Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes

Highly Efficient Redox Isomerization of Allylic Alcohols and Transfer Hydrogenation of Ketones and Aldehydes Catalyzed by Ruthenium Complexes

(2011) Pei Nian Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis

(2011) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ir-catalysed formation of C−F bonds. From allylic alcohols to α-fluoroketones

(2011) Nanna Ahlsten et al.   CHEMICAL COMMUNICATIONS

Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols

(2011) Luca Mantilli et al.   CHEMISTRY LETTERS

Ruthenium(IV)-Catalyzed Isomerization of the CC Bond of O-Allylic Substrates: A Theoretical and Experimental Study

(2011) Adrián Varela-Álvarez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Asymmetric Isomerization of Primary Allylic Alcohols with an Iridium-N,P Complex

(2011) Jia-Qi Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of β-Hydroxy and β-Amino Ketones from Allylic Alcohols Catalyzed by Ru(η5-C5Ph5)(CO)2Cl

(2011) Agnieszka Bartoszewicz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Tandem Isomerization-Mannich Reaction for the Enantioselective Synthesis of β-Amino Ketones and β-Amino Alcohols with Applications as Key Intermediates for ent-Nikkomycins and ent-Funebrine

(2011) Hai Thuong Cao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Structure of Ruthenium(IV) Complexes Featuring N-Heterocyclic Ligands with an N–H Group as the Hydrogen-Bond Donor: Hydrogen Interactions in Solution and in the Solid State

(2011) Josefina Díez et al.   INORGANIC CHEMISTRY

Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones

(2011) Piotr Kwiatkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Turnover Supramolecular Catalysis by a Protected Ruthenium(II) Complex in Aqueous Solution

(2011) Casey J. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Reductive Amination of Allylic Alcohols

(2011) Zeyneb Sahli et al.   ORGANIC LETTERS

Redox Isomerization of Allylic Alcohols into Carbonyl Compounds Catalyzed by the Ruthenium(IV) Complex [Ru(η3:η3-C10H16)Cl(κ2O,O-CH3CO2)] in Water and Ionic Liquids: Highly Efficient Transformations and Catalyst Recycling

(2011) Joaquín García-Álvarez et al.   ORGANOMETALLICS

Alternative Approaches to Enolate Chemistry

(2011) Tom Sheppard   SYNLETT

Towards Greener Fluorine Organic Chemistry: Direct Electrophilic Fluorination of Carbonyl Compounds in Water and Under Solvent-Free Reaction Conditions

(2010) Gaj Stavber et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in Catalytic Enantioselective Fluorination Reactions

(2010) Sylvain Lectard et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Improved Catalysts for the Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis

(2010) Luca Mantilli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of γ-Pyrones by Three Consecutive Redox-Aldol Reactions of Allylic Alcohols with α,β-Unsaturated Aldehydes

(2010) Akio Mizuno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances in Catalytic Enantioselective Fluorination of Active Methines

(2010) Young Ku Kang et al.   CURRENT ORGANIC CHEMISTRY

Rhodium-catalysed isomerisation of allylic alcohols in water at ambient temperature

(2010) Nanna Ahlsten et al.   GREEN CHEMISTRY

Catalysis of redox isomerization of allylic alcohols by [RuClCp(mPTA)2](OSO2CF3)2 and [RuCp(mPTA)2(OH2-κO)](OSO2CF3)3·(H2O)(C4H10O)0.5. Unusual influence of the pH and interaction of phosphate with catalyst on the reaction rate

(2010) Beatríz González et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability Studies

(2010) Arturo Azua et al.   ORGANOMETALLICS

Preparation of Cp-Functionalized N-Heterocyclic Carbene Complexes of Ruthenium. Resolution of Chiral Complexes and Catalytic Studies

(2010) André Pontes da Costa et al.   ORGANOMETALLICS

Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate

(2010) María Batuecas et al.   ORGANOMETALLICS

Rhodium-Catalysed Coupling of Allylic, Homoallylic, and Bishomoallylic Alcohols with Aldehydes andN-Tosylimines: Insights into the Mechanism

(2009) Nanna Ahlsten et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Mediated Reactions for Csp2F Bond Construction: The State of Play

(2009) John M. Brown et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols

(2009) Luca Mantilli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanded scope for the iridium-catalyzed asymmetric isomerization of primary allylic alcohols using readily accessible second-generation catalysts

(2009) Luca Mantilli et al.   CHEMICAL COMMUNICATIONS

Fluorine & chirality: how to create a nonracemic stereogenic carbon–fluorine centre?

(2009) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media

(2009) Paul Servin et al.   DALTON TRANSACTIONS

Ruthenium-catalyzed redox isomerization/transfer hydrogenation in organic and aqueous media: A one-pot tandem process for the reduction of allylic alcohols

(2009) Victorio Cadierno et al.   GREEN CHEMISTRY

Highly water-soluble arene-ruthenium(ii) complexes: application to catalytic isomerization of allylic alcohols in aqueous medium

(2009) Beatriz Lastra-Barreira et al.   GREEN CHEMISTRY

Tandem Isomerization-Mannich Reactions from Allylic Alcohols and their Use for the Preparation of Four Diastereoisomers of 1-Amino-2-Methyl-1- Phenyloctan-3-ol

(2009) Hai Cao et al.   LETTERS IN ORGANIC CHEMISTRY

Building Molecular ComplexityviaTandem Ru-catalyzed Isomerization/C−H Activation

(2009) Agnieszka Bartoszewicz et al.   ORGANIC LETTERS

Micellar-System-Mediated Direct Fluorination of Ketones in Water

(2009) Stojan Stavber et al.   SYNLETT

Iridium-catalyzed isomerization of primary allylic alcohols under mild reaction conditions

(2009) Luca Mantilli et al.   TETRAHEDRON LETTERS

Synthetic Scope of Ru(OH)x/Al2O3-Catalyzed Hydrogen-Transfer Reactions: An Application to Reduction of Allylic Alcohols by a Sequential Process of Isomerization/Meerwein-Ponndorf-Verley-Type Reduction

(2008) Jung Won Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Synthesis of β-Hydroxy Ketones from Allylic Alcohols by Catalytic Formation of Ruthenium Enolates

(2008) Agnieszka Bartoszewicz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pentamethylcyclopentadienyl ruthenium: an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds

(2008) Asmae Bouziane et al.   TETRAHEDRON

Catalytic Asymmetric Fluorination Comes of Age

(2007) Vincent A. Brunet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox isomerisation of allylic alcohols catalysed by water-soluble ruthenium complexes in aqueous systems

(2007) Tatiana Campos-Malpartida et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY