A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
出版年份 2018 全文链接
标题
A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
作者
关键词
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出版物
CHEMICAL SOCIETY REVIEWS
Volume 47, Issue 17, Pages 6603-6743
出版商
Royal Society of Chemistry (RSC)
发表日期
2018-07-23
DOI
10.1039/c8cs00201k
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- Rh(I)-Catalyzed Alkylation of ortho-C–H Bonds in Aromatic Amides with Maleimides
- (2017) Qiyuan He et al. ORGANIC LETTERS
- Ir(III)-Catalyzed Direct C–H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis
- (2017) Zhong Liu et al. ORGANIC LETTERS
- An Approach to 3-(Indol-2-yl)succinimide Derivatives by Manganese-Catalyzed C–H Activation
- (2017) Shuang-Liang Liu et al. ORGANIC LETTERS
- Iron-Catalyzed ortho-Selective C–H Borylation of 2-Phenylpyridines and Their Analogs
- (2017) Yusuke Yoshigoe et al. ORGANIC LETTERS
- Cobalt-Catalyzed Intramolecular Oxidative C(sp3)–H/N–H Carbonylation of Aliphatic Amides
- (2017) Li Zeng et al. ORGANIC LETTERS
- Directed Aromatic C–H Activation/Acetoxylation Catalyzed by Pd Nanoparticles Supported on Graphene Oxide
- (2017) Yi Zhang et al. ORGANIC LETTERS
- Copper- or Nickel-Enabled Oxidative Cross-Coupling of Unreactive C(sp3)–H Bonds with Azole C(sp2)–H Bonds: Rapid Access to β-Azolyl Propanoic Acid Derivatives
- (2017) Guangying Tan et al. ORGANIC LETTERS
- A C–H Activation-Based Strategy for N-Amino Azaheterocycle Synthesis
- (2017) Pengfei Shi et al. ORGANIC LETTERS
- Copper-Mediated Annulation of Phosphorus-Containing Arenes with Alkynes: An Approach to Phosphindolium Salts
- (2017) Qingmei Ge et al. ORGANIC LETTERS
- Transformable Sulfoximine Assisted One-Pot Double Annulation of Vinylic C–H Bonds with Unactivated Alkynes
- (2017) Majji Shankar et al. ORGANIC LETTERS
- Synthesis of Benzoquinolizinium Salts by Rh(III)-Catalyzed Cascade Double N-Annulation Reactions of Allylamines, Diarylacetylenes, and HBF4
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- Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C–H Allylation of (Hetero)Arenes with Methyleneoxetanones
- (2017) Jintao Xia et al. ORGANIC LETTERS
- Nickel-Catalyzed Stereoselective Alkenylation of C(sp3)–H Bonds with Terminal Alkynes
- (2017) Cong Lin et al. ORGANIC LETTERS
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- (2017) Keshav Raghuvanshi et al. ORGANIC LETTERS
- Rhodium(III)-Catalyzed C–H Activation/Heterocyclization as a Macrocyclization Strategy. Synthesis of Macrocyclic Pyridones
- (2017) Jean-Philippe Krieger et al. ORGANIC LETTERS
- Selective C(sp2)–H Halogenation of “Click” 4-Aryl-1,2,3-triazoles
- (2017) Asier Goitia et al. ORGANIC LETTERS
- Synthesis of Spiro-dihydroquinoline and Octahydrophenanthrene Derivatives via Palladium-Catalyzed Intramolecular Oxidative Arylation
- (2017) Zhong-Lin Zang et al. ORGANIC LETTERS
- Pd-Catalyzed Diastereoselective Trifluoromethylthiolation of Functionalized Acrylamides
- (2017) Qun Zhao et al. ORGANIC LETTERS
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- (2017) Malay Sen et al. ORGANIC LETTERS
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- (2017) Ningning Lv et al. ORGANIC LETTERS
- Cobalt(III)-Catalyzed Oxadiazole-Directed C–H Activation for the Synthesis of 1-Aminoisoquinolines
- (2017) Fan Yang et al. ORGANIC LETTERS
- Nickel-Catalyzed Amination of Aryl 2-Pyridyl Ethers via Cleavage of the Carbon–Oxygen Bond
- (2017) Jing Li et al. ORGANIC LETTERS
- Cobalt-Catalyzed Oxidative Cyclization of Benzamides with Maleimides: Synthesis of Isoindolone Spirosuccinimides
- (2017) Ramasamy Manoharan et al. ORGANIC LETTERS
- Quaternary Ammonium Salts as Alkylating Reagents in C–H Activation Chemistry
- (2017) Manuel Spettel et al. ORGANIC LETTERS
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- (2017) Shuyou Chen et al. ORGANIC LETTERS
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- (2017) Xinwei Hu et al. ORGANIC LETTERS
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- (2017) Jintao Xia et al. ORGANIC LETTERS
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- (2017) Bingxian Liu et al. ORGANIC LETTERS
- Co(III)-Catalyzed Enaminone-Directed C–H Amidation for Quinolone Synthesis
- (2017) Pengfei Shi et al. ORGANIC LETTERS
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- (2017) Keke Meng et al. ORGANIC LETTERS
- Some Items of Interest to Process R&D Chemists and Engineers
- (2017) Robert Ely et al. ORGANIC PROCESS RESEARCH & DEVELOPMENT
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- (2017) Atanu Modak et al. ORGANOMETALLICS
- Cp*RhIII-Catalyzed C–H Amidation of Ferrocenes
- (2017) Shao-Bo Wang et al. ORGANOMETALLICS
- Facile synthesis of novel [1,3]oxazino[2,3-c][1,2,4] thiadiazin-12-one derivatives
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- Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation
- (2017) Qing-Feng Wu et al. SCIENCE
- Cobalt-Catalyzed Monoselective ortho-C–H Ethylation of Carboxamides with Triethylaluminum
- (2017) Kun Xu et al. SYNTHESIS-STUTTGART
- Palladium-catalyzed regio- and chemoselective direct desulfitative arylation of anilides with arylsulfonyl chlorides
- (2017) Ebrahim Kianmehr et al. TETRAHEDRON
- An efficient synthesis of iminoisoindolione derivatives by cobalt-catalyzed oxidative isocyanide insertion
- (2017) Feihua Zou et al. TETRAHEDRON
- Copper(II)-mediated intermolecular amination of inert C(sp3)H bonds with simple alkylamines to construct α,α-disubstituted β-amino acid derivatives
- (2017) Chunxia Wang et al. TETRAHEDRON LETTERS
- Cobalt catalyzed carbonylation of unactivated C(sp3)–H bonds
- (2017) Nagaraju Barsu et al. Chemical Science
- The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C–H bonds
- (2017) Kirsten F. Hogg et al. Chemical Science
- Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
- (2017) Patrick Williamson et al. Chemical Science
- Pivalophenone imine as a benzonitrile surrogate for directed C–H bond functionalization
- (2017) Wengang Xu et al. Chemical Science
- A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights
- (2017) Laura Rubio-Pérez et al. Chemical Science
- Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation
- (2017) Qingquan Lu et al. Chemical Science
- Ligand-assisted palladium-catalyzed C–H alkenylation of aliphatic amines for the synthesis of functionalized pyrrolidines
- (2017) Chuan He et al. Chemical Science
- Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
- (2017) Yan Zhu et al. Nature Communications
- Cobalt-Catalyzed Oxidative C–H/N–H Cross-Coupling: Selective and Facile Access to Triarylamines
- (2017) Cong Du et al. ACS Catalysis
- Highly Efficient and Divergent Construction of Chiral γ-Phosphono-α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated C(sp3)–H Bonds
- (2017) Qiang Yang et al. ACS Catalysis
- Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C–H Activation: Efficient Access to α-gem-Vinylindoles
- (2017) Xukai Zhou et al. ACS Catalysis
- C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations
- (2017) Daniel Zell et al. ACS Catalysis
- N–O Bond as External Oxidant in Group 9 Cp*M(III)-Catalyzed Oxidative C–H Coupling Reactions
- (2017) Xu-Ge Liu et al. ACS Catalysis
- Ruthenium-Catalyzed Direct Hydroxymethylation of Aryl C–H Bonds
- (2017) Yunxiang Wu et al. ACS Catalysis
- Experimental and Computational Studies on Remote γ-C(sp3)–H Silylation and Germanylation of Aliphatic Carboxamides
- (2017) Arghya Deb et al. ACS Catalysis
- Palladium-Catalyzed Direct Intermolecular Amination of Unactivated Methylene C(sp3)–H Bonds with Azodiformates via Bidentate-Chelation Assistance
- (2017) He-Yuan Bai et al. ACS Catalysis
- Site-Selective C–H/C–N Activation by Cooperative Catalysis: Primary Amides as Arylating Reagents in Directed C–H Arylation
- (2017) Guangrong Meng et al. ACS Catalysis
- Palladium-Catalyzed β-C–H Arylation of Alkyl Carboxamides with Sterically Hindered Aryl Iodides Using ortho-Sulfinyl Aniline Auxiliaries
- (2017) Delong Mu et al. ACS Catalysis
- Direct Catalytic Alcoholysis of Unactivated 8-Aminoquinoline Amides
- (2017) Toru Deguchi et al. ACS Catalysis
- Expedient C–H Chalcogenation of Indolines and Indoles by Positional-Selective Copper Catalysis
- (2017) Parthasarathy Gandeepan et al. ACS Catalysis
- Merger of Visible-Light Photoredox Catalysis and C–H Activation for the Room-Temperature C-2 Acylation of Indoles in Batch and Flow
- (2017) Upendra K. Sharma et al. ACS Catalysis
- Recent Advances in Catalytic C(sp2)–H Allylation Reactions
- (2017) Neeraj Kumar Mishra et al. ACS Catalysis
- Rh(iii)-catalyzed sequential C–H activation and annulation: access to N-fused heterocycles from arylazoles and α-diazocarbonyl compounds
- (2017) Jiyang Jie et al. RSC Advances
- Regioselective C–H chlorination: towards the sequential difunctionalization of phenol derivatives and late-stage chlorination of bioactive compounds
- (2017) Chao Gao et al. RSC Advances
- Direct C-2 acylation of indoles with toluene derivatives via Pd(ii)-catalyzed C–H activation
- (2017) Yaping Zhao et al. RSC Advances
- Cu(TFA)2 -Catalyzed Picolinamido-Directed C(sp2 )−H Cyanation of Naphthalenes by Using Benzoyl Cyanide as a Cyano Source
- (2017) He Song et al. Asian Journal of Organic Chemistry
- Mild C(sp3)−H Alkylation of 8-Methylquinolines with α,β-Unsaturated Carbonyl Compounds by Rhodium(III) Catalysis
- (2017) Shengnan Han et al. Asian Journal of Organic Chemistry
- Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation
- (2017) Wenbo Ma et al. Organic Chemistry Frontiers
- Site-selective Cp*Rh(iii)-catalyzed C–H amination of indolines with anthranils
- (2017) Neeraj Kumar Mishra et al. Organic Chemistry Frontiers
- Rh(iii)-Catalyzed direct C-7 amination of indolines with anthranils
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- Pd-catalyzed selective N(3)-ortho C–H arylation of 1,4-disubstituted 1,2,3-triazoles
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- Facile synthesis of 1-aminoindoles via Rh(iii)-catalysed intramolecular three-component annulation
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- 1,2,3-Triazole-assisted C–H amidation by cobalt(iii) catalysis
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- One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization
- (2017) Hui Chen et al. Organic Chemistry Frontiers
- Palladium-catalyzed β-selective C(sp2)–H carboxamidation of enamides by isocyanide insertion: synthesis of N-acyl enamine amides
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- Hexafluoroisopropanol as a highly versatile solvent
- (2017) Ignacio Colomer et al. Nature Reviews Chemistry
- Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation
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- A First Example of Cobalt-Catalyzed Remote CH Functionalization of 8-Aminoquinolines Operating through a Single Electron Transfer Mechanism
- (2016) Christopher J. Whiteoak et al. ADVANCED SYNTHESIS & CATALYSIS
- Synthesis of [60]Fullerene-Fused TetralonesviaPalladium- Catalyzed Ketone-Directedsp2CH Activation andsp3CH Functionalization
- (2016) Dian-Bing Zhou et al. ADVANCED SYNTHESIS & CATALYSIS
- Cobalt-Catalyzed, Imine-Directed Olefin Hydroarylation under Grignard-Free Conditions
- (2016) Wengang Xu et al. ADVANCED SYNTHESIS & CATALYSIS
- Copper-Mediated Tandem C(sp2)-H Sulfenylation and Annulation of Arenes with 2-Mercaptoimidazoles: Regio- and Site-selective Access to Polycyclic Fused Imidazo[2,1-b][1,3]thiazinones
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- Ligand-Assisted Palladium(II)/(IV) Oxidation forsp3CH Fluorination
- (2016) Huan Sun et al. ADVANCED SYNTHESIS & CATALYSIS
- (Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed Oxidative [4+2] Annulation of NH Imines with Alkynes: Straightforward Synthesis of Multisubstituted Isoquinolines
- (2016) Shang-Shi Zhang et al. ADVANCED SYNTHESIS & CATALYSIS
- Multiple Roles of the Pyrimidyl Group in the Rhodium-Catalyzed Regioselective Synthesis and Functionalization of Indole-3-carboxylic Acid Esters
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- Palladium-Catalyzed CH Functionalization of Ferrocenecarboxylic Acid by using 8-Aminoquinoline as a Removable Directing Group
- (2016) Moh. Sattar et al. ADVANCED SYNTHESIS & CATALYSIS
- Easy Access to 1-Amino and 1-Carbon Substituted Isoquinolines via Cobalt-Catalyzed CH/NO Bond Activation
- (2016) Krishnamoorthy Muralirajan et al. ADVANCED SYNTHESIS & CATALYSIS
- Nickel-Catalyzed Borylation of Aryl and Benzyl 2-Pyridyl Ethers: A Method for Converting a Robust ortho -Directing Group
- (2016) Mamoru Tobisu et al. ADVANCED SYNTHESIS & CATALYSIS
- Copper-Mediatedortho-Arylation of Benzamides with Arylboronic Acid
- (2016) Qingwen Gui et al. ADVANCED SYNTHESIS & CATALYSIS
- Acylperoxycoumarins asortho-CH Acylating Agentviaa Palladium(II)-Catalyzed Redox-Neutral Process
- (2016) Prakash Ranjan Mohanta et al. ADVANCED SYNTHESIS & CATALYSIS
- Directing Group-Assisted Copper(II)-Catalyzedortho-Carbonylation to Benzamide using 2,2′-Azobisisobutyronitrile (AIBN)
- (2016) Bhuttu Khan et al. ADVANCED SYNTHESIS & CATALYSIS
- CH Bond Arylation of Diamondoids Catalyzed by Palladium(II) Acetate
- (2016) Marta Larrosa et al. ADVANCED SYNTHESIS & CATALYSIS
- Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes
- (2016) Krishnamoorthy Muralirajan et al. ADVANCED SYNTHESIS & CATALYSIS
- Cobalt-Catalyzed C−H Functionalizations by Imidate Assistance with Aryl and Alkyl Chlorides
- (2016) Ruhuai Mei et al. ADVANCED SYNTHESIS & CATALYSIS
- Rhodium(III)-Catalyzed Synthesis of Indole Derivatives From Pyrimidyl-Substituted Anilines and Diazo Compounds
- (2016) Ke Yu et al. ADVANCED SYNTHESIS & CATALYSIS
- Copper-Catalyzed Remote C−H Amination of Quinolines withN-Fluorobenzenesulfonimide
- (2016) Yao Yin et al. ADVANCED SYNTHESIS & CATALYSIS
- High-Valent Pentamethylcyclopentadienylcobalt(III) or -iridium(III)-Catalyzed CH Annulation with Alkynes: Synthesis of Heterocyclic Quaternary Ammonium Salts
- (2016) Ye-Xing Lao et al. ADVANCED SYNTHESIS & CATALYSIS
- Palladium-Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source
- (2016) Zechao Wang et al. ADVANCED SYNTHESIS & CATALYSIS
- Rhodium-Catalyzed Tandem Annulation Reactions of 7-Azaindoles with Electron-Deficient OlefinsviaDouble CH Activation
- (2016) Shuai-Shuai Li et al. ADVANCED SYNTHESIS & CATALYSIS
- Directortho-Trifluoroethylation of Aromatic Ureas by Palladium Catalyzed C-H activation: A Missing Piece of Aromatic Substitutions
- (2016) Szabolcs Kovács et al. ADVANCED SYNTHESIS & CATALYSIS
- Iridium(III)-Catalyzed Direct CH Sulfonamidation of 2-Aryl-1,2,3-triazoleN-Oxides with Sulfonyl Azides
- (2016) Bingfeng Zhu et al. ADVANCED SYNTHESIS & CATALYSIS
- Nickel(II)-Mediated Regioselective CH Monoiodination of Arenes and Heteroarenes by using Molecular Iodine
- (2016) Bhuttu Khan et al. ADVANCED SYNTHESIS & CATALYSIS
- Rhodium-Catalyzed Regioselective Synthesis of Isoindolium Salts from 2-Arylpyridines and Alkenes in Aqueous Medium under Oxygen
- (2016) Nitinkumar Satyadev Upadhyay et al. ADVANCED SYNTHESIS & CATALYSIS
- Mild C−H/C−C Activation by Z -Selective Cobalt Catalysis
- (2016) Daniel Zell et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides
- (2016) Yang Sun et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cobalt-Catalyzed C−H Thiolation through Dehydrogenative Cross-Coupling
- (2016) Tobias Gensch et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cobalt(III)-Catalyzed Redox-Neutral Synthesis of Unprotected Indoles Featuring an N−N Bond Cleavage
- (2016) Andreas Lerchen et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Lewis Acid-Base Interaction-Controlled ortho -Selective C−H Borylation of Aryl Sulfides
- (2016) Hong Liang Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium-Catalyzed DirectedparaC−H Functionalization of Phenols
- (2016) Tuhin Patra et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Divergent and Stereoselective Synthesis of β-Silyl-α-Amino Acids through Palladium-Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds
- (2016) Yue-Jin Liu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks
- (2016) Alexander P. Pulis et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Regioselective C−H Hydroarylation of Internal Alkynes with Arenecarboxylates: Carboxylates as Deciduous Directing Groups
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- A Hydrazone-Based exo -Directing-Group Strategy for β C−H Oxidation of Aliphatic Amines
- (2016) Zhongxing Huang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enaminones as Synthons for a Directed C−H Functionalization: RhIII -Catalyzed Synthesis of Naphthalenes
- (2016) Shuguang Zhou et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Mixed Directing-Group Strategy: Oxidative C−H/C−H Bond Arylation of Unactivated Arenes by Cobalt Catalysis
- (2016) Cong Du et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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- (2016) Koushik Ghosh et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cooperative Lewis Acid/Cp*CoIIICatalyzed C−H Bond Activation for the Synthesis of Isoquinolin-3-ones
- (2016) Ju Hyun Kim et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cobalt-Catalyzed Oxidative Annulation of Nitrogen-Containing Arenes with Alkynes: An Atom-Economical Route to Heterocyclic Quaternary Ammonium Salts
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- A Simple and Versatile Amide Directing Group for C−H Functionalizations
- (2016) Ru-Yi Zhu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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- (2016) Bo Su et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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- (2016) Qing-Wei Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Overcoming the Limitations of C−H Activation with Strongly Coordinating N-Heterocycles by Cobalt Catalysis
- (2016) Hui Wang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds
- (2016) Taegyo Lee et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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- (2016) Xiaochao Shi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Ruthenium(II)-Catalyzed Decarboxylative C−H Activation: Versatile Routes tometa-Alkenylated Arenes
- (2016) N. Y. Phani Kumar et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Diastereoselective [3+2] Annulation of Aromatic/Vinylic Amides with Bicyclic Alkenes through Cobalt-Catalyzed C−H Activation and Intramolecular Nucleophilic Addition
- (2016) Parthasarathy Gandeepan et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Palladium(II)-Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups
- (2016) Kiho Kim et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- ortho -C−H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium
- (2016) Agostino Biafora et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Nitrone Directing Groups in Rhodium(III)-Catalyzed C−H Activation of Arenes: 1,3-Dipoles versus Traceless Directing Groups
- (2016) Fang Xie et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Mild and Efficient Palladium-Catalyzed Direct Trifluoroethylation of Aromatic Systems by C−H Activation
- (2016) Balázs L. Tóth et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C−H Bond Addition Cascade
- (2016) Jeffrey A. Boerth et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- N−H Imine as a Powerful Directing Group for Cobalt-Catalyzed Olefin Hydroarylation
- (2016) Wengang Xu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A General Strategy for the Nickel-Catalyzed C−H Alkylation of Anilines
- (2016) Zhixiong Ruan et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)−H and C(sp2)−H under Rhodium(III) Catalysis
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- Cationic Pd(II)-catalyzed C–H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies
- (2016) Takashi Nishikata et al. Beilstein Journal of Organic Chemistry
- Synthesis of β-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp3)–H arylation
- (2016) Yunyun Liu et al. Beilstein Journal of Organic Chemistry
- Palladium-Catalyzed Double C–H Functionalization of Arenes at the Positions ortho and meta to Their Directing Group: Concise Synthesis of Benzocyclobutenes
- (2016) Takeshi Nanjo et al. CHEMICAL & PHARMACEUTICAL BULLETIN
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- (2016) Jian Han et al. CHEMICAL COMMUNICATIONS
- Nickel-catalyzed ortho-halogenation of unactivated (hetero)aryl C–H bonds with lithium halides using a removable auxiliary
- (2016) Bei-Bei Zhan et al. CHEMICAL COMMUNICATIONS
- Cobalt-catalyzed C–H olefination of aromatics with unactivated alkenes
- (2016) Ramasamy Manoharan et al. CHEMICAL COMMUNICATIONS
- Remote meta C–H bond functionalization of 2-phenethylsulphonic acid and 3-phenylpropanoic acid derivatives
- (2016) Atanu Modak et al. CHEMICAL COMMUNICATIONS
- Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer
- (2016) Nagaraju Barsu et al. CHEMICAL COMMUNICATIONS
- Unprecedented copper-mediated oxidative demethylation of propionamides via bidentate-chelation assistance
- (2016) Jing-Hui Liu et al. CHEMICAL COMMUNICATIONS
- Cobalt(iii)-catalyzed alkenylation of arenes and 6-arylpurines with terminal alkynes: efficient access to functional dyes
- (2016) Shan Wang et al. CHEMICAL COMMUNICATIONS
- Copper(ii)-mediated regioselective N-arylation of pyrroles, indoles, pyrazoles and carbazole via dehydrogenative coupling
- (2016) Pradeep Sadhu et al. CHEMICAL COMMUNICATIONS
- Auxiliary-assisted palladium-catalyzed halogenation of unactivated C(sp3)–H bonds at room temperature
- (2016) Xinglin Yang et al. CHEMICAL COMMUNICATIONS
- Rh(iii)-catalyzed C–H activation reactions forming 1H-isoindoles containing a quaternary carbon center from aryl ketones or benzylamines
- (2016) Yeonhui Yi et al. CHEMICAL COMMUNICATIONS
- Rh-Catalyzed annulations of N-methoxybenzamides with ketenimines: synthesis of 3-aminoisoindolinones and 3-diarylmethyleneisoindolinones with strong aggregation induced emission properties
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- Cobalt(iii)-catalyzed annulation of esters and alkynes: a facile route to indenones
- (2016) Wenlong Yu et al. CHEMICAL COMMUNICATIONS
- Highly mono-selective ortho-trifluoromethylation of benzamides via 8-aminoquinoline assisted Cu-promoted C–H activations
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- Palladium-catalyzed direct intermolecular silylation of remote unactivated C(sp3)–H bonds
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- Diastereoselective Pd(II)-Catalyzed sp3 C–H Arylation Followed by Ring Opening of Cyclopropanecarboxamides: Construction of anti β-Acyloxy Carboxamide Derivatives
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- Synthesis of Succinimide-Containing Chromones, Naphthoquinones, and Xanthones under Rh(III) Catalysis: Evaluation of Anticancer Activity
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- 4-Amino-2,1,3-benzothiadiazole as a Removable Bidentate Directing Group for the Pd(II)-Catalyzed Arylation/Oxygenation of sp2/sp3 β-C–H Bonds of Carboxamides
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- Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids
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- Rh-Catalyzed, Regioselective, C–H Bond Functionalization: Access to Quinoline-Branched Amines and Dimers
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- Construction of Pyrrolo[1,2-a]indoles via Cobalt(III)-Catalyzed Enaminylation of 1-(Pyrimidin-2-yl)-1H-indoles with Ketenimines and Subsequent Base-Promoted Cyclization
- (2016) Xiaorong Zhou et al. ORGANIC LETTERS
- Ruthenium-Catalyzed Intermolecular Direct Silylation of Unreactive C(sp3)–H Bonds
- (2016) Wei Li et al. ORGANIC LETTERS
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- Cobalt-Catalyzed Monoselective Ortho-C–H Functionalization of Carboxamides with Organoaluminum Reagent
- (2016) Huiqiao Wang et al. ORGANIC LETTERS
- Sequential Regioselective C–H Functionalization of Thiophenes
- (2016) Matthew H. Daniels et al. ORGANIC LETTERS
- Pd-Catalyzed Dimethylation of Tyrosine-Derived Picolinamide for Synthesis of (S)-N-Boc-2,6-dimethyltyrosine and Its Analogues
- (2016) Xuning Wang et al. ORGANIC LETTERS
- Dicumyl Peroxide as a Methylating Reagent in the Ni-Catalyzed Methylation of Ortho C–H Bonds in Aromatic Amides
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- Direct ortho-Arylation of Pyridinecarboxylic Acids: Overcoming the Deactivating Effect of sp2-Nitrogen
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- Electronic Nature of Ketone Directing Group as a Key To Control C-2 vs C-4 Alkenylation of Indoles
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- Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides
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- Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides
- (2016) Yuto Unoh et al. ORGANIC LETTERS
- Rhodium(III)-Catalyzed Regio- and Stereoselective C–H Allylation of Arenes with Vinyl Benzoxazinanones
- (2016) Zisong Qi et al. ORGANIC LETTERS
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- (2016) Chunchen Yuan et al. ORGANIC LETTERS
- Rhodium(III)-Catalyzed Oxidative C–H/C–H Cross-Coupling of Heteroarenes and Masked Benzylamines
- (2016) Jundie Hu et al. ORGANIC LETTERS
- Palladium-Catalyzed Regioselective C8–H Amination of 1-Naphthylamine Derivatives with Aliphatic Amines
- (2016) Zexian Li et al. ORGANIC LETTERS
- Silver-Free Palladium-Catalyzed sp3 and sp2 C–H Alkynylation Promoted by a 1,2,3-Triazole Amine Directing Group
- (2016) Xiaohan Ye et al. ORGANIC LETTERS
- “One-Pot” Approach to 8-Acylated 2-Quinolinones via Palladium-Catalyzed Regioselective Acylation of Quinoline N-Oxides
- (2016) Xiaopei Chen et al. ORGANIC LETTERS
- Olefination of Electron-Deficient Alkenes with Allyl Acetate: Stereo- and Regioselective Access to (2Z,4E)-Dienamides
- (2016) Feifei Li et al. ORGANIC LETTERS
- Tandem Rh(III)-Catalyzed C–H Amination/Annulation Reactions: Synthesis of Indoloquinoline Derivatives in Water
- (2016) Liangliang Shi et al. ORGANIC LETTERS
- Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes
- (2016) Lingheng Kong et al. ORGANIC LETTERS
- Ru-Catalyzed One-Pot Diannulation of Heteroaryls: Direct Access to π-Conjugated Polycyclic Amides
- (2016) Majji Shankar et al. ORGANIC LETTERS
- A Versatile, Traceless C–H Activation-Based Approach for the Synthesis of Heterocycles
- (2016) Shuguang Zhou et al. ORGANIC LETTERS
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- (2016) Lin-Bao Zhang et al. ORGANIC LETTERS
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- (2016) Vinod G. Landge et al. ORGANIC LETTERS
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- (2016) Tyler J. Potter et al. ORGANIC LETTERS
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- (2016) Xiaoyang Wang et al. ORGANIC LETTERS
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- (2016) Aitziber Irastorza et al. ORGANIC LETTERS
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- (2016) Gangam Srikanth Kumar et al. ORGANIC LETTERS
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- (2016) Wataru Miura et al. ORGANIC LETTERS
- Synthesis of 1,2-Benzothiazines by a Rhodium-Catalyzed Domino C–H Activation/Cyclization/Elimination Process from S-Aryl Sulfoximines and Pyridotriazoles
- (2016) Woo Hyung Jeon et al. ORGANIC LETTERS
- Rh-Catalyzed N–O Bond Cleavage of Anthranil: A C–H Amination Reagent for Simultaneous Incorporation of Amine and a Functional Group
- (2016) Miancheng Zou et al. ORGANIC LETTERS
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- (2016) Govind Goroba Pawar et al. ORGANIC LETTERS
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- (2016) Youka Bunno et al. ORGANIC LETTERS
- Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp3)–H Bonds in Aliphatic Amides with Terminal Alkynes
- (2016) Fei-Xian Luo et al. ORGANOMETALLICS
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- (2016) Orsolya Tischler et al. ORGANOMETALLICS
- Rhodium-Catalyzed Oxidative Coupling of Benzoic Acids with Terminal Alkynes: An Efficient Access to 3-Ylidenephthalides
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- Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C–H Bonds
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- Mechanism of Ruthenium-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides: A Computational Study
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- Ligand-accelerated enantioselective methylene C(sp3)–H bond activation
- (2016) Gang Chen et al. SCIENCE
- A general catalytic β-C–H carbonylation of aliphatic amines to β-lactams
- (2016) Darren Willcox et al. SCIENCE
- 1,2,3-Triazole amine as directing group in promoting catalytic oxidative C–H olefination under aerobic conditions
- (2016) Xiaohan Ye et al. TETRAHEDRON
- Asymmetric C–H activation as a modern strategy towards expedient synthesis of steganone
- (2016) Quentin Dherbassy et al. TETRAHEDRON
- Synthesis of ortho-arylated/benzylated arylacetamide derivatives: Pd(OAc)2-catalyzed bidentate ligand-aided arylation and benzylation of the γ-CH bond of arylacetamides
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- Multicomponent reaction comprising one-pot installation of bidentate directing group and Pd(II)-catalyzed direct β-arylation of C(sp3)H bond of aliphatic and alicyclic carboxamides
- (2016) Sruthi Mohan et al. TETRAHEDRON
- Sodium chlorate as a viable substoichiometric oxidant for cobalt-catalyzed oxidative annulation of aryl sulfonamides with alkynes
- (2016) You Ran et al. TETRAHEDRON LETTERS
- Copper-catalyzed C5-regioselective C H sulfonylation of 8-aminoquinoline amides with aryl sulfonyl chlorides
- (2016) Jun-Ming Li et al. TETRAHEDRON LETTERS
- Recent advances in transition metal (Pd, Ni)-catalyzed C(sp 3 ) H bond activation with bidentate directing groups
- (2016) Xinglin Yang et al. TETRAHEDRON LETTERS
- A unified synthesis of cyclic ethers or lactones via Pd-catalyzed intramolecular O -functionalization of sp 3 C H bonds
- (2016) Haifeng Wang et al. TETRAHEDRON LETTERS
- Rhodium-catalyzed regioselective addition of the ortho C–H bond in aromatic amides to the C–C double bond in α,β-unsaturated γ-lactones and dihydrofurans
- (2016) Kaname Shibata et al. Chemical Science
- Directing group assisted meta-hydroxylation by C–H activation
- (2016) Arun Maji et al. Chemical Science
- Rh(iii)-catalyzed diastereoselective C–H bond addition/cyclization cascade of enone tethered aldehydes
- (2016) Jeffrey A. Boerth et al. Chemical Science
- The total synthesis of K-252c (staurosporinone) via a sequential C–H functionalisation strategy
- (2016) J. C. Fox et al. Chemical Science
- Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile
- (2016) Yongbing Liu et al. Chemical Science
- β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp)–H bonds using a palladium catalyst
- (2016) Jing Peng et al. Chemical Science
- Mechanism of the CuII-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen
- (2016) Hans Sterckx et al. Chemical Science
- Palladium(ii)-catalyzed synthesis of dibenzothiophene derivatives via the cleavage of carbon–sulfur and carbon–hydrogen bonds
- (2016) Mamoru Tobisu et al. Chemical Science
- Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
- (2016) Shangda Li et al. Nature Communications
- Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
- (2016) Gang Liao et al. Nature Communications
- Nickel-Catalyzed Reaction of C–H Bonds in Amides with I2: ortho-Iodination via the Cleavage of C(sp2)–H Bonds and Oxidative Cyclization to β-Lactams via the Cleavage of C(sp3)–H Bonds
- (2016) Yoshinori Aihara et al. ACS Catalysis
- Versatile Cp*Rh(III)-Catalyzed Selective Ortho-Chlorination of Arenes and Heteroarenes
- (2016) Fabian Lied et al. ACS Catalysis
- Ketone-Assisted Ruthenium(II)-Catalyzed C–H Imidation: Access to Primary Aminoketones by Weak Coordination
- (2016) Keshav Raghuvanshi et al. ACS Catalysis
- Rh(I)/NHC*-Catalyzed Site- and Enantioselective Functionalization of C(sp3)–H Bonds Toward Chiral Triarylmethanes
- (2016) Ju Hyun Kim et al. ACS Catalysis
- Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C–H Activation and Intramolecular Nucleophilic Addition
- (2016) Ramajayam Kuppusamy et al. ACS Catalysis
- Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles
- (2016) Qingquan Lu et al. ACS Catalysis
- Aerobic Direct C(sp2)-H Hydroxylation of 2-Arylpyridines by Palladium Catalysis Induced with Aldehyde Auto-Oxidation
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- Unified Strategy for Nickel-Catalyzed C-2 Alkylation of Indoles through Chelation Assistance
- (2016) Vineeta Soni et al. ACS Catalysis
- Nickel-Catalyzed C–H Alkynylation of Anilines: Expedient Access to Functionalized Indoles and Purine Nucleobases
- (2016) Zhixiong Ruan et al. ACS Catalysis
- Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins
- (2016) Soham Maity et al. ACS Catalysis
- Metal and Metal Oxide Nanoparticles: A Lever for C–H Functionalization
- (2016) Daniel Pla et al. ACS Catalysis
- Remote Functionalization: Palladium-Catalyzed C5(sp3)-H Arylation of 1-Boc-3-aminopiperidine through the Use of a Bidentate Directing Group
- (2016) Ben F. Van Steijvoort et al. ACS Catalysis
- Iron/Zinc-Co-catalyzed Directed Arylation and Alkenylation of C(sp3)–H Bonds with Organoborates
- (2016) Laurean Ilies et al. ACS Catalysis
- Diverting C–H Annulation Pathways: Nickel-Catalyzed Dehydrogenative Homologation of Aromatic Amides
- (2016) Zhiqi He et al. ACS Catalysis
- Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C–H/N–O Functionalization with Nitrones
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- Fast and Selective Dehydrogenative C–H/C–H Arylation Using Mechanochemistry
- (2016) Shao-Jie Lou et al. ACS Catalysis
- Cp*Co(III)-Catalyzed C(sp3)–H Bond Activation: A Highly Stereoselective and Regioselective Alkenylation of 8-Methylquinoline with Alkynes
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- Mild Acylation of C(sp3)–H and C(sp2)–H Bonds under Redox-Neutral Rh(III) Catalysis
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- Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis
- (2016) Ruhuai Mei et al. ACS Catalysis
- Chelation-Assisted Rhodium-Catalyzed Direct Amidation with Amidobenziodoxolones: C(sp2)–H, C(sp3)–H, and Late-Stage Functionalizations
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- Manganese-Catalyzed C–H Activation
- (2016) Weiping Liu et al. ACS Catalysis
- Nickel-catalyzed direct alkynylation of C(sp2)–H bonds of amides: an “inverse Sonogashira strategy” to ortho-alkynylbenzoic acids
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- Palladium-Catalyzed C(sp3 )−H Functionalization at the C3 Position of l -Pipecolinic Acid Derivatives
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- Cobalt-Catalyzed Oxidative Dimerization of 2-Phenylpyridine Derivatives
- (2016) Yanli Xie et al. Asian Journal of Organic Chemistry
- Pd-Catalyzed Late-Stage Monoacetoxylation and Monoiodination of 4-Alkyl-1,5-diaryl-1 H -pyrazole-3-carboxylates via Direct Csp2 −H Bond Activation
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- Selective Mono- and Di-C(aryl)−H Sulfenylation of Benzamides by One-Pot Assembly of 8-Aminoquinoline, Benzoyl chlorides, and Thiophenols
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- Pd(ii)-catalyzed direct functionalization of C–H bonds of benzamides for synthesis of 1,1-difluoro-1-alkenes
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- Palladium-catalyzed C(sp3)–H arylation of lactic acid: efficient synthesis of chiral β-aryl-α-hydroxy acids
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- Rhenium and base co-catalyzed [3 + 2] annulations of N–H ketimines and alkynes to access unprotected tertiary indenamines through C–H bond activation
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- Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides
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- Iridium(iii)- and rhodium(iii)-catalyzed coupling of anilines with α-diazoesters via chelation-assisted C–H activation
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- Nickel(ii)-catalyzed direct arylation of aryl C–H bonds with aryl-boron reagents directed by a removable bidentate auxiliary
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- Palladium-catalyzed arylation of β-methylene C(sp3)–H bonds at room temperature: desymmetrization of simple cycloalkyl carboxylic acids
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- Ru-Catalyzed selective C–H oxidative olefination with N-heteroarenes directed by pivaloyl amide
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- Copper-catalyzed 8-amido chelation-induced regioselective C–H fluoroalkylation of quinolines
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- A remarkable solvent effect of fluorinated alcohols on transition metal catalysed C–H functionalizations
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- Cp*Co(iii)-catalyzed, N–N bond-based redox-neutral synthesis of isoquinolines
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- Cobalt(iii)-catalyzed efficient synthesis of indenones through carboannulation of benzoates and alkynes
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- Low-valent cobalt-catalyzed C–H allylation
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- Nickel-Catalyzed Aromatic C–H Functionalization
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- Palladium(II)-Promoted Directing Group-Enabled Regioselective C-H Arylation of The C-3 Position of 2- or 3-(Aminoalkyl)-Thiophene and Furfurylamine Derivatives
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- Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds
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- Manganese Catalyzed C–H Halogenation
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- Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations
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- Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes
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- Rhodium(III)-Catalyzed in situ Oxidizing Directing Group- Assisted CH Bond Activation and Olefination: A Route to 2-Vinylanilines
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- Rhodium(III)-Catalyzed Selective CH Cyanation of Indolines and Indoles with an Easily Accessible Cyano Source
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- Rhodium-Catalyzed Decarbonylative Direct Olefination of Arenes with Vinyl Carboxylic Acids
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- Iron-Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides
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- Copper(II)/Silver(I)-Catalyzed Sequential Alkynylation and Annulation of Aliphatic Amides with Alkynyl Carboxylic Acids: Efficient Synthesis of Pyrrolidones
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- Phosphaannulation of Aryl- and Benzylphosphonic Acids with Unactivated AlkenesviaPalladium-Catalyzed CH Activation/Oxidative Cyclization Reaction
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- Copper-Mediated Sulfonylation of Aryl C(sp2)H Bonds with Sodium and Lithium Sulfinates
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- Directortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide
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- Palladium-Catalysed CH Bond Electrophilic Fluorination of Highly Substituted Arylpyrazoles: Experimental and DFT Mechanistic Insights
- (2015) Christelle Testa et al. ADVANCED SYNTHESIS & CATALYSIS
- Rhodium(III)-Catalyzed Redox-Neutral CH Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives
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- Regioselective Access to Sultam Motifs through Cobalt-Catalyzed Annulation of Aryl Sulfonamides and Alkynes using an 8-Aminoquinoline Directing Group
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- Arylmethyl Chlorides: New Bifunctional Reagents for Palladium-Catalyzedortho-Chlorination and Acylation of 2-Arylpyridines
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- Copper(I)-Catalyzed Dehydrogenative Amidation of Arenes Using Air as the Oxidant
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- Cationic Rhodium(III)-Catalyzed Direct C-2 Carboxamidation of Indoles with IsocyanatesviaCH Bond Functionalization
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- Copper-Mediatedortho-Nitration of Arene and Heteroarene CH Bonds Assisted by an 8-Aminoquinoline Directing Group
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- Cobalt(II)-Catalyzed C sp 2H Alkynylation/Annulation with Terminal Alkynes: Selective Access to 3-Methyleneisoindolin-1-one
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- Rhodium-Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar-Chiral Metallocene Siloles
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- General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed CH Carboxylation
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- A General and Scalable Synthesis of Aeruginosin Marine Natural Products Based on Two Strategic C(sp3)H Activation Reactions
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- CH Alkenylations with Alkenyl Acetates, Phosphates, Carbonates, and Carbamates by Cobalt Catalysis at 23 °C
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- Orchestrated Triple CH Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles
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- Manganese-Catalyzed Direct Nucleophilic C(sp2)H Addition to Aldehydes and Nitriles
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- Strong Bonds Made Weak: Towards the General Utility of Amides as Synthetic Modules
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- Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes
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- Ligand-Promoted Borylation of C(sp3 )H Bonds with Palladium(II) Catalysts
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- Synthesis of Dibenzo[c,e]oxepin-5(7H)-ones from Benzyl Thioethers and Carboxylic Acids: Rhodium-Catalyzed Double CH Activation Controlled by Different Directing Groups
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- Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant
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- Cobalt(III)-Catalyzed Aryl and Alkenyl CH Aminocarbonylation with Isocyanates and Acyl Azides
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- Diaryliodoniums by Rhodium(III)-Catalyzed CH Activation: Mild Synthesis and Diversified Functionalizations
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- Cp*RhIII-Catalyzed Arylation of C(sp3)H Bonds
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- Selective Alkenylation and Hydroalkenylation of Enol Phosphates through Direct CH Functionalization
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- Ligand-Enabled Catalytic CH Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway
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- Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems
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- Rhodium(I)-Catalyzed Regiospecific Dimerization of Aromatic Acids: Two Direct CH Bond Activations in Water
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- Sodium Halides as Halogenating Reagents: Rhodium(III)-Catalyzed Versatile and Practical Halogenation of Aryl Compounds
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- (2014) Takanori Shibata et al. ADVANCED SYNTHESIS & CATALYSIS
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- Synthesis of Dibenzothiophenes by Pd-Catalyzed Dual CH Activation from Diaryl Sulfides
- (2014) Rui Che et al. CHEMISTRY-A EUROPEAN JOURNAL
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- A Convenient Synthesis ofN-Aryl Benzamides by Rhodium-Catalyzedortho-Amidation and Decarboxylation of Benzoic Acids
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- (2014) Andrew McNally et al. NATURE
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- (2014) David E. Stephens et al. ACS Catalysis
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- Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines
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- Eco-friendly solvents and amphiphilic catalytic polyoxometalate nanoparticles: a winning combination for olefin epoxidation
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- Pd(ii)-catalyzed alkoxylation of unactivated C(sp3)–H and C(sp2)–H bonds using a removable directing group: efficient synthesis of alkyl ethers
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- Thioethers as Directing Group for the Palladium-Catalyzed Direct Arylation of Arenes
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- Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol
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- (2011) Keary M. Engle et al. ACCOUNTS OF CHEMICAL RESEARCH
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- Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation
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- Silanol: A Traceless Directing Group for Pd-Catalyzedo-Alkenylation of Phenols
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- Ir(I)-Catalyzed Enantioselective Secondary sp3C–H Bond Activation of 2-(Alkylamino)pyridines with Alkenes
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- Iridium-Catalyzed AreneOrtho-Silylation by Formal Hydroxyl-Directed C−H Activation
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- Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles
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- Regioselectivity-Switchable Hydroarylation of Styrenes
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- Reactions between Grignard reagents and heterocyclic N-oxides: Stereoselective synthesis of substituted pyridines, piperidines, and piperazines
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- Synthesis of Unsymmetricalo-Biphenols ando-Binaphthols via Silicon-Tethered Pd-Catalyzed C−H Arylation
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- Palladium(II)-CatalyzedOrthoArylation of 2-Phenoxypyridines with Potassium Aryltrifluoroborates via C−H Functionalization
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- Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis
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- Mechanisms of C–H bond activation: rich synergy between computation and experiment
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- NMR studies of the products of hydrolysis of 3-ethyl-2-methylbenzo[d]azol-3-ium iodides
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- Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System
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- TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines
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- Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation
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- Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron- and Tin-Based Methods
- (2008) Scott E. Denmark et al. ACCOUNTS OF CHEMICAL RESEARCH
- Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery
- (2008) Young Jun Park et al. ACCOUNTS OF CHEMICAL RESEARCH
- Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C−H Functionalization and C−N Bond Formation
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- Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization
- (2008) Lopa V. Desai et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature
- (2008) James A. Jordan-Hore et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Silyl-Directed, Iridium-Catalyzedortho-Borylation of Arenes. A One-Potortho-Borylation of Phenols, Arylamines, and Alkylarenes
- (2008) Timothy A. Boebel et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions
- (2008) Robert J. Phipps et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Organic Solvent Nanofiltration and Adsorbents; A Hybrid Approach to Achieve Ultra Low Palladium Contamination of Post Coupling Reaction Products
- (2008) Christopher J. Pink et al. ORGANIC PROCESS RESEARCH & DEVELOPMENT
- Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components
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