A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights

Divergent and Stereoselective Synthesis of β-Silyl-α-Amino Acids through Palladium-Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds

(2016) Yue-Jin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes

(2016) Yuanhong Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Pincer Ruthenium Complex for Regioselective C–H Silylation of Heteroarenes

(2016) Huaquan Fang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Intermolecular Direct Silylation of Unreactive C(sp3)–H Bonds

(2016) Wei Li et al.   ORGANIC LETTERS

Experimental and Computational Studies on the Reactivity and Binding Mode of Thiophene with N-Heterocyclic Carbene Iridium Complexes

(2016) Laura Rubio-Pérez et al.   ORGANOMETALLICS

Ruthenium-Catalyzed Dehydrogenative Aromatic CH Silylation of Benzamides with Hydrosilanes

(2015) Kosuke Takada et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization

(2015) Simon Wübbolt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

(2015) Laura Rubio-Pérez et al.   CHEMICAL COMMUNICATIONS

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Application of the π-accepting ability parameter of N-heterocyclic carbene ligands in iridium complexes for signal amplification by reversible exchange (SABRE)

(2015) Bram J. A. van Weerdenburg et al.   DALTON TRANSACTIONS

Iridium-Catalyzed Silylation of Aryl C–H Bonds

(2015) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bipyridine- and Phenanthroline-Based Metal–Organic Frameworks for Highly Efficient and Tandem Catalytic Organic Transformations via Directed C–H Activation

(2015) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Direct silylation reactions of inert C-H bonds via transition metal catalysis

(2015) Yunhui Yang et al.   Science China-Chemistry

The divergent effects of strong NHC donation in catalysis

(2015) Justin A. M. Lummiss et al.   Chemical Science

Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic CH Bonds Directed by a Secondary Amine

(2014) Qian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective CH Bond Functionalization of 2-(2-Thienyl)pyridine by a Rhodium N-Heterocyclic Carbene Catalyst

(2014) Laura Rubio-Pérez et al.   ChemCatChem

Mechanism of the Rhodium-Catalyzed Silylation of Arene C–H Bonds

(2014) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

9-Silafluorenes via Base-Promoted Homolytic Aromatic Substitution (BHAS) – The Electron as a Catalyst

(2014) Dirk Leifert et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct C–H Silylation and Germanylation of Benzamides and Carboxamides

(2014) Kyalo Stephen Kanyiva et al.   ORGANIC LETTERS

Disilaferracycle Dicarbonyl Complex Containing Weakly Coordinated η2-(H-Si) Ligands: Application to C–H Functionalization of Indoles and Arenes

(2014) Yusuke Sunada et al.   ORGANOMETALLICS

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Hyperpolarisation through reversible interactions with parahydrogen

(2014) Lyrelle S. Lloyd et al.   Catalysis Science & Technology

Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE)

(2013) Bram J. A. van Weerdenburg et al.   CHEMICAL COMMUNICATIONS

Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes

(2013) Masashi Koyanagi et al.   CHEMISTRY LETTERS

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic C–H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(i)/2,9-dimethylphenanthroline (dmphen) complex

(2013) Tatsuo Ishiyama et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification

(2013) Alexey Kuznetsov et al.   ORGANIC LETTERS

New Host Material for High-Performance Blue Phosphorescent Organic Electroluminescent Devices

(2012) Jong-Kwan Bin et al.   ADVANCED MATERIALS

Ruthenium-catalyzed Ortho-selective Aromatic C–H Silylation: Acceptorless Dehydrogenative Coupling of Hydrosilanes

(2012) Toru Sakurai et al.   CHEMISTRY LETTERS

Ligand-Controlled Regioselectivity in the Hydrothiolation of Alkynes by Rhodium N-Heterocyclic Carbene Catalysts

(2012) Andrea Di Giuseppe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

1,3,4-Oxadiazole Containing Silanes as Novel Hosts for Blue Phosphorescent Organic Light Emitting Diodes

(2012) Man-kit Leung et al.   ORGANIC LETTERS

Scandium-Catalyzed Silylation of Aromatic CH Bonds

(2011) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicon-based cross-coupling reaction: an environmentally benign version

(2011) Yoshiaki Nakao et al.   CHEMICAL SOCIETY REVIEWS

Abnormal NHC Palladium Complexes: Synthesis, Structure, and Reactivity

(2011) Aurelie Poulain et al.   CURRENT ORGANIC CHEMISTRY

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium N-Heterocyclic Carbene Complexes as Efficient Catalysts for Magnetization Transfer frompara-Hydrogen

(2011) Michael J. Cowley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-mediated fluorination of aryl silanes

(2011) Pingping Tang et al.   TETRAHEDRON

How to Conceptualize Catalytic Cycles? The Energetic Span Model

(2010) Sebastian Kozuch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iridium-Catalyzed AreneOrtho-Silylation by Formal Hydroxyl-Directed C−H Activation

(2010) Eric M. Simmons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Silicon-Based Blue Phosphorescence Host Materials: Structure and Photophysical Property Relationship on Methyl/Phenylsilanes Adorned with 4-(N-Carbazolyl)phenyl Groups and Optimization of Their Electroluminescence by Peripheral 4-(N-Carbazolyl)phenyl Numbers

(2009) Won-Sik Han et al.   Journal of Physical Chemistry C

Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides

(2009) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorination of Boronic Acids Mediated by Silver(I) Triflate

(2009) Takeru Furuya et al.   ORGANIC LETTERS

LabileN-Heterocyclic Carbene Complexes of Iridium

(2009) Olga Torres et al.   ORGANOMETALLICS

A Highly Efficient Host/Dopant Combination for Blue Organic Electrophosphorescence Devices

(2008) Jin-Ju Lin et al.   ADVANCED FUNCTIONAL MATERIALS

Efficient Iridium-Catalyzed CH Functionalization/Silylation of Heteroarenes

(2008) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Silylation of Aromatic Carbon-Hydrogen Bonds in 2-Arylpyridines with Disilane

(2008) Mamoru Tobisu et al.   Chemistry-An Asian Journal

High Oxidation State Transition Metal Complexes Ligated with N-Heterocyclic Carbenes

(2008) K. Jain et al.   CURRENT ORGANIC CHEMISTRY

Nanosized starlike molecules. Synthesis and optical properties of tris- and tetrakis[oligo(disilanylenebithienylene)dimethylsilyl]benzene

(2008) Akinobu Naka et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY