Rh(III)‐Catalyzed [3+2] Annulation and C−H Alkenylation of Indoles with 1,3‐Diynes by C−H Activation

Co(III), Rh(III) & Ir(III)‐Catalyzed Direct C–H Alkylation/ Alkenylation/ Arylation with carbene precursors

(2021) Saiprasad Nunewar et al.   Chemistry-An Asian Journal

Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis

(2021) Fei Zhao et al.   ORGANIC LETTERS

Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity

(2020) Shreemoyee Kumar et al.   ORGANIC LETTERS

Advances in Rhodium-Catalyzed Oxidative Arene Alkenylation

(2020) Weihao Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Enantioselective Hydroarylation of 1,6-Enynes

(2020) Andrew Whyte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advancements in the development of heterocyclic anti-inflammatory agents

(2020) Sahil Sharma et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Rh(III)-Catalyzed Redox-Neutral Cascade Annulation of Benzamides with p -Quinone Methides

(2020) Vinaykumar Kanchupalli et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Oxidative C–H Activation/Domino Annulation of Anilines with 1,3-Diynes: A Rapid Access to Blue-Emitting Tricyclic N,O-Heteroaromatics

(2020) Shengyou Qian et al.   ORGANIC LETTERS

Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems

(2020) Yuji Nishii et al.   ACS Catalysis

Traceless Bidentate Directing Group Assisted Cobalt-Catalyzed sp2-C–H Activation and [4 + 2]-Annulation Reaction with 1,3-Diynes

(2020) Arnab Dey et al.   ORGANIC LETTERS

Rh(III)-Catalyzed [3 + 2] Spirocyclization of 2H-Imidazoles with 1,3-Diynes for the Synthesis of Spiro-[imidazole-indene] Derivatives

(2020) Yi Luo et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Alkenylation/Directing Group Migration for the Regio- and Stereoselective Synthesis of Tetrasubstituted Alkenes

(2020) Xiaowei Wu et al.   ORGANIC LETTERS

Mn(I)-Catalyzed Mechanochemical C–H Bond Activation: C-2 Selective Alkenylation of Indoles

(2020) Dharmendra Das et al.   ACS Sustainable Chemistry & Engineering

Mn-Catalyzed Dehydrocyanative Transannulation of Heteroarenes and Propargyl Carbonates through C−H Activation: Beyond the Permanent Directing Effects of Pyridines/Pyrimidines

(2019) Guangfan Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium‐Catalyzed Copper‐Assisted Intermolecular Domino C−H Annulation of 1,3‐Diynes with Picolinamides: Access to Pentacyclic π‐Extended Systems

(2019) Ángel Manu Martínez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Re‐Catalyzed Annulations of Weakly Coordinating N ‐Carbamoyl Indoles/Indolines with Alkynes via C−H/C−N Bond Cleavage

(2019) Yunhui Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Manganese(I)-Catalyzed Synthesis of Fused Eight- and Four-Membered Carbocycles via C–H Activation and Pericyclic Reactions

(2019) Youwei Xu et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C–H Activation and Nucleophilic Cyclization

(2019) Miaomiao Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobaltaelectro-Catalyzed Oxidative C–H/N–H Activation with 1,3-Diynes by Electro-Removable Hydrazides

(2019) Ruhuai Mei et al.   ORGANIC LETTERS

Synthesis and highly potent anti-inflammatory activity of licofelone- and ketorolac-based 1-arylpyrrolizin-3-ones

(2019) Damian A. Madrigal et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Indole-based melatonin analogues: Synthetic approaches and biological activity

(2019) Su-Yan Wang et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation

(2019) Sara Cembellín et al.   ACS Catalysis

Rhenium- and Manganese-Catalyzed Selective Alkenylation of Indoles

(2018) Chengming Wang et al.   ChemCatChem

Room Temperature C-H bond Functionalization by Merging Cobalt- and Photoredox catalysis

(2018) Deepti Kalsi et al.   ACS Catalysis

Functionalized Cyclopentadienyl Ligands and Their Substituent Effects on a Rhodium(III)-Catalyzed Oxidative [4+2] Annulation of Indole- and Pyrrole-1-Carboxamides with Alkynes

(2018) Takayuki Yamada et al.   Asian Journal of Organic Chemistry

One-pot Synthesis of Alkynylated Coumarins via Rhodium-Catalyzed Annulation of Aryl Thiocarbamates with 1,3-Diynes or Terminal Alkynes

(2018) Yuan Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt(III)−Catalyzed C−H Activation: A Secondary Amide Directed Decarboxylative Functionalization of Alkynyl Carboxylic Acids Wherein Amide NH-group Remains Unreactive

(2018) Nachimuthu Muniraj et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese-Catalyzed Sequential Annulation between Indoles and 1,6-Diynes

(2018) Wanzhi Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-catalyzed cyclization of benzamides with alkynes: a facile route to isoquinolones with hydrogen evolution

(2018) Ramasamy Manoharan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

C–H activation-annulation on the N-heterocyclic carbene platform

(2018) Champak Dutta et al.   RSC Advances

Cobalt‐Catalyzed Temperature‐Dependent Annulation of 3‐Aryl‐1,2,4‐oxadiazolones with 1,3‐Diynes: An Approach to π‐Conjugated Molecules

(2018) Wenge Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cp*Co(III)-Catalyzed Regioselective Synthesis of Cyclopenta[b]carbazoles via Dual C(sp2)–H Functionalization of 1-(Pyridin-2-yl)-indoles with Diynes

(2018) Qiuyun Li et al.   ORGANIC LETTERS

Arylative Cyclization of Indole-1-carboxamides with 1,6-Enynes for the Synthesis of Polycyclic Indole Scaffolds

(2017) Chatrala Ravikumar Reddy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Selective Synthesis of Alkynylated Isoquinolines and Biisoquinolines via RhIII Catalyzed C–H Activation/1,3-Diyne Strategy

(2017) Ruokun Feng et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium(II)-Catalyzed Redox-Neutral [3+2] Annulation of Indoles with Internal Alkynes via C–H Bond Activation: Accessing a Pyrroloindolone Scaffold

(2017) Yanan Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt Catalyzed, Regioselective C(sp2)–H Activation of Amides with 1,3-Diynes

(2017) Subban Kathiravan et al.   ORGANIC LETTERS

Plausible Rh(V) Intermediates in Catalytic C–H Activation Reactions

(2017) Suhelen Vásquez-Céspedes et al.   ACS Catalysis

Recent Advances in Catalytic C(sp2)–H Allylation Reactions

(2017) Neeraj Kumar Mishra et al.   ACS Catalysis

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C–H activation

(2016) Yudong Yang et al.   CHEMICAL COMMUNICATIONS

Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions

(2016) Saner Poplata et al.   CHEMICAL REVIEWS

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Cp*CoIII-Catalyzed Synthesis of Pyrido[2′,1′:2,3]pyrimido[1,6-a]indol-5-iums via Tandem C–H Activation and Subsequent Annulation from 1-(Pyridin-2-yl)-1H-indoles and Internal Alkynes

(2016) Yuhan Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-catalyzed C–C coupling reactions via double C–H activation

(2016) Shuai-Shuai Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh/Cu-catalyzed multiple C–H, C–C, and C–N bond cleavage: facile synthesis of pyrido[2,1-a]indoles from 1-(pyridin-2-yl)-1H-indoles and γ-substituted propargyl alcohols

(2015) Ting Li et al.   CHEMICAL COMMUNICATIONS

A review on recent developments of indole-containing antiviral agents

(2015) Ming-Zhi Zhang et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Nickel-Catalyzed Three-Component Domino Reactions of Aryl Grignard Reagents, Alkynes, and Aryl Halides Producing Tetrasubstituted Alkenes

(2015) Fei Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Ruthenium(II)-Catalyzed Direct C2-syn-Alkenylation of Indoles with Alkynes

(2015) Wei Zhang et al.   ORGANIC LETTERS

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

(2015) Ryosuke Morioka et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

(2014) Xiao-Feng Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic Applications

(2014) Yingguang Zhu et al.   CHEMICAL REVIEWS

Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes

(2014) Ying-Feng Han et al.   CHEMICAL SOCIETY REVIEWS

Rh(III)-Catalyzed C–H Activation/Cyclization of Indoles and Pyrroles: Divergent Synthesis of Heterocycles

(2014) Yan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium(II)-Catalyzed Direct Addition of Indole/Pyrrole C2–H Bonds to Alkynes

(2014) Libo Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

(2014) Hideya Ikemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-catalyzed oxidative C2-alkenylation of indoles with alkynes: unexpected cleavage of directing group

(2014) Satyasheel Sharma et al.   TETRAHEDRON LETTERS

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

(2012) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed N-Nitroso-Directed C–H Olefination of Arenes. High-Yield, Versatile Coupling under Mild Conditions

(2012) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)–H/C(sp3)–H and C(sp2)–H/O–H Bonds

(2012) Xing Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds

(2011) Sandeep R. Kandukuri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation and Evaluation of Carborane Analogues of Tamoxifen

(2010) Michael L. Beer et al.   JOURNAL OF MEDICINAL CHEMISTRY

The Norbornene Shuttle: Multicomponent Domino Synthesis of Tetrasubstituted Helical Alkenes through Multiple CH Functionalization

(2009) Kersten M. Gericke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Amide-Directed Alkenylation of sp2C−H Bonds Catalyzed by a Cationic Rh(I)/BIPHEP Complex Under Mild Conditions: Dramatic Rate Acceleration by a 1-Pyrrolidinecarbonyl Group

(2009) Yu Shibata et al.   ORGANIC LETTERS

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Flinderoles A−C: Antimalarial Bis-indole Alkaloids fromFlindersiaSpecies

(2008) Liza S. Fernandez et al.   ORGANIC LETTERS