Sigmatropic rearrangements of B(MIDA)-propargylic alcohols towards the diverse synthesis of α-functionalized organoborons

Highly Regio‐, Stereo‐, and Enantioselective Copper‐Catalyzed B−H Bond Insertion of α‐Silylcarbenes: Efficient Access to Chiral Allylic gem ‐Silylboranes

(2022) Ming‐Yao Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of allenyl-B(MIDA) via hydrazination/fragmentation reaction of B(MIDA)-propargylic alcohol

(2022) Jiasheng Qian et al.   CHINESE CHEMICAL LETTERS

Boryl-Dictated Site-Selective Intermolecular Allylic and Propargylic C–H Amination

(2022) Yuan Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-Catalyzed Hydroboration of Ynones Leads to a Nontraditional Mode of Reactivity

(2022) Qiang Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of fluorinated aminoalkylboronic acids from amphoteric α‐boryl aldehydes

(2021) Harjeet S. Soor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Saturated boronic acids, boronates, and trifluoroborates: an update on their synthetic and medicinal chemistry

(2021) Dmitriy M. Volochnyuk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aza-Matteson Reactions via Controlled Mono- and Double-Methylene Insertions into Nitrogen–Boron Bonds

(2021) Qiqiang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Fluorination of Alkenes via Bora‐Wagner–Meerwein Rearrangement. Access to β‐Difluoroalkyl Boronates

(2021) Qiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Potassium Acyltrifluoroborates (KATs) from Carboxylic Acids by Copper‐Catalyzed Borylation of Mixed Anhydrides**

(2021) Pinku Tung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formyl MIDA Boronate: C 1 Building Block Enables Straightforward Access to α‐Functionalized Organoboron Derivatives

(2020) Yevhen M. Ivon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One‐Step Synthesis of Acylboron Compounds via Cu‐Catalyzed Carbonylative Borylation of Alkyl Halides

(2020) Li-Jie Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxyboronate as a Versatile in situ CO surrogate in Palladium‐Catalyzed Carbonylative Transformations

(2020) Andrei K. Yudin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Synthesis of Potassium Acyltrifluoroborates (KATs) from Boronic Acids and the Thioimidate KAT Transfer Reagent

(2020) Anne Schuhmacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Synthesis of Potassium Acyltrifluoroborates from Aldehydes through Copper(I)-Catalyzed Borylation/Oxidation

(2019) Jumpei Taguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Synthesis of Potassium Acyltrifluoroborates (KATs) by Chemoselective Cross-Coupling with a Bifunctional Reagent

(2019) Dino Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Traceless Templated Amide-Forming Ligations

(2019) Alberto Osuna Gálvez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diversity-Oriented Synthesis of α-Functionalized Acylborons and Borylated Heteroarenes via Nucleophilic Ring-Opening of α-Chloroepoxyboronates

(2019) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Radical Hydroboration of gem-Difluoroalkenes: Synthesis of α-Borylated Organofluorines

(2019) Ji-Kang Jin et al.   ORGANIC LETTERS

gem -Difluorination of Alkenyl N -methyliminodiacetyl Boronates: Synthesis of α- and β-Difluorinated Alkylborons

(2018) Wen-Xin Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Acylation of Primary Amines and Amides with Potassium Acyltrifluoroborates under Acidic Conditions

(2017) Alberto Osuna Gálvez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acylboranes: synthetic strategies and applications

(2017) Florian Korbinian Scharnagl et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Oxidative Difunctionalization of Alkenyl MIDA Boronates: A Versatile Platform for Halogenated and Trifluoromethylated α-Boryl Ketones

(2016) Wen-Xin Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Aminoboronic Acid Derivatives from Amines and Amphoteric Boryl Carbonyl Compounds

(2016) Diego B. Diaz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-aminoboronic acids

(2016) Patricia Andrés et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of α,β-Unsaturated Acylsilanes via Perrhenate-Catalyzed Meyer–Schuster Rearrangement of 1-Silylalkyn-3-ols

(2015) Andrei Nikolaev et al.   ORGANIC LETTERS

Recent Advances on the Lewis Acid-Catalyzed Cascade Rearrangements of Propargylic Alcohols and Their Derivatives

(2014) Yuanxun Zhu et al.   ACS Catalysis

Boronic Esters in Asymmetric Synthesis

(2013) Donald S. Matteson   JOURNAL OF ORGANIC CHEMISTRY

Oxidative Geminal Functionalization of Organoboron Compounds

(2012) Zhi He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Three-Component Highly Selective Synthesis of Homoallylboronates by Using Metal-Free Catalysis

(2012) Ismail Ibrahem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amphoteric α-Boryl Aldehydes

(2011) Zhi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pinene-Derived Iminodiacetic Acid (PIDA): A Powerful Ligand for Stereoselective Synthesis and Iterative Cross-Coupling of C(sp3) Boronate Building Blocks

(2011) Junqi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Simple and General Platform for Generating Stereochemically Complex Polyene Frameworks by Iterative Cross-Coupling

(2010) Suk Joong Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed transformations of propargylic alcohols into α,β-unsaturated carbonyl compounds: from the Meyer–Schuster and Rupe rearrangements to redox isomerizations

(2010) Victorio Cadierno et al.   DALTON TRANSACTIONS

Synthesis of an Acyltrifluoroborate and Its Fusion with Azides To Form Amides

(2010) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile one-pot synthesis of three different substituted thiazoles from propargylic alcohols

(2010) Xun Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY