Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

Catalytic Asymmetric Homologation of Ketones with α-Alkyl α-Diazo Esters

(2021) Fei Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes

(2021) Yong‐Liang Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Catalytic Synthesis of Hexahydropyrrolo‐isoquinolines via Three‐Component 1,3‐Dipolar‐Cycloaddition

(2021) Zhaojing Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Formal Vinylogous N–H Insertion of Secondary Aliphatic Amines Catalyzed by a High-Spin Cobalt(II) Complex

(2021) Wei Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalytic 1,3-dipolar cycloaddition of α-diazoesters for synthesis of 1-pyrazoline-based spirochromanones and beyond

(2021) Peng Zhao et al.   Science China-Chemistry

Lightening Diazo Compounds?

(2021) Jakub Durka et al.   ACS Sustainable Chemistry & Engineering

Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions

(2020) Sripati Jana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu(I)/Chiral Bisoxazoline-Catalyzed Enantioselective Sommelet–Hauser Rearrangement of Sulfonium Ylides

(2020) Shu-Sen Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Multisubstituted pyrazole synthesis via [3 + 2] cycloaddition/rearrangement/N H insertion cascade reaction of α-diazoesters and ynones

(2020) Peng Zhao et al.   CHINESE CHEMICAL LETTERS

Enantioselective Carbonyl 1,2- or 1,4-Addition Reactions of Nucleophilic Silyl and Diazo Compounds Catalyzed by the Chiral Oxazaborolidinium Ion

(2019) Su Yong Shim et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Catalytic [2,3]-Stevens and Sommelet-Hauser Rearrangements of α-Diazo Pyrazoleamides with Sulfides

(2019) Xiaobin Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermal Stability and Explosive Hazard Assessment of Diazo Compounds and Diazo Transfer Reagents

(2019) Sebastian P. Green et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Chiral Nickel(II) Complex Catalyzed Enantioselective Doyle–Kirmse Reaction of α-Diazo Pyrazoleamides

(2018) Xiaobin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-catalyzed regioselective hydroamination of alkenyl diazoacetates to synthesize γ-amino acid equivalents

(2018) Jun Ueda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chiral Lewis acid-catalyzed enantioselective cyclopropanation and C–H insertion reactions of vinyl ketones with α-diazoesters

(2018) Peng Zhao et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Metal-Catalyzed Asymmetric 1,4-Conjugate Addition (ACA) of Nonorganometallic Nucleophiles

(2018) Ke Zheng et al.   CHEMICAL REVIEWS

Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C–H bonds

(2018) Kuangbiao Liao et al.   Nature Chemistry

Chiral Lewis Acid Catalyzed Reactions of α-Diazoester Derivatives: Construction of Dimeric Polycyclic Compounds

(2018) Fei Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement of sulfonium ylides

(2017) Zhikun Zhang et al.   Nature Chemistry

Nitrogen Group Retaining Reaction in the Transformation of Diazo Compounds

(2016) Di Qiu et al.   ACTA CHIMICA SINICA

Homologation Reaction of Ketones with Diazo Compounds

(2016) Nuno R. Candeias et al.   CHEMICAL REVIEWS

Catalytic Michael/Ring-Closure Reaction of α,β-Unsaturated Pyrazoleamides with Amidomalonates: Asymmetric Synthesis of (−)-Paroxetine

(2016) Yu Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of N−H-Free 1,5-Benzothiazepines

(2016) Guojin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

(2016) Jun-Xia Guo et al.   Chemical Science

Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts

(2015) Patrick L. Holland   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Catalytic Reactions with N-Acyliden Penta-atomic Aza-heterocycles. Heterocycles as Masked Bricks To Build Chiral Scaffolds

(2015) Giovanni Desimoni et al.   CHEMICAL REVIEWS

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

N,N′-Dioxide/Gadolinium(III)-Catalyzed Asymmetric Conjugate Addition of Nitroalkanes to α,β-Unsaturated Pyrazolamides

(2015) Qian Yao et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Intramolecular Homologation of Ketones with α-Diazoesters: Synthesis of Cyclic α-Aryl/Alkyl β-Ketoesters

(2014) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis

(2014) Xiaohua Liu et al.   Organic Chemistry Frontiers

Catalytic Asymmetric Homologation of α-Ketoesters with α-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers

(2013) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Tetrahydropyridazines by a Metal-Carbene-Directed Enantioselective Vinylogous NH Insertion/Lewis Acid-Catalyzed Diastereoselective Mannich Addition

(2012) Xinfang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalytic Asymmetric Ring-Expansion Reaction of Isatins and α-Alkyl-α-Diazoesters: Highly Efficient Synthesis of Functionalized 2-Quinolone Derivatives

(2012) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ChiralN,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions

(2011) XiaoHua Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric Addition of Alkyl Enol Ethers to 1,2-Dicarbonyl Compounds: Highly Enantioselective Synthesis of Substituted 3-Alkyl-3-Hydroxyoxindoles

(2011) Ke Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

New Electrophilic Addition of α-Diazoesters with Ketones for Enantioselective C–N Bond Formation

(2011) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrizing Asymmetric Ring Expansion of Cyclohexanones with α-Diazoacetates Catalyzed by Chiral Aluminum Lewis Acid

(2011) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Enantioselective Synthesis of 2-Aryl Cycloalkanones by Sc-Catalyzed Carbon Insertion

(2011) Victor L. Rendina et al.   ORGANIC LETTERS

Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters

(2010) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective synthesis of tertiary alcohols: C2-symmetric N,N′-dioxide-Sc(iii) complex promoted direct aldol reaction of α-ketoesters and diazoacetate esters

(2009) Fei Wang et al.   CHEMICAL COMMUNICATIONS

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

(2009) Yan Zhang et al.   CHEMICAL COMMUNICATIONS

Dyotropic Reactions: Mechanisms and Synthetic Applications†

(2009) Israel Fernández et al.   CHEMICAL REVIEWS

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C−C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes

(2009) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON