H2O2-mediated oxidative formation of amides from aromatic amines and 1,3-diketones as acylation agents via C–C bond cleavage at room temperature in water under metal-free conditions

Facile Access to Chiral Ketones through Metal-Free Oxidative CC Bond Cleavage of Aldehydes by O2

(2012) Bhoopendra Tiwari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross Coupling of Acyl and Aminyl Radicals: Direct Synthesis of Amides Catalyzed by Bu4NI with TBHP as an Oxidant

(2012) Zhaojun Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TBHP/I2-promoted oxidative coupling of acetophenones with amines at room temperature under metal-free and solvent-free conditions for the synthesis of α-ketoamides

(2012) Xiaobin Zhang et al.   GREEN CHEMISTRY

Unexpected C–C Bond Cleavage: A Route to 3,6-Diarylpyridazines and 6-Arylpyridazin-3-ones from 1,3-Dicarbonyl Compounds and Methyl Ketones

(2012) Qinghe Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Assembly of 3-Substituted Isocoumarins via a CuI-Catalyzed Domino Coupling/Addition/Deacylation Process

(2012) Shangjun Cai et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Isocoumarin Derivatives via the Copper-Catalyzed Tandem Sequential Cyclization of 2- Halo-N-phenyl Benzamides and Acyclic 1,3-Diketones

(2012) Veerababurao Kavala et al.   JOURNAL OF ORGANIC CHEMISTRY

K2CO3-Catalyzed Synthesis of Chromones and 4-Quinolones through the Cleavage of Aromatic C–O Bonds

(2012) Jie Zhao et al.   ORGANIC LETTERS

Iron-Promoted Tandem Reaction of Anilines with Styrene Oxides via C–C Cleavage for the Synthesis of Quinolines

(2012) Yicheng Zhang et al.   ORGANIC LETTERS

Mn-promoted Aerobic Oxidative C–C Bond Cleavage of Aldehydes with Dioxygen Activation: A Simple Synthetic Approach to Formamides

(2012) Chun Zhang et al.   ORGANIC LETTERS

A novel and metal-free approach towards α-ketoamides using a TBHP/I2-promoted tandem reaction of amines with β-diketones via C–C bond cleavage

(2012) Xiaobin Zhang et al.   RSC Advances

Iron-Catalyzed CH and CC Bond Cleavage: A Direct Approach to Amides from Simple Hydrocarbons

(2011) Chong Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Efficient and General Iron-Catalyzed CC Bond Activation with 1,3-Dicarbonyl Units as a Leaving Groups

(2011) Huanrong Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Intramolecular Ullmann-Type O-Arylation: Synthesis of Chromone Derivatives

(2011) Jie Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative CH Bond Arylation of Thiophenes

(2011) Peng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Cleavage of a Carbon-Carbon Single Bond between Carbonyl Carbon and α-Carbon Atoms of Ketones

(2011) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia

(2011) Kazuya Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of the α-Ketoacid-Hydroxylamine Amide-Forming Ligation

(2011) Ivano Pusterla et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Amide Synthesis from Alcohols and Amines by Virtue of a Water-Soluble Gold/DNA Catalyst

(2011) Ye Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Formation of CC and CN Bonds through Palladium-Catalyzed Dual CH Activation: Synthesis of Phenanthridinones

(2011) Guan-Wu Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A highly efficient TBAF-promoted intramolecular cyclization of gem-dibromoolefins for the synthesis of 2-bromobenzofurans(thiophenes)

(2011) Wei Chen et al.   CHEMICAL COMMUNICATIONS

Direct amidation of azoles with formamides via metal-free C–H activation in the presence of tert-butyl perbenzoate

(2011) Tao He et al.   CHEMICAL COMMUNICATIONS

Direct use of dioxygen as an oxygen source: catalytic oxidative synthesis of amides

(2011) Wei Wei et al.   CHEMICAL COMMUNICATIONS

Metal-free, organocatalytic cascade formation of C–N and C–O bonds through dual sp3C–H activation: oxidative synthesis of oxazole derivatives

(2011) Jin Xie et al.   CHEMICAL COMMUNICATIONS

Tandem Reactions Leading to Benzo[c]chromen-6-ones and 3-Substituted Isocoumarins

(2011) Xuesen Fan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper(II)-Catalyzed Synthesis of Benzo[f]pyrido[1,2-a]indole-6,11-dione Derivatives via Naphthoquinone Difunctionalization Reaction

(2011) Yun Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal Nitrite: A Powerful Oxidizing Reagent

(2011) Mahiuddin Baidya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Formal [5 + 1]/[2 + 2 + 1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds

(2011) Mu Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Amides via Palladium-Catalyzed Amidation of Aryl Halides

(2011) Huanfeng Jiang et al.   ORGANIC LETTERS

Iron-Catalyzed Oxidation of Tertiary Amines: Synthesis of β-1,3-Dicarbonyl Aldehydes by Three-Component C–C Couplings

(2011) Weiping Liu et al.   ORGANIC LETTERS

EnantioselectiveN-Heterocyclic Carbene-Catalyzed Michael Addition to α,β-Unsaturated Aldehydes by Redox Oxidation

(2011) Zi-Qiang Rong et al.   ORGANIC LETTERS

Highly Stereoselective Synthesis of 1,2,3-Trisubstituted Indanes via Oxidative N-Heterocyclic Carbene-Catalyzed Cascades

(2011) Anup Biswas et al.   ORGANIC LETTERS

Direct C2-Alkylation of Azoles with Alcohols and Ethers through Dehydrogenative Cross-Coupling under Metal-Free Conditions

(2011) Tao He et al.   ORGANIC LETTERS

Palladium-Catalyzed Arylative Ring-Opening Reactions of Norbornenols: Entry to Highly Substituted Cyclohexenes, Quinolines, and Tetrahydroquinolines

(2010) Michael Waibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Palladium-Catalyzed Aminocarbonylation of Aryl Halides with CO and Ammonia

(2010) Xiao-Feng Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Aromatic Carbon-Carbon ipso-Substitution Reaction

(2010) Sergio M. Bonesi et al.   CHEMISTRY-A EUROPEAN JOURNAL

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes

(2010) Tetsuaki Fujihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes

(2010) Yasuhiro Hirata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Catalyzed Arylation/C−C Bond Activation: An Approach toward α-Aryl Ketones

(2010) Chuan He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Bond Activation by 1,1-Carboboration of Internal Alkynes

(2010) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleaving carbon–carbon bonds by inserting tungsten into unstrained aromatic rings

(2010) Aaron Sattler et al.   NATURE

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

An Efficient Synthesis of Hydantoins via Sustainable Integration of Coupled Domino Processes

(2010) Meng Gao et al.   ORGANIC LETTERS

Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation

(2010) Bryan Roberts et al.   ORGANIC LETTERS

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Mediated Cleavage of CC Bonds in Vicinal Tricarbonyl Compounds in Water

(2009) Jasmin Mecinović et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PPh3-catalyzed unexpected α-addition reaction of 1-(o-hydroxyaryl)-1,3-diketones to terminal alkynoates: a straightforward synthesis of multifunctional vinylesters

(2009) Ling-Guo Meng et al.   CHEMICAL COMMUNICATIONS

Synthesis of Aromatic Esters via Pd-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoesters with Aryl Bromides and Chlorides

(2009) Rui Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An unusual carbon–carbon bond cleavage reaction during phosphinothricin biosynthesis

(2009) Robert M. Cicchillo et al.   NATURE

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amide bond formation: beyond the myth of coupling reagents

(2008) Eric Valeur et al.   CHEMICAL SOCIETY REVIEWS

Molecule of the Month

(2008) Craig Lindsley   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

(2008) Lars Ulrik Nordstrøm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines

(2008) Ashley M. Dreis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Ruthenium(II) Porphyrin Catalyzed Amidation of Aldehydes

(2007) Joyce Wei Wei Chang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds

(2007) Mamoru Tobisu et al.   CHEMICAL SOCIETY REVIEWS