Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 275-280Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000667
Keywords
aldehydes; isomerization; ketones; reduction; ruthenium
Categories
Funding
- NSFC [20902020]
- Shanghai Pujiang Talent Program [09J1403500]
- Fundamental Research Funds for the Central Universities
- Hong Kong Research Grant Council [PolyU 5006/07P]
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A dicationic dichloro-bipyridine-ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl-bipyridine-ruthenium complex shows reverse catalytic activities in the two reactions.
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