期刊
ORGANIC LETTERS
卷 17, 期 17, 页码 4260-4263出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02052
关键词
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资金
- NSFC [91213302, 91413107, 81473095, 21432003]
- National S&T Major Project of China [2012ZX09504001-003]
- Program for Chang-jiang Scholars and Innovative Research Team in University [PCSIRT: IRT1137]
- Innovation Group of Gansu Province [1210RIIA002]
A highly enantioselective formal [3 + 2] cycloaddition reaction between 3-isothiocyanato oxindoles and alkynyl ketones is reported for the first time. An oxazoline OH type chiral ligand derived from o-hydroxyphenylacetic acid is employed to generate an effective magnesium catalyst in the current cyclization reaction and give serials of chiral spirocodndoles with good chemical yields and enantioselectivities.
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