期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 32, 页码 11058-11062出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201904576
关键词
acylboron compounds; cross-coupling; Stille reactions; synthetic methods; zwitterions
资金
- Eli Lilly and Company [0] Funding Source: Medline
Potassium acyltrifluoroborates (KATs) are increasingly important functional groups, and general methods for their preparation are of great current interest. We report a bifunctional iminium reagent bearing both a tin nucleophile and a trifluoroborate, which was applied in chemoselective Pd-0-catalyzed Migita-Kosugi-Stille cross-coupling reactions owith aryl and vinyl halides. This method gives access to previously inaccessible aromatic and alpha,beta-unsaturated acyltrifluoroborates, including precursors to amino-acid derived KATs.
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