期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 41, 页码 18016-18022出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202007651
关键词
aldehydes; boron; C(1)building blocks; oxidation; synthetic methods
资金
- Ministry of Education and Science of Ukraine [19BF037-03, 19BF037-06]
- Enamine Ltd.
Formyl MIDA boronate has been known to be an elusive type of acylboronate that has not been obtained to date. In this work, an approach to the one-pot preparation and chemical transformations of formyl MIDA boronate were developed to provide new types of alpha-functionalized organoboron compounds. Among them are acylboronate reagents which present boron-substituted analogues of ynones and beta-dicarbonyl compounds. The developed synthetic procedures, utilizing formyl MIDA boronate, are tolerant to diverse functional groups, making this reagent an advantageous C(1)building block for extending the scope of organoboron chemistry.
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