Article
Chemistry, Applied
Mingyang Gao, Jiamin Wang, Weixiang Shang, Yuchao Chai, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li
Summary: Suzuki-Miyaura cross-coupling reaction is a powerful method to construct carbon-carbon bonds and is widely used in the synthesis of functional organic compounds. In this study, zeolite-encased Pd particles (Pd@MFI) were successfully prepared and investigated as promising heterogeneous catalysts for the Suzuki-Miyaura cross-coupling reaction. The Pd@MFI catalysts showed high activity, with dispersed Pd particles efficiently stabilized within the MFI zeolite matrix. The presence of basic sites adjacent to Pd sites was crucial for achieving high catalytic activity.
Review
Chemistry, Physical
Brijesh S. Kadu
Summary: Palladium has been widely used in the Suzuki-Miyaura cross coupling reaction for over 30 years, but it comes with drawbacks such as high cost, tedious work-ups, product contamination, and metal leaching. In recent years, other metals like Ni, Cu, Co, Fe, Rh, and Ru have attracted attention for their potential in SMCR, allowing for the synthesis of industrially important compounds with various functional groups. This review discusses recent advancements in catalysis related to SMCR, providing valuable insights for researchers in designing synthetic protocols for pharmacophores and drug molecules.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Timothy B. Boit, Milauni M. Mehta, Junyong Kim, Emma L. Baker, Neil K. Garg
Summary: This study presents a new method for adding two different nucleophiles to the carbonyl carbon of an amide in a single step, leading to the conversion of amides to chiral alcohols. The use of non-precious-metal catalysis enables this one-pot process, potentially allowing for the development of new transformations converting carboxylic acid derivatives to functional groups with stereogenic centers.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Materials Science, Multidisciplinary
Khaoula Oudghiri, Lahoucine Bahsis, Said Eddarir, Hafid Anane, Moha Taourirte
Summary: A green protocol for the in situ synthesis of Pd nanoparticles on chitosan beads (Pd NPs-CS) without toxic reducing agents was reported. The Pd nanoparticles catalyst was prepared by a simple coordination reaction between chitosan beads and palladium ions. The Pd NPs-CS catalyst showed high catalytic activity and selectivity in Suzuki-Miyaura cross-coupling reaction and Heck reaction, with the bead form of the catalyst easily separated from the reaction mixture.
Article
Chemistry, Organic
Shoaib Iqbal, Muhammad Sharif, Peter Langer
Summary: This review discusses the importance and impact of Suzuki-Miyaura coupling reactions of fluorinated arenes in chemical and biological research, as well as their applications in various aspects.
Article
Chemistry, Multidisciplinary
Anindita Dewan, Manashi Sarmah, Prantika Bhattacharjee, Pankaj Bharali, Ashim J. Thakur, Utpal Bora
Summary: This study reports the design, synthesis, and application of naturally occurring cellulose from agro waste pomegranate peel as a novel support for active biogenic Pd nanoparticles for Suzuki-Miyaura and Sonogashira cross-coupling reactions at room temperature. The cellulose matrix enables well dispersion of Pd nanoparticles over the support to generate Pd@cellulose, exhibiting excellent catalytic activity and recyclability under ligand-free mild reaction conditions. The synthesized cellulose nanofibers and Pd-anchored heterogeneous nanofibers were characterized through various analytical techniques.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2021)
Article
Chemistry, Physical
Elvis N. Nishida, Elder C. Leopoldino, Laize Zaramello, Higor A. Centurion, Renato Goncalves, Ricardo F. Affeldt, Carlos E. M. Campos, Bruno S. Souza
Summary: A novel Pd(II)-polymeric pre-catalyst was successfully prepared and demonstrated good activity in the Suzuki-Miyaura coupling reaction. The catalyst showed recyclability and its performance was affected by the concentration of the cross-coupling partners. The presence of oxygen was found to be crucial in preventing the formation of inactive Pd(0) aggregates.
Article
Chemistry, Physical
Paul O. Peterson, Matthew Joannou, Eric M. Simmons, Steven R. Wisniewski, Junho Kim, Paul J. Chirik
Summary: The synthesis and characterization of phenoxy(imine) iron(II) alkyl precatalysts for C(sp2)-C(sp3) Suzuki-Miyaura cross-coupling reaction is reported. This method utilizes mild alkoxide bases and nonpolar solvents to achieve high efficiency C(sp2)-C(sp3) bond formation with various aryl boronic esters and alkyl bromides. The study also highlights the compatibility of the precatalysts with base-sensitive functionality and the role of boronate intermediates in transmetalation.
Article
Chemistry, Applied
Vikas Yadav, Vijaykumar Chavan
Summary: This study presents a novel synthesis method for the sustainable, cost-effective, and environmentally friendly Schiff base-Pd nanomagnetic heterogeneous catalyst (MNP-AF-Pd) decorated on superparamagnetic Fe3O4@SiO2 core-shell magnetic nanoparticles. The synthesized catalyst was characterized using various analytical techniques, including TGA, FT-IR, XRD, XPS, ICP-OES, BET, EDX, VSM, FE-SEM, and HR-TEM. The results demonstrated that the MNP-AF-Pd catalyst exhibited excellent catalytic activity for the Suzuki-Miyaura cross-coupling reaction and degradation of hazardous organic dyes. Moreover, the catalyst can be easily recovered and reused for multiple cycles without significant loss of catalytic activity.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Applied
Satya Kumar Avula, Najeeb Ur Rehman, Muhammad U. Anwar, Ghanim Aalthani, Rene Csuk, Ahmed Al-Harrasi
Summary: A series of new para-terphenyl derivatives have been efficiently synthesized using a ligand-free heterogeneous Pd/C-catalyzed two-fold Suzuki-Miyaura coupling reaction. The structures of the new derivatives were confirmed using several analytical techniques, and they were obtained in very good yields. This synthetic facile route shows potential for improving the preparation of para-terphenyl-based natural products.
NATURAL PRODUCT RESEARCH
(2022)
Article
Chemistry, Physical
Han Shen, Jingyi He, Feng He, Yurui Xue, Yongjun Li, Yuliang Li
Summary: In this study, N-doped graphdiyne was synthesized as the support for metal nanoparticles by bottom-up approach from tetraethynylpyrazine. The specific introduction of pyridine nitrogen atoms in the N-doped carbon material makes it a promising material for supporting ultrafine metal particles or clusters. Microwave-assisted anchoring of Pd, Pt, Cu, Ni nanoparticles on NGDY generated novel hybrid composites with Pd-NGDY showing high versatility for Suzuki-Miyaura reaction.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Polymer Science
Laura Riva, Gloria Nicastro, Mingchong Liu, Chiara Battocchio, Carlo Punta, Alessandro Sacchetti
Summary: This article highlights the importance of designing and synthesizing durable heterogeneous catalysts from renewable sources derived from biomass waste. It presents an efficient method for loading Pd(II) ions on a cellulose-based organic support, as well as the application and recycling performance of this support in Suzuki-Miyaura coupling reactions.
Article
Chemistry, Multidisciplinary
Sheng-Qi Qiu, Yu Chen, Xiang-Jun Peng, Shi-Jiang He, Jun Kee Cheng, Yong-Bin Wang, Shao-Hua Xiang, Jun Song, Peiyuan Yu, Junmin Zhang, Bin Tan
Summary: In this study, we achieved the arene-alkene Suzuki-Miyaura coupling reaction between hindered aryl halides and vinyl boronates by designing appropriate ligands and reaction parameters. The axially chiral acyclic aryl-alkenes obtained exhibited remarkable efficiency, enantioselectivity, and E/Z selectivity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
L. Reginald Mills, David Gygi, Jacob R. Ludwig, Eric M. Simmons, Steven R. Wisniewski, Junho Kim, Paul J. Chirik
Summary: In this study, efficient precatalysts for the C(sp(2))-C(sp(3)) Suzuki-Miyaura cross-coupling reaction between alkyl bromides and neopentylglycol (hetero)arylboronic esters were generated in situ using Cobalt(II) halides in combination with phenoxyimine (FI) ligands. The protocol allowed for efficient C-C bond formation with various nucleophiles and electrophiles. The results also suggested that alkyl radicals play an important role in the catalytic reaction.
Editorial Material
Chemistry, Multidisciplinary
Javier F. Reynes, Felipe Garcia
Summary: Several mechanochemically heated processes have been published, but precise control over mechanochemical catalysed coupling reactions has been difficult. A recent report demonstrates a programmable jar heater manifold that efficiently enables the Suzuki-Miyaura-type cross coupling reaction of aryl sulfamates and aryl boronic acid species. This methodology can be easily upscaled 200-fold using twin-screw extrusion methodologies.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Sanjay N. Jadhav, Chandrashekhar V. Rode
Article
Chemistry, Organic
Sanjay Jadhav, Gajanan Rashinkar, Rajashri Salunkhe, Arjun Kumbhar
TETRAHEDRON LETTERS
(2017)
Article
Chemistry, Physical
Sagar More, Sanjay Jadhav, Rajashri Salunkhe, Arjun Kumbhar
MOLECULAR CATALYSIS
(2017)
Article
Chemistry, Multidisciplinary
Bipin Shinde, Santosh Kamble, Pramod Gaikwad, Vishvanath Ghanwat, Sagar Tanpure, Pavan Pagare, Bhausaheb Karale, Arvind Burungale
RESEARCH ON CHEMICAL INTERMEDIATES
(2018)
Article
Chemistry, Multidisciplinary
Bipin Shinde, Santosh B. Kamble, Harsharaj S. Jadhav, Bhausaheb K. Karale, Kaluram G. Kanade, Arvind S. Burungale
Article
Chemistry, Multidisciplinary
Bipin Shinde, Santosh B. Kamble, Dattaprasad M. Pore, Prasad Gosavi, Amol Gaikwad, Harsharaj S. Jadhav, Klbhausaheb K. Karale, Arvind S. Burungale
Article
Chemistry, Inorganic & Nuclear
Sanjay Jadhav, Seema Patil, Arjun Kumbhar, Santosh Kamble, Rajashri Salunkhe
TRANSITION METAL CHEMISTRY
(2019)
Article
Chemistry, Physical
Sanjay N. Jadhav, Seema P. Patil, Dipti Prava Sahoo, Dharitri Rath, Kulamani Parida, Chandrashekhar V. Rode
Article
Chemistry, Organic
Aboli Sapkal, Santosh Kamble
JOURNAL OF HETEROCYCLIC CHEMISTRY
(2020)
Article
Chemistry, Multidisciplinary
Suraj R. Attar, Bipin Shinde, Santosh B. Kamble
RESEARCH ON CHEMICAL INTERMEDIATES
(2020)
Article
Chemistry, Multidisciplinary
Bipin Shinde, Santosh Kamble, Harsharaj Jadhav, Prasad Mane, Kalpesh Khude, Hern Kim, Bhausaheb Karale, Arvind Burungale
Summary: This study investigated the biogenic synthesis of copper oxide nanoparticles from Alpinia zerumbet leaf extract, which showed efficient reactivity, stability, and recyclability in a water solution of NaPTS hydrotrope. The catalytic system formed by CuO NPs fabricated from A. zerumbet leaf extract in combination with NaPTS proved to be the best in terms of yield and reaction time in water at room temperature.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Review
Chemistry, Inorganic & Nuclear
Archana Rajmane, Sanjay Jadhav, Arjun Kumbhar
Summary: Pd-catalyzed cross-coupling reactions are crucial in achieving valuable organic transformations, and recent developments have focused on phosphine-free ligands such as N-heterocyclic carbenes and amines, which offer broad scope and environmental friendliness.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2022)
Review
Chemistry, Multidisciplinary
Aboli Sapkal, Santosh Kamble
Proceedings Paper
Nanoscience & Nanotechnology
Chaitali S. Bagade, Vishvanath B. Ghanwat, Santosh B. Kamble, Popatrao N. Bhosale
EMERGING TECHNOLOGIES: MICRO TO NANO (ETMN-2017)
(2018)
