期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 62, 页码 9640-9643出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02877b
关键词
-
资金
- NSFC [21432003, 81473095, 21272102]
- Program for Chang-jiang Scholars and Innovative Research Team in University [PCSIRT: IRT1137]
- ministry of education of China [20130211130005]
- Fundamental Research Funds for the Central Universities [lzujbky-2015-282]
The first alpha-sp(2)-carbon of carbonyl compounds attacked catalytic desymmetrization reaction of aziridines is disclosed. A simple in situ generated magnesium catalyst from 3,3'-bromine-8H-BINOL and dibutylmagnesium was employed. It is interesting that the bromine atom on the chiral ligand plays a key role in introducing a high level of enantioselectivities and high reaction efficiency. Both enantiomers of the ring-opening product could be smoothly obtained by using (R)- and (S)-L7.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据