期刊
ORGANIC LETTERS
卷 21, 期 9, 页码 3402-3406出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01139
关键词
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资金
- Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
- NSFC [21525208, 21472186]
Pericyclic reactions have allowed facile construction of complex cycles. On the other hand, metal-catalyzed C-H activation has been established as an important strategy for rapid synthesis of complex structures. The two areas are integrated in Mn(I)-catalyzed redox-neutral coupling of 3-alkenyl- and 3-allylindoles with propargylic carbonates, which occurred via C-H allenylation with subsequent pericyclic reactions to afford fused eight- and four-membered carbocycles, respectively.
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