Rhenium- and Manganese-Catalyzed Selective Alkenylation of Indoles

Inert C–H Bond Transformations Enabled by Organometallic Manganese Catalysis

(2018) Yuanyuan Hu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent advances in manganese-catalysed C–H activation: scope and mechanism

(2018) Rafael Cano et al.   Catalysis Science & Technology

Manganese(I)-Catalyzed Direct C–H Allylation of Arenes with Allenes

(2017) Shi-Yong Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Doubly Regioselective C–H Hydroarylation of Unsymmetrical Alkynes Using Carboxylates as Deciduous Directing Groups

(2017) Agostino Biafora et al.   ORGANIC LETTERS

Manganese(I)-Catalyzed C–H 3,3-Difluoroallylation of Pyridones and Indoles

(2017) Jiabin Ni et al.   ORGANIC LETTERS

An Approach to 3-(Indol-2-yl)succinimide Derivatives by Manganese-Catalyzed C–H Activation

(2017) Shuang-Liang Liu et al.   ORGANIC LETTERS

Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

(2017) Qingquan Lu et al.   Chemical Science

Aromatic C-H addition of ketones to imines enabled by manganese catalysis

(2017) Bingwei Zhou et al.   Nature Communications

Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C–H Activation: Efficient Access to α-gem-Vinylindoles

(2017) Xukai Zhou et al.   ACS Catalysis

C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations

(2017) Daniel Zell et al.   ACS Catalysis

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

(2017) Wenbo Ma et al.   Organic Chemistry Frontiers

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

(2017) Michela Milan et al.   ACS Central Science

Manganese-Catalyzed ortho -C−H Alkenylation of Aromatic N−H Imidates with Alkynes: Versatile Access to Mono -Alkenylated Aromatic Nitriles

(2016) Xiaoxu Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

(2016) Nasiru P. Yahaya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp2 )−H Bonds by Carbene Insertion

(2016) Ana Conde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(I)-Catalyzed Substitutive C−H Allylation

(2016) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Manganese-Mediated C−H Alkylation of Unbiased Arenes Using Alkylboronic Acids

(2016) Susana Castro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalyst-Guided C=Het Hydroarylations by Manganese-Catalyzed Additive-Free C−H Activation

(2016) Yu-Feng Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

(2016) Dmitry A. Valyaev et al.   COORDINATION CHEMISTRY REVIEWS

A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation

(2016) Xiu-Liang Lv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C–H Bond of Aromatic and Heteroaromatic Imidates

(2016) Zijia Wang et al.   ORGANIC LETTERS

C2-Alkylation and Alkenylation of Indoles Catalyzed by a Low-Valent Cobalt Complex in the Absence of Reductant

(2016) Brendan J. Fallon et al.   ORGANIC LETTERS

Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C–H Bond Activation

(2016) Shunsuke Sueki et al.   ORGANIC LETTERS

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese-Catalyzed Synthesis ofcis-β-Amino Acid Esters through Organometallic CH Activation of Ketimines

(2015) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Direct Nucleophilic C(sp2)H Addition to Aldehydes and Nitriles

(2015) Bingwei Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes

(2015) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels-Alder Reaction of In Situ Generatedortho-Quinone Methides with 3-Methyl-2-Vinylindoles

(2015) Jia-Jia Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese catalyzed C–H functionalization of indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid is the key to control selectivity

(2015) Lijun Shi et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Insertion of Alkynes and Electron-Deficient Olefins into Unactivated sp3CH Bonds

(2015) Soham Maity et al.   CHEMISTRY-A EUROPEAN JOURNAL

A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination

(2015) Shauna M. Paradine et al.   Nature Chemistry

Highly Stereoselective Ruthenium(II)-Catalyzed Direct C2-syn-Alkenylation of Indoles with Alkynes

(2015) Wei Zhang et al.   ORGANIC LETTERS

Rhenium-Catalyzed [4 + 1] Annulation of Azobenzenes and Aldehydes via Isolable Cyclic Rhenium(I) Complexes

(2015) Xiaoyu Geng et al.   ORGANIC LETTERS

Divergent Functionalization of Indoles with Acryloyl Silanes via Rhodium-Catalyzed C–H Activation

(2015) Ping Lu et al.   ORGANIC LETTERS

Iron-Catalyzed Directed C2-Alkylation and Alkenylation of Indole with Vinylarenes and Alkynes

(2015) Mun Yee Wong et al.   ORGANIC LETTERS

Indole synthesis through transition metal-catalyzed C–H activation

(2015) Tenglong Guo et al.   TETRAHEDRON LETTERS

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct C-2 Olefination of Unactivated Indoles Utilizing OH/NH2as Directing Group

(2014) Chen-Yu Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese-Catalyzed Dehydrogenative [4+2] Annulation of NH Imines and Alkynes by CH/NH Activation

(2014) Ruoyu He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine-accelerated manganese-catalyzed aromatic C–H conjugate addition to α,β-unsaturated carbonyls

(2014) Bingwei Zhou et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed Direct Addition of Indole/Pyrrole C2–H Bonds to Alkynes

(2014) Libo Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

(2014) Hideya Ikemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-catalyzed oxidative C2-alkenylation of indoles with alkynes: unexpected cleavage of directing group

(2014) Satyasheel Sharma et al.   TETRAHEDRON LETTERS

Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

(2013) Luo-Qiang Zhang et al.   CHEMICAL COMMUNICATIONS

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation

(2013) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Regioselective C2 Alkenylation of Indoles and Pyrroles via C–H Bond Functionalization

(2013) Bin Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Re/Mg Bimetallic Tandem Catalysis for [4+2] Annulation of Benzamides and Alkynes via C-H/N-H Functionalization

(2013) Qiuzheng Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-Catalyzed Aromatic C–H Alkenylation with Terminal Alkynes

(2013) Bingwei Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regioselective C2-Alkenylation of Indoles Using the N-Benzoyl Directing Group: An Efficient Ru-Catalyzed Coupling Reaction

(2013) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regioselective C–H Alkenylation Directed by a Free Amino Group

(2013) Chiharu Suzuki et al.   ORGANIC LETTERS

Manganese-Mediated C-C Bond Formation via C-H Activation: From Stoichiometry to Catalysis

(2013) Congyang Wang   SYNLETT

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes

(2012) Gianluigi Broggini et al.   Beilstein Journal of Organic Chemistry

Development of Novel and Highly Efficient Methods to Construct Carbon–Carbon Bonds Using Group 7 Transition-Metal Catalysts

(2012) Yoichiro Kuninobu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones

(2012) Peng Zhao et al.   ORGANIC LETTERS

Indole synthesis – something old, something new

(2012) Martyn Inman et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation

(2011) Pin-Sheng Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-Catalyzed Regiodivergent Addition of Indoles to Terminal Alkynes

(2011) Dexin Xia et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

(2011) Naohiko Yoshikai   SYNLETT

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

Organic Reactions Catalyzed by Rhenium Carbonyl Complexes

(2010) Yoichiro Kuninobu et al.   CHEMICAL REVIEWS

The Enantioselective, Organocatalyzed Diels-Alder Reaction of 2-Vinylindoles with α,β-Unsaturated Aldehydes: An Efficient Route to Functionalized Tetrahydrocarbazoles

(2010) Changwu Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by theN-(2-Pyridyl)sulfonyl Protecting Group

(2009) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Hydroarylation Reactions of Alkynes Through Direct Functionalization of C-H Bonds: A Convenient Tool for Organic Synthesis

(2009) Tsugio Kitamura   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Synthesis of Indoles from Alkynes

(2008) Karolin Krüger (née Alex) et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART