1,3-Dipolar Cycloadditions of Ethyl 2-Diazo-3,3,3-trifluoropropanoate to Alkynes and [1,5] Sigmatropic Rearrangements of the Resulting 3H-Pyrazoles: Synthesis of Mono-, Bis- and Tris(trifluoromethyl)-Substituted Pyrazoles

One-Pot Synthesis of CF3-Substituted Pyrazolines/Pyrazoles from Electron-Deficient Alkenes/Alkynes and CF3CHN2Generated in situ: Optimized Synthesis of Tris(trifluoromethyl)pyrazole

(2014) Evgeniy Y. Slobodyanyuk et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective One-Step Synthesis of Pyrazoles from Alkynes and N-Tosylhydrazones: [3+2] Dipolar Cycloaddition/[1,5] Sigmatropic Rearrangement Cascade

(2013) M. Carmen Pérez-Aguilar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

A New Life for an Old Reagent: Fluoroalkyl Amino Reagents as Efficient Tools for the Synthesis of Diversely Fluorinated Pyrazoles

(2013) Sergiy Pazenok et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 4-Fluoromethylsydnones and their Participation in Alkyne Cycloaddition Reactions

(2013) Robert S. Foster et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkylation and Ring Opening of Perfluoroalkyl- and Perfluoroaryl-Substituted 2-Siloxycyclopropanecarboxylates Yielding Fluorinated γ-Oxo Esters or β,γ-Unsaturated Ketones

(2013) Hans-Ulrich Reissig et al.   SYNTHESIS-STUTTGART

Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations

(2013) Guosheng Liu et al.   SYNTHESIS-STUTTGART

Synthesis of Perfluoroalkyl-Substitutedγ-Lactones and 4,5-Dihydropyridazin-3(2H)-onesviaDonorAcceptor Cyclopropanes

(2012) Daniel Gladow et al.   HELVETICA CHIMICA ACTA

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Taming of Fluoroform: Direct Nucleophilic Trifluoromethylation of Si, B, S, and C Centers

(2012) G. K. S. Prakash et al.   SCIENCE

From 2000 to Mid-2010: A Fruitful Decade for the Synthesis of Pyrazoles

(2011) Santos Fustero et al.   CHEMICAL REVIEWS

Recent developments of cyclopropene chemistry

(2011) Zhi-Bin Zhu et al.   CHEMICAL SOCIETY REVIEWS

Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds

(2011) Victoria N. Tsupreva et al.   INORGANIC CHEMISTRY

Synthesis of 3-Amino-4-fluoropyrazoles

(2011) Riccardo Surmont et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Selective Synthesis of Pyrazole and Spiropyrazoline Phosphonates via Base-Assisted Reaction of the Bestmann–Ohira Reagent with Enones

(2011) Deepti Verma et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Substituted Pyrazoles via Tandem Cross-Coupling/Electrocyclization of Enol Triflates and Diazoacetates

(2011) David J. Babinski et al.   JOURNAL OF ORGANIC CHEMISTRY

“Reported, but Still Unknown.” A Closer Look into 3,4-Bis- and 3,4,5-Tris(trifluoromethyl)pyrazoles

(2011) Igor I. Gerus et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Aminolysis of β-Carbonyl 1,3-Dithianes: Synthesis of Stereodefined β-Enaminones and 3,4-Disubstituted Pyrazoles

(2011) Yeming Wang et al.   ORGANIC LETTERS

Three-Component Reaction Using the Bestmann-Ohira Reagent: A Regioselective Synthesis of Phosphonyl Pyrazole Rings

(2010) Kishor Mohanan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination Versatility of Pyrazole-Based Ligands towards High-Nuclearity Transition-Metal and Rare-Earth Clusters

(2010) Marta Viciano-Chumillas et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Fluorine in health care: Organofluorine containing blockbuster drugs

(2010) David O’Hagan   JOURNAL OF FLUORINE CHEMISTRY

Polyfluorinated ligand-supported organometallic complexes of copper, silver, and gold

(2010) H. V. Rasika Dias   PURE AND APPLIED CHEMISTRY

Heteroaromatic annulation studies on 2-[bis(methylthio)methylene]-1,3-indanedione: efficient routes to indenofused heterocycles

(2010) Rajiv K. Verma et al.   TETRAHEDRON

One-pot copper-catalyzed synthesis of N-functionalized pyrazoles from boronic acids

(2010) Ramsay E. Beveridge et al.   TETRAHEDRON LETTERS

Pyrazole NNRTIs 4: Selection of UK-453,061 (lersivirine) as a Development Candidate

(2009) Charles E. Mowbray et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Efficient Routes to Pyrazolo[3,4-b]indoles and Pyrazolo[1,5-a]benzimidazoles via Palladium- and Copper-Catalyzed Intramolecular C−C and C−N Bond Formation†

(2009) Sarvesh Kumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkyne [3 + 2] Cycloadditions of Iodosydnones Toward Functionalized 1,3,5-Trisubstituted Pyrazoles

(2009) Duncan L. Browne et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in the Synthesis of Pyrazoles. A Review

(2009) Santos Fustero et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

Nano-organocatalyst: magnetically retrievable ferrite-anchored glutathione for microwave-assisted Paal–Knorr reaction, aza-Michael addition, and pyrazole synthesis

(2009) Vivek Polshettiwar et al.   TETRAHEDRON

Synthesis of pyrazoles through catalyst-free cycloaddition of diazo compounds to alkynes

(2008) Daniela Vuluga et al.   GREEN CHEMISTRY

Identification ofN-(4-Piperidinyl)-4-(2,6-dichlorobenzoylamino)-1H-pyrazole-3-carboxamide (AT7519), a Novel Cyclin Dependent Kinase Inhibitor Using Fragment-Based X-Ray Crystallography and Structure Based Drug Design†

(2008) Paul G. Wyatt et al.   JOURNAL OF MEDICINAL CHEMISTRY

Base-Mediated Reaction of Hydrazones and Nitroolefins with a Reversed Regioselectivity:  A Novel Synthesis of 1,3,4-Trisubstituted Pyrazoles

(2008) Xiaohu Deng et al.   ORGANIC LETTERS

One-pot three-component synthesis of pyrazoles through a tandem coupling-cyclocondensation sequence

(2008) Hai-Ling Liu et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS