Enantioselective Formal Vinylogous N–H Insertion of Secondary Aliphatic Amines Catalyzed by a High-Spin Cobalt(II) Complex

Regiospecific and Enantioselective Arylvinylcarbene Insertion of a C–H Bond of Aniline Derivatives Enabled by a Rh(I)-Diene Catalyst

(2021) Dong-Xing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Z-Selective Double Bond Transposition in Simple Alkenes and Allylarenes through a Spin-Accelerated Allyl Mechanism

(2021) Daniel Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes

(2020) Bowen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Feng Ligand: Privileged Chiral Ligand in Asymmetric Catalysis

(2020) Ming‐Yang Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Asymmetric Catalytic [2,3]-Stevens and Sommelet-Hauser Rearrangements of α-Diazo Pyrazoleamides with Sulfides

(2019) Xiaobin Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective carbene insertion into N–H bonds of aliphatic amines

(2019) Mao-Lin Li et al.   SCIENCE

Chiral Amino Acids-Derived Catalysts and Ligands

(2018) Xiaohua Liu et al.   CHINESE JOURNAL OF CHEMISTRY

Chiral Nickel(II) Complex Catalyzed Enantioselective Doyle–Kirmse Reaction of α-Diazo Pyrazoleamides

(2018) Xiaobin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-catalyzed regioselective hydroamination of alkenyl diazoacetates to synthesize γ-amino acid equivalents

(2018) Jun Ueda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Chiral α,β-Unsaturated γ-Amino Esters via Pd-Catalyzed Asymmetric Allylic Amination

(2017) Chao Xia et al.   ORGANIC LETTERS

Synthesis of Enantioenriched γ-Amino-α,β-unsaturated Esters Utilizing Palladium-Catalyzed Rearrangement of Allylic Carbamates for Direct Application to Formal [3 + 2] Cycloaddition

(2017) Azusa Kondoh et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of Cyclopentyl β-Amino Esters by [3+2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates

(2016) Yongming Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of N−H-Free 1,5-Benzothiazepines

(2016) Guojin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

(2016) Jun-Xia Guo et al.   Chemical Science

Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts

(2015) Patrick L. Holland   ACCOUNTS OF CHEMICAL RESEARCH

A Short Scalable Route to (−)-α-Kainic Acid Using Pt-Catalyzed Direct Allylic Amination

(2015) Ming Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Divergent Addition Reactions of Enoldiazoacetamides with Nitrones

(2015) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Double Activation Method for the Conversion of Vinyl Epoxides into vic-Amino Alcohols and Chiral Benzoxazine/Quinoxaline Derivatives

(2015) Gourishetty Srikanth et al.   ORGANIC LETTERS

Reversal of the Regiochemistry in the Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes

(2014) Pablo E. Guzmán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Alkylation of Sulfenate Anions to Chiral Heterocyclic Sulfoxides Using Halogenated Pentanidium Salts

(2014) Lili Zong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives

(2014) Yin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective, Intermolecular Hydroamination of Allenyl Esters Catalyzed by Bifunctional Phosphinothioureas

(2014) Yuan-Qing Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis

(2014) Xiaohua Liu et al.   Organic Chemistry Frontiers

Highly Enantioselective Dearomatizing Formal [3+3] Cycloaddition Reactions ofN-Acyliminopyridinium Ylides with Electrophilic Enol Carbene Intermediates

(2013) Xinfang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Rh2(R-TPCP)4-Catalyzed Enantioselective [3+2]-Cycloaddition between Nitrones and Vinyldiazoacetates

(2013) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Syntheses of Quinolizidines by Dirhodium-Catalyzed Dearomatization of Isoquinolinium/Pyridinium Methylides–The Role of Catalyst and Carbene Source

(2013) Xichen Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalyzed regiospecific and stereospecific allylic amination for the syntheses of α,β-unsaturated γ-amino esters and the bifurcation of the reaction pathway leading to the formation of oxazolidin-2-ones

(2013) Jun Hee Lee et al.   Chemical Science

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Tetrahydropyridazines by a Metal-Carbene-Directed Enantioselective Vinylogous NH Insertion/Lewis Acid-Catalyzed Diastereoselective Mannich Addition

(2012) Xinfang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates

(2012) Austin G. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(S-biTISP)2-Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids

(2012) Yajing Lian et al.   ORGANIC LETTERS

ChiralN,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions

(2011) XiaoHua Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

(2011) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Drug Discovery Targeting Amino Acid Racemases

(2011) Paola Conti et al.   CHEMICAL REVIEWS

Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N–H Insertion

(2011) Shou-Fei Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmeric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates

(2011) Xiaochen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Insertion of Carbenoids into NH Bonds Catalyzed by Copper(I) Complexes of Binol Derivatives

(2010) Zongrui Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Salinosporamide Natural Products: Potent 20 S Proteasome Inhibitors as Promising Cancer Chemotherapeutics

(2010) Tobias A. M. Gulder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vinylogous reactivity of silver(i) vinylcarbenoids

(2010) Jørn H. Hansen et al.   Chemical Science