Journal
ORGANIC LETTERS
Volume 11, Issue 8, Pages 1749-1752Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900243x
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- Swedish Research Council (Vetenskapsradet)
- Berzelius Center Exselent
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A tandem isomerization/C-H activation of allylic alcohols was performed using a catalytic amount of RUCl2(PPh3)(3). A variety of ortho alkylated ketones have been obtained in excellent yields. This tandem process relies on an in situ generation of a carbonyl functional group that directs the ortho C-H bond activation.
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