Formyl Substituent at C-4 of Pyrazoles: A Temporary Protecting Group for Regioselective Palladium-Catalyzed Direct Arylation at C-5

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Benzenesulfonyl chlorides: new reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes

(2013) Kedong Yuan et al.   Chemical Science

Palladium-Catalysed Direct Polyarylation of Pyrrole Derivatives

(2012) Liqin Zhao et al.   ChemCatChem

A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst

(2012) Atanu Modak et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Direct Arylation of 5-Chloropyrazoles: A Selective Access to 4-Aryl Pyrazoles

(2012) Tao Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct arylation of dithienylperfluorocyclopentenes via palladium-catalysed C–H bond activation: a simpler access to photoswitches

(2012) Kassem Beydoun et al.   Catalysis Science & Technology

Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles

(2012) Sergei I. Kozhushkov et al.   Catalysis Science & Technology

Efficient synthesis of 1,3-diaryl-4-halo-1H-pyrazoles from 3-arylsydnones and 2-aryl-1,1-dihalo-1-alkenes

(2011) Yiwen Yang et al.   Beilstein Journal of Organic Chemistry

Palladium-catalysed direct arylation of a tris-cyclometallated Ir(iii) complex bearing 2,2′-thienylpyridine ligands: a powerful tool for the tuning of luminescence properties

(2011) Kassem Beydoun et al.   CHEMICAL COMMUNICATIONS

Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation

(2011) Cedric Fischmeister et al.   GREEN CHEMISTRY

A novel three-step synthesis of Celecoxib via palladium-catalyzed direct arylation

(2011) Steven M. Gaulier et al.   TETRAHEDRON LETTERS

Evaluation of Electron-Deficient Phosphine Ligands for Direct Arylation of Heterocycles

(2010) Olivier René et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Synthesis of Pyrazolo[5,1-a]isoindoles via Intramolecular Palladium-Catalyzed CH Bond Activation

(2010) Young Lok Choi et al.   ADVANCED SYNTHESIS & CATALYSIS

Regioselective Palladium-Catalyzed Arylation of 4-Chloropyrazoles

(2010) Carlos Mateos et al.   ORGANIC LETTERS

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

C−H Bonds as Ubiquitous Functionality: A General Approach to Complex Arylated Pyrazoles via Sequential RegioselectiveC-Arylation andN-Alkylation Enabled by SEM-Group Transposition

(2009) Roman Goikhman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON