“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects

Directed, Remote Gas-Phase CH and CC Bond Activations by Metal Oxide Cations Anchored to a Nitrile Group

(2011) Nicolas Dietl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphorescent Sensor for Robust Quantification of Copper(II) Ion

(2011) Youngmin You et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum(II)-Cyclometalated “Roll-over” Complexes with a Chiral Pinene-Derived 2,2′-Bipyridine

(2011) Antonio Zucca et al.   ORGANOMETALLICS

Thermal C−H Bond Activation of Benzene, Toluene, and Methane with Cationic [M(X)(bipy)]+(M = Ni, Pd, Pt; X = CH3, Cl; bipy = 2,2′-bipyridine): A Mechanistic Study

(2011) Burkhard Butschke et al.   ORGANOMETALLICS

Reactions of a Platinum(II) Agostic Complex: Decyclometalation, Dicyclometalation, and Solvent-Switchable Formation of a Rollover Complex

(2011) Sarah H. Crosby et al.   ORGANOMETALLICS

Nitrogen adduction by three coordinate group 10 organometallic cations: platinum is favoured over nickel and palladium

(2011) Matthew J. Woolley et al.   RAPID COMMUNICATIONS IN MASS SPECTROMETRY

[(E)-But-2-enoato-κO]chlorido(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)zinc(II) monohydrate

(2010) Mei Du et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Ion-Molecule Reactions of “Rollover” Cyclometalated [Pt(bipy−H)]+ (bipy=2,2′-bipyridine) with Dimethyl Ether in Comparison with Dimethyl Sulfide: An Experimental/Computational Study

(2010) Burkhard Butschke et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the gas-phase decomposition of acyclic ethers mediated by “rollover” cyclometalated [Pt(bipy−H)]+ (bipy=2,2′-bipyridine): A mechanistic study

(2010) Burkhard Butschke et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

On the Activation of Chloromethanes by Cyclometalated [Pt(bipy – H)]+ in the Gas Phase: A Mechanistic Study

(2010) Burkhard Butschke et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

Crystal Structures of Two Palladacycles from the C–H Activation of 2-(Thiophen-2-yl)pyridine

(2010) Samantha K. Callear et al.   JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

Synthesis, structural characterization and thermal properties of a new Cd(II) complex: As bithiazole precursor for preparation of CdS nanoparticles

(2010) Akram Hosseinian et al.   JOURNAL OF MOLECULAR STRUCTURE

Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents

(2010) Brian G. Hashiguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Study on the Gas-Phase Generation of “Rollover”-Cyclometalated [M(bipy − H)]+(M = Ni, Pd, Pt)†

(2010) Burkhard Butschke et al.   ORGANOMETALLICS

Intramolecular C(sp2)−H Bond Activation in 6,6′-Dimethoxy-2,2′-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N′,C(3) “Rollover” Cycloaurated Derivative

(2010) Fabio Cocco et al.   ORGANOMETALLICS

Creating Ligands with Multiple Personalities

(2010) R. H. Crabtree   SCIENCE

(2,2′-Dimethyl-4,4′-bi-1,3-thiazole-κ2N,N′)bis(thiocyanato-κS)mercury(II)

(2009) Nasser Safari et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Switchable Ambient-Temperature Singlet-Triplet Dual Emission in Nonconjugated Donor-Acceptor Triarylboron-PtIIComplexes

(2009) Zachary M. Hudson et al.   CHEMISTRY-A EUROPEAN JOURNAL

2,2′-Bipyrimidine as Efficient Sensitizer of the Solid-State Luminescence of Lanthanide and Uranyl Ions from Visible to Near-Infrared

(2009) Gaël Zucchi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclopalladated azido complexes containing C,N-donor (HC∼N = 2-(2′-thienyl)pyridine, azobenzene, 3,3′-dimethyl azobenzene, N,N′-dimethylbenzylamine, 2-phenylpyridine) ligands: reactivity towards organic unsaturated compounds and catalytic properties

(2009) Kyung-Eun Lee et al.   DALTON TRANSACTIONS

N^N^C platinum(II) and palladium(II) cyclometallates of 6,6′-diphenyl-2,2′-bipyridine, L: Crystal and molecular structure of [Pd(L–H)Cl]

(2009) Antonio Zucca et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Step by step palladium mediated syntheses of new 2-(pyridin-2-yl)-6-R-nicotinic acids and esters

(2009) Giacomo Luigi Petretto et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Large Effect of a Small Substitution: Competition of Dehydration with Charge Retention and Coulomb Explosion in Gaseous [(bipyR)Au(μ-O)2Au(bipyR)]2+Dications

(2009) Eric C. Tyo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalation of 2,2′-Bipyridine. Mono- and Dinuclear C,N Platinum(II) Derivatives

(2009) Antonio Zucca et al.   ORGANOMETALLICS

Cyclometalation of 6-Phenyl-2,2′-Bipyridine and Iridium: Synthesis, Characterization, and Reactivity Studies

(2009) Kenneth J. H. Young et al.   ORGANOMETALLICS

Versatile, Selective, and Switchable Coordination Modes of Pincer Click Ligands

(2009) Elaine M. Schuster et al.   ORGANOMETALLICS

Synthesis, DNA-binding and photocleavage studies of ruthenium(II) complexes [Ru(btz)3]2+ and [Ru(btz)(dppz)2]2+

(2009) HuiJuan Yu et al.   Science in China. Series B, Chemistry

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Branched-Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

(2008) Christian U. Grünanger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Roll-over” Cyclometalation of 2,2′-Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study

(2008) Burkhard Butschke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions: IX. A Series of Novel Polyoxotungstates Sandwiched by Octa-Copper Clusters

(2008) Jun-Wei Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Competitive Intramolecular Aryl- and Alkyl-CH Bond Activation and Ligand Evaporation from Gaseous Bisimino Complexes [Pt(L)(CH3)((CH3)2S)]+(L=C6H5NC(CH3)C(CH3)NC6H5)

(2008) Burkhard Butschke et al.   HELVETICA CHIMICA ACTA

Platinum(II)-mediated dehydrosulfurization and oxidative carbon–carbon coupling in the gas-phase decomposition of thioethers

(2008) Burkhard Butschke et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

C–H activation in bithiazole ring with thallium(III) ion

(2008) Behrouz Notash et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

N,C “Rollover” Cyclometalated Platinum(II) Hydrides: Mono- and Polynuclear Derivatives

(2008) Giovanni Minghetti et al.   ORGANOMETALLICS

Synthesis, characterization and crystal structure determination of zinc (II) and mercury (II) complexes with 2,2′-dimethyl-4,4′-bithiazole

(2008) Hamid Reza Khavasi et al.   POLYHEDRON

Remote C–H bond functionalization reveals the distance-dependent isotope effect

(2008) Jiao-Jie Li et al.   TETRAHEDRON