Rhodium(III)-Catalyzed Amidation of Unactivated C(sp3)H Bonds

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tandem Catalytic C(sp3)H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents

(2015) Julien Buendia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Activation of C sp 3H Bonds and Subsequent Intermolecular Amidation at Room Temperature

(2015) Xiaolei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*RhIII-Catalyzed Arylation of C(sp3)H Bonds

(2015) Xiaoming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)/PAr3-Catalyzed Intermolecular Amination of C(sp3)H Bonds: Synthesis of β-Amino Acids

(2015) Jian He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent

(2015) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Alkenylation Reactions of 8-Methylquinolines with Alkynes by C(sp3)H Activation

(2014) Bingxian Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Light-Induced Ruthenium-Catalyzed Nitrene Transfer Reactions: A Photochemical Approach towards N-Acyl Sulfimides and Sulfoximines

(2014) Vincent Bizet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)–H Functionalization

(2014) Nuancheng Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source

(2014) Sae Hume Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

(2014) Ba L. Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

(2014) Andrew McNally et al.   NATURE

Rhodium(III)-Catalyzed Coupling of Arenes with 7-Oxa/Azabenzonorbornadienes by CH Activation

(2013) Zisong Qi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

(2013) Yota Nishioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Cp*RhCl2]2-catalyzed ortho-C–H bond amination of acetophenone o-methyloximes with primary N-chloroalkylamines: convenient synthesis of N-alkyl-2-acylanilines

(2013) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

Nonheme Iron-Mediated Amination of C(sp3)–H Bonds. Quinquepyridine-Supported Iron-Imide/Nitrene Intermediates by Experimental Studies and DFT Calculations

(2013) Yungen Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

(2013) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture

(2013) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed C–H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

(2013) Songjie Yu et al.   ORGANIC LETTERS

Rh[III]-Catalyzed C–H Amidation Using Aroyloxycarbamates To Give N-Boc Protected Arylamines

(2013) Christoph Grohmann et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular N-Chelator-Directed Aromatic C–H Amidation with Amides

(2013) Huaiqing Zhao et al.   ORGANIC LETTERS

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Rhodium-Catalyzed Oxidativeortho-Acylation of Aryl KetoneO-Methyl Oximes with Aryl and Alkyl Aldehydes

(2012) Yaxi Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular C(sp3)H Amidation

(2012) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Sultams by Rhodium(III)-Catalyzed Directed CH Activation

(2012) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

(2012) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective intermolecular C–H amination reactions

(2012) Hélène Lebel et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of 2,5-Disubstituted Oxazoles and Oxazolines Catalyzed by Ruthenium(II) Porphyrin and Simple Copper Salts

(2012) Chuan Long Zhong et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Ritter-Type C–H Amination of Unactivated sp3 Carbons

(2012) Quentin Michaudel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed N-Nitroso-Directed C–H Olefination of Arenes. High-Yield, Versatile Coupling under Mild Conditions

(2012) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)–H/C(sp3)–H and C(sp2)–H/O–H Bonds

(2012) Xing Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

(2011) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed CH Bond Activation: Application to the Total Synthesis of Oxychelerythrine

(2011) Jayachandran Jayakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C sp 3H Bonds

(2011) Jun Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

(2011) Thomas A. Ramirez et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Amidation of Unactivated C(sp3)H Bonds: from Anilines to Indolines

(2009) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes

(2009) Seth L. Marquard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbonyldiimidazole-Mediated Lossen Rearrangement

(2009) Pascal Dubé et al.   ORGANIC LETTERS

Enantioselective CH Amination Using Cationic Ruthenium(II)-pybox Catalysts

(2008) Erika Milczek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Nitrene Complexes in Catalytic CH Amination

(2008) Yosra M. Badiei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY