Construction of Optically Active 2 H ‐ and 3 H ‐Pyrroles by Cyclization and Chirality Maintaining 1,5 ‐Ester Shift Reactions

Magnesium Catalysis in Asymmetric Synthesis

(2019) Dongxu Yang et al.   Chem

Non-Aromatic 3H -Pyrroles in the Reaction with Nucleophiles: Is High Reactivity a Myth?

(2019) Dmitrii A. Shabalin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Still Unconquered: Enantioselective Passerini and Ugi Multicomponent Reactions

(2018) Qian Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Important Role of the Byproduct Triphenylphosphine Oxide in the Magnesium(II)-Catalyzed Enantioselective Reaction of Hemiacetals and Phosphorus Ylides

(2018) Linqing Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Tandem Michael Addition of Tryptamine-Derived Oxindoles to Alkynones: Concise Synthesis of Strychnos Alkaloids

(2018) Weigang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent, Enantioselective Synthesis of Pyrroles, 3H -Pyrroles and Bicyclic Imidazolines by Ag- or P-Catalyzed [3+2] Cycloaddition of Allenoates with Activated Isocyanides

(2018) Germaine Pui Yann Kok et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Catalytic Double Michael Additions for the Synthesis of Spirooxindoles

(2018) Tengfei Kang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Superbase-catalyzed domino 3H -pyrroles synthesis from ketoximes and acetylene: DFT study vs experiment

(2018) Anton V. Kuzmin et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Direct Asymmetric Formal [3 + 2] Cycloaddition Reaction of Isocyanoesters with β-Trifluoromethyl β,β-Disubstituted Enones Leading to Optically Active Dihydropyrroles

(2018) Bing Xu et al.   ORGANIC LETTERS

Diversiform Reactivity of Naphthols in Asymmetric Dearomatization or O-Alkylation Reactions with Aziridines

(2018) Linqing Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Atropenantioselective Heteroannulation between Isocyanoacetates and Alkynyl Ketones: Synthesis of Enantioenriched Axially Chiral 3-Arylpyrroles

(2018) Sheng-Cai Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

3H-Pyrroles as a platform for the catalyst-free construction of dihydropyrrolo[2,1-b]oxazoles: [4 + 2]-cycloaddition vs [2 + 3]-annulation with 1-cyano-3-hydroxyalkynes

(2018) Ludmila A. Oparina et al.   TETRAHEDRON LETTERS

Enantioselective Cycloaddition of Styrenes with Aldimines Catalyzed by a Chiral Magnesium Potassium Binaphthyldisulfonate Cluster as a Chiral Brønsted Acid Catalyst

(2017) Manabu Hatano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnesium Catalysis Mediated Tetrazoles in Desymmetrization Reaction of Aziridines

(2017) Dan Li et al.   ORGANIC LETTERS

Development of Biligands Magnesium Catalysis in Asymmetric Conjugate Reactions of C3-Pyrrolyl-Oxindoles

(2017) Kezhou Wang et al.   ORGANIC LETTERS

Highly Efficient Asymmetric Synthesis of Chiral γ-Alkenyl Butenolides Catalyzed by Chiral N,N′-Dioxide–Scandium(III) Complexes

(2017) Jie Ji et al.   ACS Catalysis

Regioselective Synthesis of Pyrroles from Alkyne-Isocyanide Click Reactions: An Angle Strain-Induced Bond Migration Approach

(2016) Jimil George et al.   ADVANCED SYNTHESIS & CATALYSIS

The Organocatalytic Approach to Enantiopure 2H- and 3H-Pyrroles: Inhibitors of the Hedgehog Signaling Pathway

(2016) Lisa Kötzner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Controlled Switch in Chemo- and Diastereoselectivities: Annulations of Morita-Baylis-Hillman Carbonates from Isatins

(2016) Gu Zhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple magnesium catalyst mediated γ-butyrolactams in desymmetrization of meso-aziridines

(2016) Dan Li et al.   CHEMICAL COMMUNICATIONS

Enantioselective construction of imidazolines having vicinal tetra-substituted stereocenters by direct Mannich reaction of α-substituted α-isocyanoacetates with ketimines

(2016) Shuichi Nakamura et al.   CHEMICAL COMMUNICATIONS

MgII -Catalyzed Desymmetrization Reaction of meso -Aziridines with Hydroxylamines: Synthesis of Novel Chiral 1,2-Diamine Skeletons

(2016) Dan Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

MgII-Mediated Catalytic Asymmetric Dearomatization (CADA) Reaction of β-Naphthols with Dialkyl Acetylenedicarboxylates

(2016) Linqing Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions

(2015) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Enantioselective Dearomatization Reaction of β-Naphthol Usingmeso-Aziridine: A Bifunctional In Situ Generated Magnesium Catalyst

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of a CC Bond-Forming Conjugate Addition Reaction in Asymmetric Dearomatization of β-Naphthols

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates

(2015) Raquel de la Campa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

(2015) Takuya Hashimoto et al.   CHEMICAL REVIEWS

Catalytic Divergent Synthesis of 3H or 1H Pyrroles by [3 + 2] Cyclization of Allenoates with Activated Isocyanides

(2015) Jia-Yu Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric [3 + 2] Cyclization Reactions of 3-Isothiocyanato Oxindoles and Alkynyl Ketones Via an in Situ Generated Magnesium Catalyst

(2015) Linqing Wang et al.   ORGANIC LETTERS

3H-Pyrroles from ketoximes and acetylene: synthesis, stability and quantum-chemical insight

(2015) Dmitrii A. Shabalin et al.   TETRAHEDRON

Direct Catalytic Enantio- and Diastereoselective Mannich Reaction of Isocyanoacetates and Ketimines

(2014) Irene Ortín et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric Mannich-Type Reaction of α-Isocyanoacetates with Ketimines using Cinchona Alkaloid/Copper(II) Catalysts

(2014) Masashi Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Silver-Catalyzed Double [3+2] Cyclization of α-Imino Esters with Isocyanoacetate

(2014) Pan-Lin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity

(2014) Chao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Synthesis of Polysubstituted 2H-Pyrroles via Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Pyrroles

(2014) Chun-Xiang Zhuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cinchona Alkaloid Squaramide/AgOAc Cooperatively Catalyzed Diastereo- and Enantioselective Mannich/Cyclization Cascade Reaction of Isocyanoacetates and Cyclic Trifluoromethyl Ketimines

(2014) Mei-Xin Zhao et al.   ORGANIC LETTERS

Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid-Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones

(2013) Manabu Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Site-Specific and Highly Enantioselective γ-Functionalization of Linear α,β-Unsaturated Ketones: Bifunctional Catalytic Strategy

(2013) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Isocyanide-Alkyne Cycloaddition: A General and Practical Method to Oligosubstituted Pyrroles

(2013) Jianquan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides

(2013) Meng Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure-Based Design of β-Site APP Cleaving Enzyme 1 (BACE1) Inhibitors for the Treatment of Alzheimer’s Disease

(2013) Jing Yuan et al.   JOURNAL OF MEDICINAL CHEMISTRY

Highly stereoselective Michael addition of azlactones to electron-deficient triple bonds under P-spiro chiral iminophosphorane catalysis: importance of protonation pathway

(2013) Daisuke Uraguchi et al.   Chemical Science

Highly Z-Selective Asymmetric Conjugate Addition of Alkynones with Pyrazol-5-ones Promoted by N,N′-Dioxide-Metal Complexes

(2012) Zhen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles

(2011) Jie Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

HighlyZ-Selective Asymmetric 1,4-Addition Reaction of 5H-Oxazol-4-ones with Alkynyl Carbonyl Compounds Catalyzed by Chiral Guanidines

(2011) Tomonori Misaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Family of Cinchona-Derived Amino Phosphine Precatalysts: Application to the Highly Enantio- and Diastereoselective Silver-Catalyzed Isocyanoacetate Aldol Reaction

(2011) Filippo Sladojevich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Aldol Reaction of Methyl α-Isocyanoacetate: A Cooperative Catalysis Approach

(2011) Hun Young Kim et al.   ORGANIC LETTERS

Asymmetric dearomatization of pyrrolesviaIr-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles

(2011) Chun-Xiang Zhuo et al.   Chemical Science

Isocyanoacetate Derivatives: Synthesis, Reactivity, and Application

(2010) Anton V. Gulevich et al.   CHEMICAL REVIEWS

Magnesium(II)-Binaphtholate as a Practical Chiral Catalyst for the Enantioselective Direct Mannich-Type Reaction with Malonates

(2010) Manabu Hatano et al.   ORGANIC LETTERS

A Stable Homodinuclear Biscobalt(III)-Schiff Base Complex for Catalytic Asymmetric 1,4-Addition Reactions of β-Keto Esters to Alkynones

(2009) Zhihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalyzed Enantioselective Three-Component Reaction Involving the α Addition of Isocyanides to Imines

(2009) Tao Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The First Magnetic Nanoparticle-Supported Chiral DMAP Analogue: Highly Enantioselective Acylation and Excellent Recyclability

(2009) Oliver Gleeson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Magnesium-Catalyzed Asymmetric Direct Aldol Addition of Ethyl Diazoacetate to Aromatic, Aliphatic, and α,β-Unsaturated Aldehydes

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol Reaction of α-Isothiocyanato Esters with Ketones

(2009) Tatsuhiko Yoshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Formal [3+2] Cycloaddition Reaction of Isocyanoesters to Nitroolefins Leading to Highly Optically Active Dihydropyrroles

(2008) Chang Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BINOLate–Magnesium Catalysts for Enantioselective Hetero-Diels–Alder Reaction of Danishefsky's Diene with Aldehydes

(2008) Haifeng Du et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Lamellarins and Related Pyrrole-Derived Alkaloids from Marine Organisms

(2007) Hui Fan et al.   CHEMICAL REVIEWS