期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 48, 页码 17141-17144出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603898
关键词
asymmetric synthesis; diamines; hydroxylamine; magnesium; oxazoline
资金
- NSFC [91413107, 21432003, 91213302, 81473095, 21272102]
- Program for Chang-jiang Scholars and Innovative Research Team in University (PCSIRT) [IRT1137]
- Innovation Group of Gansu Province [1210RJIA002]
- Fundamental Research Funds for the Central Universities [lzujbky-2015-282]
A Mg-II-catalyzed desymmetrization reaction of meso-aziridines with hydroxylamines has been disclosed for the first time. A series of novel chiral 1,2-diamine skeletons were obtained in good yields and enantioselectivities. The reaction employed magnesium catalysis generated in situ from a simple oxazoline-OH chiral ligand. Obviously, the diverse structures of the obtained chiral 1,2-diamine compounds could allow them to be potential chiral ligands in future catalytic asymmetric synthesis studies.
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