The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes

Exploration of New C−O Electrophiles in Cross-Coupling Reactions

(2010) Da-Gang Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Constructing Multiply Substituted Arenes Using Sequential Palladium(II)-Catalyzed CH Olefination

(2010) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Strategy Toward Aromatic 1,2-Ambiphilic Synthons: Palladium-Catalyzed ortho-Halogenation of PyDipSi-Arenes

(2010) Alexander S. Dudnik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd0/PR3-Catalyzed Arylation of Nicotinic and Isonicotinic Acid Derivatives

(2010) Masayuki Wasa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

(2010) Chang-Liang Sun et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Recent advances in the use of temporary silicon tethers in metal-mediated reactions

(2010) Sonia Bracegirdle et al.   CHEMICAL SOCIETY REVIEWS

PdII-Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N-(2-Pyridyl)sulfonyl Group: C2-Alkenylation and Dehydrogenative Homocoupling

(2010) Alfonso García-Rubia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Integrated Palladium-Catalyzed Arylation of Heavier Group 14 Hydrides

(2010) Aldes Lesbani  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes

(2010) Diego A. Alonso et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regiospecific Synthesis of Nitroarenes by Palladium-Catalyzed Nitrogen-Donor-Directed Aromatic CH Nitration

(2010) Yun-Kui Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds

(2010) Tomonari Ureshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Macrocyclization of Linear Peptides Enabled by Amphoteric Molecules

(2010) Ryan Hili et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands

(2010) Yi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyanation of Arenes via Iridium-Catalyzed Borylation

(2010) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2as an Oxidant

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-CatalyzedOrtho-Arylation ofO-Phenylcarbamates with Simple Arenes and Sodium Persulfate

(2010) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes

(2010) Natalia Chernyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Entry of Amination Reagents for Heteroaromatic C−H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature

(2010) Tsuyoshi Kawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic C−H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover

(2010) Alison N. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Drug Synthesis and Diversification via ortho-C−H Iodination using Recyclable PdI2as the Precatalyst

(2010) Tian-Sheng Mei et al.   ORGANIC LETTERS

Nickel-Catalyzed C−O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates

(2010) Gary A. Molander et al.   ORGANIC LETTERS

A Formal [4 + 4] Complementary Ambiphile Pairing Reaction: A New Cyclization Pathway forortho-Quinone Methides

(2010) Thiwanka B. Samarakoon et al.   ORGANIC LETTERS

Gold(III)-Catalyzed Halogenation of Aromatic Boronates withN-Halosuccinimides

(2010) Di Qiu et al.   ORGANIC LETTERS

Mild Silver(I)-Mediated Regioselective Iodination and Bromination of Arylboronic Acids

(2010) Raed M. Al-Zoubi et al.   ORGANIC LETTERS

Synthesis of Unsymmetricalo-Biphenols ando-Binaphthols via Silicon-Tethered Pd-Catalyzed C−H Arylation

(2010) Chunhui Huang et al.   ORGANIC LETTERS

Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation

(2010) Shun Hiroshima et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

(2010) Tetsuya Satoh et al.   SYNTHESIS-STUTTGART

Direct synthesis of ortho-dihalogenated arylpyrimidines using calcium halides as halogen sources

(2010) Xiaojian Zheng et al.   TETRAHEDRON LETTERS

Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate

(2010) Charles S. Yeung et al.   Chemical Science

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

C(aryl)O Activation of Aryl Carboxylates in Nickel-Catalyzed Biaryl Syntheses

(2009) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambiphilic allenes: synthesis and reactivity

(2009) David Tejedor et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular oxidative cross-coupling of arenes

(2009) James A. Ashenhurst   CHEMICAL SOCIETY REVIEWS

Ortho-Functionalization of 2-Phenoxypyrimidines via Palladium-Catalyzed C−H Bond Activation

(2009) Shaojin Gu et al.   JOURNAL OF ORGANIC CHEMISTRY

Chelation-Assisted Palladium-Catalyzed Cascade Bromination/Cyanation Reaction of 2-Arylpyridine and 1-Arylpyrazole C−H Bonds

(2009) Xiaofei Jia et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives

(2009) Shunsuke Furukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amphoteric Amino Aldehydes Reroute the Aza-Michael Reaction

(2009) Ryan Hili et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation

(2009) Fumitoshi Kakiuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki−Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

(2009) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N,N-DiethylO-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner

(2009) Aurora Antoft-Finch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Ni-Catalyzed Selective C−O Bond Activation in Cross-Coupling of Aryl Esters

(2009) Zhe Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Coupling of 2-[(2-Pyrrolyl)silyl]aryl Triflates through 1,2-Silicon Migration

(2009) Kenji Mochida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines

(2009) Chunhui Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C−O Bond Activation

(2009) Bi-Jie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2or Air

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

(2009) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

(2009) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate

(2009) Nicholas R. Deprez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Applications of Pd(II)-Catalyzed C−H Carboxylation and Mechanistic Insights: Expedient Routes to Anthranilic Acids, Oxazolinones, and Quinazolinones

(2009) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Phenol Esters

(2009) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

Synthesis of Benzo[b]siloles via KH-Promoted Cyclization of (2-Alkynylphenyl)silanes

(2009) Laurean Ilies et al.   ORGANIC LETTERS

Mechanistic Comparison between Pd-Catalyzed Ligand-Directed C−H Chlorination and C−H Acetoxylation

(2009) Kara J. Stowers et al.   ORGANIC LETTERS

Chelation-Assisted Palladium-Catalyzed Direct Cyanation of 2-Arylpyridine C−H Bonds

(2009) Xiaofei Jia et al.   ORGANIC LETTERS

Site-Selective Azaindole Arylation at the Azine and Azole Rings viaN-Oxide Activation

(2009) Malcolm P. Huestis et al.   ORGANIC LETTERS

Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C−H Bond Cleavages

(2009) Lutz Ackermann et al.   ORGANIC LETTERS

Palladium-Catalyzed Aryl C−H Bonds Activation/Acetoxylation Utilizing a Bidentate System

(2009) Fa-Rong Gou et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes

(2009) Mamoru Tobisu et al.   ORGANIC LETTERS

Pd-Catalyzed C−H Functionalizations ofO-Methyl Oximes with Arylboronic Acids

(2009) Chang-Liang Sun et al.   ORGANIC LETTERS

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron- and Tin-Based Methods

(2008) Scott E. Denmark et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Coupling of Aryl/Alkenyl Pivalates with Organozinc Reagents through Nickel-Catalyzed CO Bond Activation under Mild Reaction Conditions

(2008) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PdII‐Catalyzed MonoselectiveorthoHalogenation of CH Bonds Assisted by Counter Cations: A Complementary Method to Directedortho Lithiation

(2008) Tian‐Sheng Mei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Approach to Silicon-Bridged Biaryls: Palladium-Catalyzed Intramolecular Coupling of 2-(Arylsilyl)aryl Triflates

(2008) Masaki Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ortho-selective Arylation of Arylazoles with Aryl Bromides Catalyzed by Ruthenium Complexes

(2008) Shuichi Oi et al.   CHEMISTRY LETTERS

Palladium-Catalyzed Silylation of Electron-Deficient Aryl Iodides Using Triorganosilane in the Presence of Pyridine and LiCl

(2008) Muneaki Iizuka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct and Selective Arylation of Tertiary Silanes with Rhodium Catalyst

(2008) Yoshinori Yamanoi et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Ortho-Acetoxylation of Anilides via Palladium-Catalyzed sp2C−H Bond Oxidative Activation

(2008) Guan-Wu Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Regiospecific One-Pot Synthesis of Diaryliodonium Tetrafluoroborates from Arylboronic Acids and Aryl Iodides

(2008) Marcin Bielawski et al.   JOURNAL OF ORGANIC CHEMISTRY

Site-Selective sp2and Benzylic sp3Palladium-Catalyzed Direct Arylation

(2008) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Benzoic and Phenyl Acetic Acids

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights into Directing Group Ability in Palladium-Catalyzed C−H Bond Functionalization

(2008) Lopa V. Desai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling Reactions of Aryl Pivalates with Boronic Acids

(2008) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions

(2008) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS

Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes

(2008) Shuichi Oi et al.   TETRAHEDRON

Remote C–H bond functionalization reveals the distance-dependent isotope effect

(2008) Jiao-Jie Li et al.   TETRAHEDRON

Regioselective ortho-hydroxylation of aryl moiety of 2-arylpyridines using Pd(OAc)2/Oxone in PEG-3400/tert-BuOH

(2008) Sung Hwan Kim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed cross-coupling reaction of aryl trimethoxysilanes with terminal alkynes

(2008) Zhishi Ye et al.   TETRAHEDRON LETTERS