [3+2] Cycloaddition

(2013) Yulia A. Volkova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rearrangements of Furan-, Thiophene- andN-Boc-Pyrrole-Derived Donor-Acceptor Cyclopropanes: Scope and Limitations

(2013) Johannes Kaschel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3 + 2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans

(2013) Gaosheng Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes

(2013) Hu Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Symmetric and unsymmetric 3,3′-linked bispyrroles via ring-enlargement reactions of furan-derived donor–acceptor cyclopropanes

(2013) Johannes Kaschel et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Urea-catalyzed construction of oxazinanes

(2013) Andrea M. Hardman et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Lewis Acids Promoted Formal Intramolecular [3 + 2] Parallel and Cross-Cycloadditions of Cyclopropane 1,1-Diesters with Allenes

(2013) Zhenjun Wang et al.   ORGANIC LETTERS

The Alkynyl Moiety as a Donor for Donor–Acceptor Cyclopropanes

(2013) Stefan Haubenreisser et al.   ORGANIC LETTERS

Six-Membered Cyclic Nitronates as 1,3-Dipoles in Formal [3 + 3]-Cycloaddition with Donor–Acceptor Cyclopropanes. Synthesis of New Type of Bicyclic Nitrosoacetals

(2013) Evgenia O. Gorbacheva et al.   ORGANIC LETTERS

Asymmetric Synthesis of Both Enantiomers of Arteludovicinolide A

(2013) Andreas Kreuzer et al.   ORGANIC LETTERS

Donor-Substituted Nitrocyclopropanes: Immediate Ring-Enlargement to Cyclic Nitronates

(2013) Christian D. Schmidt et al.   ORGANIC LETTERS

InBr3-Mediated One-Pot Synthesis of 2-(Polyhydroxylatedalkyl)-N-aryl-/-alkylpyrroles from 1,2-Cyclopropa-3-pyranone and Amines

(2013) Pingyuan Wang et al.   ORGANIC LETTERS

Regio- and Diastereoselective Stepwise [8 + 3]-Cycloaddition Reaction between Tropone Derivatives and Donor–Acceptor Cyclopropanes

(2013) Alexandra R. Rivero et al.   ORGANIC LETTERS

Catalytic Friedel–Crafts Reaction of Aminocyclopropanes

(2013) Florian de Nanteuil et al.   ORGANIC LETTERS

γ-Substituted Butanolides from Cyclopropane Hemimalonates: An Expedient Synthesis of Natural (R)-Dodecan-4-olide

(2013) Huck K. Grover et al.   ORGANIC LETTERS

Asymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel–Crafts Alkylation with Cyclopropanes

(2013) Steven M. Wales et al.   ORGANIC LETTERS

Alkylation and Ring Opening of Perfluoroalkyl- and Perfluoroaryl-Substituted 2-Siloxycyclopropanecarboxylates Yielding Fluorinated γ-Oxo Esters or β,γ-Unsaturated Ketones

(2013) Hans-Ulrich Reissig et al.   SYNTHESIS-STUTTGART

Multicomponent Synthesis of Pyrroles from Cyclopropanes: A One-Pot Palladium(0)-Catalyzed Dehydrocarbonylation/Dehydration

(2012) William J. Humenny et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Domino Reactions of Donor-Acceptor-Substituted Cyclopropanes for the Synthesis of 3,3′-Linked Oligopyrroles and Pyrrolo[3,2-e]indoles

(2012) Johannes Kaschel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalytic Multicomponent Approach for the Stereoselective Synthesis ofcis-4,5-Disubstituted Pyrrolidinones and Tetrahydro-3H-pyrrolo[3,2-c]quinolines

(2012) Sudipta Roy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Catalyzed Intramolecular [4+2] and [3+2] Cross-Cycloaddition of Alkynylcyclopropane Ketones with Carbonyl Compounds and Imines

(2012) Yu Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π-π Stacking Interactions

(2012) You-Yun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of (−)-paeonilide

(2012) Klaus Harrar et al.   CHEMICAL COMMUNICATIONS

Synthesis of 2-aminofurans and 2-unsubstituted furans via carbenoid-mediated [3 + 2] cycloaddition

(2012) Yaojia Jiang et al.   CHEMICAL COMMUNICATIONS

Donor–acceptor cyclopropanes with Lawesson's and Woollins' reagents: formation of bisthiophenes and unprecedented cage-like molecules

(2012) Johannes Kaschel et al.   CHEMICAL COMMUNICATIONS

Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity

(2012) Jian-Ping Qu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantiospecific [3+2] Annulation of Aminocyclopropanes with Ketones

(2012) Fides Benfatti et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Functionalized, Sterically Congested Calix[4]phyrin Macrocycles Using Donor-Acceptor-Substituted Cyclopropanes - First Example of a Mono-meso-spirolactone Incorporated into a Calix[4]phyrin

(2012) M. Hassan Beyzavi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Perfluoroalkyl-Substitutedγ-Lactones and 4,5-Dihydropyridazin-3(2H)-onesviaDonorAcceptor Cyclopropanes

(2012) Daniel Gladow et al.   HELVETICA CHIMICA ACTA

Stereoselective Double Lewis Acid/Organo-Catalyzed Dimerization of Donor–Acceptor Cyclopropanes into Substituted 2-Oxabicyclo[3.3.0]octanes

(2012) Roman A. Novikov et al.   JOURNAL OF ORGANIC CHEMISTRY

Tandem Ring-Opening Decarboxylation of Cyclopropane Hemimalonates with Sodium Azide: A Short Route to γ-Aminobutyric Acid Esters

(2012) Michael R. Emmett et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Fused Bromofurans via Mg-Mediated Dibromocyclopropanation of Cycloalkanone-Derived Chalcones and Cloke–Wilson Rearrangement

(2012) Elumalai Gopi et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Diastereo- and Enantioselective Formal [3 + 2]-Cycloadditions of Substituted Vinylcyclopropanes

(2012) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tungsten-Catalyzed Heterocycloisomerization Approach to 4,5-Dihydro-benzo[b]furans and -indoles

(2012) Ethan L. Fisher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

FeCl3 promoted highly regioselective [3 + 2] cycloaddition of dimethyl 2-vinyl and aryl cyclopropane-1,1-dicarboxylates with aryl isothiocyanates

(2012) Huina Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Ring Expansion–Glycosylation Strategy toward the Synthesis of Septano-oligosaccharides

(2012) Perali Ramu Sridhar et al.   ORGANIC LETTERS

Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes

(2012) Alexander F. G. Goldberg et al.   ORGANIC LETTERS

Enantioselective Cyclopropanation of Indoles: Construction of All-Carbon Quaternary Stereocenters

(2012) Gülsüm Özüduru et al.   ORGANIC LETTERS

Polar Intramolecular Cross-Cycloadditions of Cyclopropanes toward Natural Product Synthesis

(2012) Zhongwen Wang   SYNLETT

Lewis Acid-Catalyzed [3+4] Annulation of 2-(Heteroaryl)- cyclopropane-1,1-dicarboxylates with Cyclopentadiene

(2011) Olga A. Ivanova et al.   ADVANCED SYNTHESIS & CATALYSIS

Lewis Acid Catalyzed Intramolecular [3+2] Cross-Cycloaddition of Donor-Acceptor Cyclopropanes with Carbonyls: A General Strategy for the Construction of Acetal[n.2.1] Skeletons

(2011) Siyang Xing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic [3+2] Annulation of Aminocyclopropanes for the Enantiospecific Synthesis of Cyclopentylamines

(2011) Florian de Nanteuil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclobutanes in Catalysis

(2011) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An efficient synthesis of hydropyrido[1,2-a]indole-6(7H)-ones via an In(iii)-catalyzed tandem cyclopropane ring-opening/Friedel–Crafts alkylation sequence

(2011) Dadasaheb V. Patil et al.   CHEMICAL COMMUNICATIONS

Formal Homo-Nazarov and Other Cyclization Reactions of Activated Cyclopropanes

(2011) Filippo De Simone et al.   CHEMISTRY-A EUROPEAN JOURNAL

Domino Cyclodimerization of Indole-Derived Donor-Acceptor Cyclopropanes: One-Step Construction of the Pentaleno[1,6-a,b]indole Skeleton

(2011) Olga A. Ivanova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Total Synthesis of (+)-Hagen's Gland Lactones

(2011) Santosh J. Gharpure et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

(3 + 3)-Cyclodimerization of Donor–Acceptor Cyclopropanes. Three Routes to Six-Membered Rings

(2011) Olga A. Ivanova et al.   JOURNAL OF ORGANIC CHEMISTRY

Polarity Inversion of Donor–Acceptor Cyclopropanes: Disubstituted δ-Lactones via Enantioselective Iridium Catalysis

(2011) Joseph Moran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in ring-forming reactions of donor–acceptor cyclopropanes

(2011) Mikhail Ya. Mel’nikov et al.   MENDELEEV COMMUNICATIONS

Kleine Ringe erweitern: Auf die Spannung kommt es an

(2011) Johannes Kaschel et al.   NACHRICHTEN AUS DER CHEMIE

Stereoselective synthesis and applications of nitrogen substituted donor–acceptor cyclopropanes (N-DACs) in the divergent synthesis of azacycles

(2011) Santosh J. Gharpure et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Catalytic Homo-Nazarov Cyclization Protocol for the Synthesis of Heteroaromatic Ring-Fused Cyclohexanones

(2011) Lien H. Phun et al.   ORGANIC LETTERS

Ring-Enlargement Reactions of Donor−Acceptor-Substituted Cyclopropanes: Which Combinations are Most Efficient?

(2011) Tobias F. Schneider et al.   ORGANIC LETTERS

The Formal [4+3] Cycloaddition between Donor−Acceptor Cyclobutanes and Nitrones

(2011) Andrew C. Stevens et al.   ORGANIC LETTERS

Iron-Catalyzed [3 + 2] Annulation of Aminocyclopropanes with Aldehydes: Stereoselective Synthesis of Aminotetrahydrofurans

(2011) Fides Benfatti et al.   ORGANIC LETTERS

Highly Diastereoselective Synthesis of 1-PyrrolinesviaSnCl4-Promoted [3 + 2] Cycloaddition between Activated Donor–Acceptor Cyclopropanes and Nitriles

(2011) Gopal Sathishkannan et al.   ORGANIC LETTERS

Cyclopropane−Aldehyde Annulations at Quaternary Donor Sites: Stereoselective Access to Highly Substituted Tetrahydrofurans

(2011) Austin G. Smith et al.   ORGANIC LETTERS

Nucleophilic Ring Opening of Cyclopropane Hemimalonates Using Internal Brønsted Acid Activation

(2011) Michael R. Emmett et al.   ORGANIC LETTERS

[3+2] Cyclodimerization of 2-arylcyclopropane-1,1-diesters. Lewis acid induced reversion of cyclopropane umpolung

(2011) Alexey O. Chagarovskiy et al.   TETRAHEDRON LETTERS

Lewis Acid-Catalyzed Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates: A New Efficient Route to 2-Styrylmalonates

(2010) Alexey O. Chagarovskiy et al.   ADVANCED SYNTHESIS & CATALYSIS

Total Synthesis of (+)-Isatisine A

(2010) Avedis Karadeolian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Selective Cyclizations of Aminocyclopropanes: Formal Synthesis of Aspidospermidine and Total Synthesis of Goniomitine

(2010) Filippo De Simone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Construction of Oxa- and Aza-[n.2.1] Skeletons: Lewis Acid Catalyzed Intramolecular [3+2] Cycloaddition of Cyclopropane 1,1-Diesters with Carbonyls and Imines

(2010) Siyang Xing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Furan to Molecular Stairs: Syntheses, Structural Properties, and Theoretical Investigations of Oligocyclic Oligoacetals

(2010) Tobias F. Schneider et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Regioselective Control in the Diastereoselective 1,3-Dipolar Cycloaddition Reactions of 1-(1-Alkynyl)cyclopropyl Ketones with Nitrones

(2010) Yanqing Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (+)-Isatisine A

(2010) Avedis Karadeolian et al.   JOURNAL OF ORGANIC CHEMISTRY

Complexity-Building Annulations of Strained Cycloalkanes and C═O π Bonds

(2010) Matthew J. Campbell et al.   JOURNAL OF ORGANIC CHEMISTRY

AlCl3-Promoted Highly Regio- and Diastereoselective [3 + 2] Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans

(2010) Gaosheng Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Dynamic Kinetic Asymmetric Synthesis of Substituted Pyrrolidines from Racemic Cyclopropanes and Aldimines: Reaction Development and Mechanistic Insights

(2010) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 5-Azaindoles via a Cycloaddition Reaction between Nitriles and Donor−Acceptor Cyclopropanes

(2010) Mahmoud M. Abd Rabo Moustafa et al.   ORGANIC LETTERS

Synthesis of Enantioenriched Allenes from 1,1-Cyclopropanediesters

(2010) Pascal Cérat et al.   ORGANIC LETTERS

Indium-Catalyzed Homo-Nazarov Cyclizations of Alkenyl Cyclopropyl Ketones

(2010) Dadasaheb V. Patil et al.   ORGANIC LETTERS

Ytterbium Triflate Catalyzed Synthesis of Alkoxy-Substituted Donor−Acceptor Cyclobutanes and Their Formal [4 + 2] Cycloaddition with Imines: Stereoselective Synthesis of Piperidines

(2010) Mahmoud M. Abd Rabo Moustafa et al.   ORGANIC LETTERS

Intramolecular annulations of donor–acceptor cyclopropanes

(2010) Terry P. Lebold et al.   PURE AND APPLIED CHEMISTRY

Total synthesis of (+)-virgatusin via AlCl3-catalyzed [3+2] cycloaddition

(2009) Shanina D. Sanders et al.   CHEMICAL COMMUNICATIONS

Heterocycles from cyclopropanes: applications in natural product synthesis

(2009) Cheryl A. Carson et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of [n,5]-Spiroketals by Ring Enlargement of Donor-Acceptor-Substituted Cyclopropane Derivatives

(2009) Christian Brand et al.   JOURNAL OF ORGANIC CHEMISTRY

Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds

(2009) Jian-Ping Qu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Tetrahydropyrans from Propargyl Alcohols and 1,1-Cyclopropanediesters: A One-Pot Ring-Opening/Conia-ene Protocol

(2009) Andrew B. Leduc et al.   JOURNAL OF ORGANIC CHEMISTRY

Formal [4 + 2] Cycloaddition of Donor−Acceptor Cyclobutanes and Aldehydes: Stereoselective Access to Substituted Tetrahydropyrans

(2009) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes

(2009) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Donor−Acceptor Substituted Cyclopropafuranones by Intramolecular Cyclopropanation of Vinylogous Carbonates: Divergent Synthesis of Tetrahydrofuran-3-one, Tetrahydropyran-3-one, and Lactones

(2009) Santosh J. Gharpure et al.   ORGANIC LETTERS

Synthesis of Cyclohexanes via [3 + 3] Hexannulation of Cyclopropanes and 2-Chloromethyl Allylsilanes

(2009) Katarina Sapeta et al.   ORGANIC LETTERS

Total Synthesis of FR901483

(2009) Cheryl A. Carson et al.   ORGANIC LETTERS

Catalytic Formal Homo-Nazarov Cyclization

(2009) Filippo De Simone et al.   ORGANIC LETTERS

anti-Oligoannelated THF Moieties: Synthesis viaPush−Pull-Substituted Cyclopropanes‡

(2009) Tobias F. Schneider et al.   ORGANIC LETTERS

Stereodivergent Synthesis of Fused Bicyclopyrazolidines: Access to Pyrazolines and Pyrrolidines

(2009) Terry P. Lebold et al.   ORGANIC LETTERS

Zn(II)-Catalyzed Synthesis of Piperidines from Propargyl Amines and Cyclopropanes

(2009) Terry P. Lebold et al.   ORGANIC LETTERS

Total Synthesis of (−)-Allosecurinine

(2008) Andrew B. Leduc et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor–Acceptor Cyclopropanes as Three-Carbon Components in a [4+3] Cycloaddition Reaction with 1,3-Diphenylisobenzofuran

(2008) Olga A. Ivanova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylmethyl-substituted cyclopropyl and other strained ring systems: cycloaddition with dipolarophiles

(2008) Divya Agrawal et al.   CHEMICAL COMMUNICATIONS

Single-pot triple catalytic transformations based on coupling of in situ generated allyl boronates with in situ hydrolyzed acetals

(2008) Nicklas Selander et al.   CHEMICAL COMMUNICATIONS

Lewis Acid Catalyzed Reactions of Donor-Acceptor Cyclopropanes with Anthracenes

(2008) Olga A. Ivanova et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nucleophilic Addition of Phenol Derivatives to Methyl 1-Nitrocyclopropanecarboxylates

(2008) Olga Lifchits et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent Methodology for the Synthesis of Complex Pyrrolidines

(2008) Stephen K. Jackson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism for Lewis Acid-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes: Evidence for a Stereospecific Intimate Ion Pair Pathway

(2008) Patrick D. Pohlhaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Borylative Ring-Opening Reaction of Vinylcyclopropanes with Bis(pinacolato)diboron Yielding Allylic Boronates

(2008) Yuto Sumida et al.   ORGANIC LETTERS

Cycloadditions of Aromatic Azomethine Imines with 1,1-Cyclopropane Diesters

(2008) Christian Perreault et al.   ORGANIC LETTERS

A Mild Procedure for the Lewis Acid-Catalyzed Ring-Opening of Activated Cyclopropanes with Amine Nucleophiles

(2008) Olga Lifchits et al.   ORGANIC LETTERS