Enantioselective Synthesis of N−H-Free 1,5-Benzothiazepines

Enantioselective bifunctional iminophosphorane catalyzed sulfa-Michael addition of alkyl thiols to unactivated β-substituted-α,β-unsaturated esters

(2017) Jinchao Yang et al.   Chemical Science

Asymmetric Hydrogenation of Vinylthioethers: Access to Optically Active 1,5-Benzothiazepine Derivatives

(2016) Wei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Michael/Ring-Closure Reaction of α,β-Unsaturated Pyrazoleamides with Amidomalonates: Asymmetric Synthesis of (−)-Paroxetine

(2016) Yu Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly enantioselective Michael addition of malononitrile to α,β-unsaturated pyrazolamides catalyzed by a bifunctional thiourea

(2016) Yuanqin Zheng et al.   TETRAHEDRON

Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage

(2016) Yuting Liao et al.   Chemical Science

Regio- and Enantioselective Aza-Diels-Alder Reactions of 3-Vinylindoles: A Concise Synthesis of the Antimalarial Spiroindolone NITD609

(2015) Haifeng Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes

(2015) Qian Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Catalytic Reactions with N-Acyliden Penta-atomic Aza-heterocycles. Heterocycles as Masked Bricks To Build Chiral Scaffolds

(2015) Giovanni Desimoni et al.   CHEMICAL REVIEWS

N,N′-Dioxide/Gadolinium(III)-Catalyzed Asymmetric Conjugate Addition of Nitroalkanes to α,β-Unsaturated Pyrazolamides

(2015) Qian Yao et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Net Cycloaddition Approach to Optically Active 1,5-Benzothiazepines

(2015) Yukihiro Fukata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cation-Directed Enantioselective Sulfur-Mediated Michael/Mannich Three-Component Domino Reaction involving Chalcones as Michael Acceptors

(2015) Ran Ding et al.   ORGANIC LETTERS

Organocatalytic Enantioselective Sulfur-Michael Addition of Thioacetic Acid to Arylmethylidenemalonates

(2014) Renchao Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Addition of Thioacids to Trisubstituted Nitroalkenes

(2014) James P. Phelan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Carbon–Sulfur Bond-Forming Reactions

(2014) Pankaj Chauhan et al.   CHEMICAL REVIEWS

Magnesium Complexes as Highly Effective Catalysts for Conjugate Cyanation of α,β-Unsaturated Amides and Ketones

(2014) Jinlong Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Microwave-Assisted Tandem Organocatalytic Peptide-Coupling Intramolecular aza-Michael Reaction: α,β-UnsaturatedN-Acyl Pyrazoles as Michael Acceptors

(2014) María Sánchez-Roselló et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Sulfa-Michael Addition to α-Substituted Vinyl Ketones Catalyzed by Chiral Primary Amine

(2014) Niankai Fu et al.   ORGANIC LETTERS

Iron catalyzed enantioselective sulfa-Michael addition: a four-step synthesis of the anti-asthma agent Montelukast

(2014) James D. White et al.   Chemical Science

Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis

(2014) Xiaohua Liu et al.   Organic Chemistry Frontiers

Organocatalytic Asymmetric Sulfa-Michael Addition of Thiols to α,β-Unsaturated Hexafluoroisopropyl Esters: Expeditious Access to (R)-Thiazesim

(2013) Xin Fang et al.   ORGANIC LETTERS

Highly Efficient Catalytic Asymmetric Sulfa-Michael Addition of Thiols to trans-4,4,4-Trifluorocrotonoylpyrazole

(2012) Xiu-Qin Dong et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Conjugate Addition of Thiols to α,β-Unsaturated Thioamides: Expeditious Access to Enantioenriched 1,5-Benzothiazepines

(2012) Takanori Ogawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric domino sulfa-Michael–aldol reactions of 2-mercaptobenzaldehyde with α,β-unsaturated N-acylpyrazoles for the construction of thiochromane

(2012) Xiu-Qin Dong et al.   CHEMICAL COMMUNICATIONS

Chiral-Sc catalyzed asymmetric Michael addition/protonation of thiols with enones in water

(2012) Taku Kitanosono et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chiral ionic Brønsted acid–achiral Brønsted base synergistic catalysis for asymmetric sulfa-Michael addition to nitroolefins

(2012) Daisuke Uraguchi et al.   Chemical Science

ChiralN,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions

(2011) XiaoHua Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diastereodivergent Asymmetric Sulfa-Michael Additions of α-Branched Enones using a Single Chiral Organic Catalyst

(2011) Xu Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Enolate Protonation in Sulfa–Michael Addition to α-SubstitutedN-Acryloyloxazolidin-2-ones with Bifunctional Organocatalyst

(2011) Nirmal K. Rana et al.   ORGANIC LETTERS

Sc(III)-Catalyzed Enantioselective Addition of Thiols to α,β-Unsaturated Ketones in Neutral Water

(2011) Simona Bonollo et al.   ORGANIC LETTERS

Highly Enantioselective Conjugate Addition of Thioglycolate to Chalcones Catalyzed by Lanthanum: Low Catalyst Loading and Remarkable Chiral Amplification

(2010) Yonghai Hui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric ruthenium-catalyzed 1,4-additions of aryl thiols to enones

(2009) Andrei Bădoiu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

1,5-Benzothiazepine, a versatile pharmacophore: A review

(2008) Jitender B. Bariwal et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Molecular sieves 4A work to mediate the catalytic metal enolization of nucleophile precursors: application to catalyzed enantioselective Michael addition reactions

(2008) Masayuki Hasegawa et al.   TETRAHEDRON LETTERS