Lightening Diazo Compounds?

Blue LED-Mediated N–H Insertion of Indoles into Aryldiazoesters at Room Temperature in Batch and Flow: Reaction Kinetics, Density Functional Theory, and Mechanistic Study

(2021) Debajit Maiti et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemical Carbene Transfer Reactions of Aryl/Aryl Diazoalkanes – Experiment and Theory

(2021) Sripati Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Arene C-H Alkylation Enabled by Organic Photoredox Catalysis

(2020) Natalie Holmberg-Douglas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible‐Light Driven Photocatalyst‐ and Additive‐Free Cross‐Coupling of β‐Ketothioamides with α‐Diazo 1,3‐diketones: Access to Highly Functionalized Thiazolines

(2020) Maya Shankar Singh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photochemical Doyle–Kirmse Reaction: A Route to Allenes

(2020) Katarzyna Orłowska et al.   ORGANIC LETTERS

Sequential Visible-Light and N-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-b]indoles

(2020) Chengyuan Wang et al.   ORGANIC LETTERS

Contribution of Organofluorine Compounds to Pharmaceuticals

(2020) Munenori Inoue et al.   ACS Omega

Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions

(2020) Sripati Jana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radical-Mediated Strategies for the Functionalization of Alkenes with Diazo Compounds

(2020) Yong-Liang Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Cyclopropanation of Cyclooctatetraene and (Poly-)unsaturated Carbocycles

(2020) Yujing Guo et al.   ORGANIC LETTERS

Blue light-promoted N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates: Synthesis of unnatural α-aryl amino acid derivatives

(2020) Celso Y. Okada et al.   TETRAHEDRON

Photochemical O−H Functionalization Reactions of Cyclic Diazoamides

(2020) Claire Empel et al.   ADVANCED SYNTHESIS & CATALYSIS

Photochemical O–H Functionalization of Aryldiazoacetates with Phenols via Proton Transfer

(2020) Claire Empel et al.   ORGANIC LETTERS

Visible-Light-Promoted Site-Selective N1-Alkylation of Benzotriazoles with α-Diazoacetates

(2020) Jingya Yang et al.   ORGANIC LETTERS

Visible-Light-Promoted Polysubstituted Olefins Synthesis Involving Sulfur Ylides as Carbene Trapping Reagents

(2020) Cong Ye et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox Catalysis Enables Decarboxylative Cyclization with Hypervalent Iodine(III) Reagents: Access to 2,5-Disubstituted 1,3,4-Oxadiazoles

(2020) Jian Li et al.   ORGANIC LETTERS

Visible-light-mediated C3-ethoxycarbonylmethylation of imidazo[1,2-a]pyridines and convenient access to Zolpidem

(2020) Yuanjiu Xiao et al.   TETRAHEDRON LETTERS

gem-Difluoroallylation of Aryl Diazoesters via Catalyst-Free, Blue-Light-Mediated Formal Doyle–Kirmse Reaction

(2019) Jianhua Yang et al.   ORGANIC LETTERS

Mechanistic Investigation of Biocatalytic Heme Carbenoid Si‐H Insertions

(2019) Rahul Khade et al.   ChemCatChem

Photochemical, Metal‐Free Sigmatropic Rearrangement Reactions of Sulfur Ylides

(2019) Zhen Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible Light Induced Metal-Free Carbene N-Carbazolation

(2019) Claire Empel et al.   JOURNAL OF ORGANIC CHEMISTRY

Photocatalytic Alkylation of Pyrroles and Indoles with α-Diazo Esters

(2019) Łukasz W. Ciszewski et al.   ORGANIC LETTERS

Photoredox Decarboxylative C(sp3)–N Coupling of α-Diazoacetates with Alkyl N-Hydroxyphthalimide Esters for Diversified Synthesis of Functionalized N-Alkyl Hydrazones

(2019) Chun-Ming Chan et al.   ORGANIC LETTERS

Hantzsch Ester-Mediated Benzannulation of Diazo Compounds under Visible Light Irradiation

(2019) Savita B. Nagode et al.   ORGANIC LETTERS

Norcaradiene Synthesis via Visible-Light-Mediated Cyclopropanation Reactions of Arenes

(2019) Yujing Guo et al.   ORGANIC LETTERS

Synthesis of Chiral Esters via Asymmetric Wolff Rearrangement Reaction

(2019) Jing Meng et al.   ORGANIC LETTERS

Catalyst-Free [2,3]-Sigmatropic Rearrangement Reactions of Photochemically Generated Ammonium Ylides

(2019) Fang Li et al.   SYNTHESIS-STUTTGART

Blue Light‐Promoted N−H Insertion of Carbazoles, Pyrazoles and 1,2,3‐Triazoles into Aryldiazoacetates

(2019) Mateus L. Stivanin et al.   ADVANCED SYNTHESIS & CATALYSIS

Photoinduced Proton-Transfer Reactions for Mild O-H Functionalization of Unreactive Alcohols

(2019) Sripati Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stoichiometric Photochemical Carbene Transfer by Bamford–Stevens Reaction

(2019) Sripati Jana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Insertion Reactions of Silanes with Aryldiazoacetates

(2019) Feifei He et al.   JOURNAL OF ORGANIC CHEMISTRY

Continuous-flow photochemical carbene transfer reactions

(2019) Claire Empel et al.   Journal of Flow Chemistry

Cyclopentene Annulations of Alkene Radical Cations with Vinyl Diazo Species Using Photocatalysis

(2018) Francisco J. Sarabia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Blue Light-promoted Cross-Coupling of Aryldiazoacetates and Diazocarbonyl Compounds

(2018) Tiebo Xiao et al.   CHEMICAL COMMUNICATIONS

Visible light-promoted radical benzannulation of diazoketones with alkynes leading to polysubsituted naphthols

(2018) Yuwei He et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Generating carbyne equivalents with photoredox catalysis

(2018) Zhaofeng Wang et al.   NATURE

Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes

(2018) Yi-Pan Li et al.   TETRAHEDRON LETTERS

Blue light-promoted photolysis of aryldiazoacetates

(2018) Igor D. Jurberg et al.   Chemical Science

Ammonium Ylide Mediated Cyclization Reactions

(2018) Lukas Roiser et al.   Asian Journal of Organic Chemistry

Sulfur-Based Ylides in Transition-Metal-Catalysed Processes

(2018) James D. Neuhaus et al.   Topics in Current Chemistry

Rhodium-Catalyzed Regioselective N 2 -Alkylation of Benzotriazoles with Diazo Compounds/Enynones via a Nonclassical Pathway

(2018) Kai Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interception of Radicals by Molecular Oxygen and Diazo Compounds: Direct Synthesis of Oxalate Esters Using Visible-Light Catalysis

(2018) Meihua Ma et al.   ORGANIC LETTERS

Blue-Light-Induced Carbene-Transfer Reactions of Diazoalkanes

(2018) Renè Hommelsheim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Trapping of Pd-Containing 1,5-Dipoles by Photogenerated Ketenes: Access to 7-Membered Lactones Bearing Chiral Quaternary Stereocenters

(2018) Yi Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Regioselective Acylation of β-Ketoesters with α-Diazo Ketones Induced by Visible Light

(2018) Dan Liu et al.   ORGANIC LETTERS

Metal-Free Blue-Light-Mediated Cyclopropanation of Indoles by Aryl(diazo)acetates

(2018) Jun-Long Niu et al.   SYNTHESIS-STUTTGART

Highly Enantioselective Copper- and Iron-Catalyzed Intramolecular Cyclopropanation of Indoles

(2017) Huan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Visible-Light Photoactivation and Palladium Catalysis Enabling Enantioselective [4+2] Cycloadditions

(2017) Miao-Miao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light catalyzed Mannich reaction between tert-amines and silyl diazoenolates

(2017) Mukund M. D. Pramanik et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent progress in the catalytic carbene insertion reactions into the silicon–hydrogen bond

(2017) Hoda Keipour et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal-Free C–H Functionalization of Alkanes by Aryldiazoacetates

(2017) Cecilia Tortoreto et al.   ORGANIC LETTERS

Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds

(2017) Hoda Keipour et al.   ORGANIC LETTERS

Radical Cation Cyclopropanations via Chromium Photooxidative Catalysis

(2017) Francisco J. Sarabia et al.   ORGANIC LETTERS

Transition metal-catalyzed [2,3]-sigmatropic rearrangements of ylides: An update of the most recent advances

(2017) Zhe Sheng et al.   TETRAHEDRON

Cobalt(i)-catalysed CH-alkylation of terminal olefins, and beyond

(2016) Maciej Giedyk et al.   CHEMICAL COMMUNICATIONS

Design and Synthesis of Novel Chiral Dirhodium(II) Carboxylate Complexes for Asymmetric Cyclopropanation Reactions

(2016) Frady G. Adly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Catalysis with Organic Azides and Diazo Compounds Initiated by Photoinduced Electron Transfer

(2016) Xiaoqiang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds

(2015) Yong Liu et al.   Science China-Chemistry

Enantioselective Iron-Catalyzed Intramolecular Cyclopropanation Reactions

(2014) Jun-Jie Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements

(2014) Amanda C. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Visible-Light Induced Cross-Dehydrogenative Coupling of Tertiary Amines with Diazo Compounds

(2014) Tiebo Xiao et al.   ORGANIC LETTERS

Synthesis of benzo[a]carbazoles and indolo[2,3-a]carbazoles via photoinduced carbene-mediated C–H insertion reaction

(2014) Jidong Yang et al.   RSC Advances

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Screening Rhodium Metallopeptide Libraries “On Bead”: Asymmetric Cyclopropanation and a Solution to the Enantiomer Problem

(2012) Ramya Sambasivan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free N–H Insertions of Donor/Acceptor Carbenes

(2012) Stephanie R. Hansen et al.   ORGANIC LETTERS

Olefin Cyclopropanation Catalyzed by Iridium(III) Porphyrin Complexes

(2012) Bernie J. Anding et al.   ORGANOMETALLICS

Influence of the difluoromethylene group (CF2) on the conformation and properties of selected organic compounds

(2012) David O'Hagan et al.   PURE AND APPLIED CHEMISTRY

One-Step Catalytic Asymmetric Synthesis of Configurationally Stable Tröger Bases

(2011) Ankit Sharma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

(2011) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application

(2011) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Puretrans-β-Lactams from α-Amino Acids via Compact Fluorescent Light (CFL) Continuous-Flow Photolysis

(2010) Yvette S. Mimieux Vaske et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solvent-free catalytic enantioselective C–C bond forming reactions with very high catalyst turnover numbers

(2010) Philip Pelphrey et al.   Chemical Science

Sigmatropic rearrangements of ‘onium’ ylids

(2009) J. B. Sweeney   CHEMICAL SOCIETY REVIEWS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Carbene Reactivity of 4-Diazo-4H-imidazoles toward Nucleophiles and Aromatic Compounds

(2009) Matthew R. Smith et al.   JOURNAL OF ORGANIC CHEMISTRY

C−H Carbene Insertion of α-Diazo Acetamides by Photolysis in Non-Conventional Media

(2008) Nuno R. Candeias et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON

Gold-catalyzed olefin cyclopropanation

(2008) Auxiliadora Prieto et al.   TETRAHEDRON