Cobalt-Catalyzed Negishi Cross-Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Cross-Coupling of Organozinc Halides with Bromoalkynes

(2014) Martin Corpet et al.   ADVANCED SYNTHESIS & CATALYSIS

Total Synthesis of (±)-Paroxetine by Diastereoconvergent Cobalt-Catalysed Arylation

(2014) Carole F. Despiau et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Strategies To Prepare and Use Functionalized Organometallic Reagents

(2014) Thomas Klatt et al.   JOURNAL OF ORGANIC CHEMISTRY

Beyond Directed ortho Metalation: Ru-Catalyzed CAr–O Activation/Cross-Coupling Reaction by Amide Chelation

(2014) Yigang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins

(2014) Junfeng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Co(III)-Catalyzed C–H Activation/Formal SN-Type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation

(2014) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed ortho Metalation Strategies. Effective Regioselective Routes to 1,2-, 2,3-, and 1,2,3-Substituted Naphthalenes

(2014) Katherine Groom et al.   ORGANIC LETTERS

Cobalt-Mediated Diastereoselective Cross-Coupling Reactions between Cyclic Halohydrins and Arylmagnesium Reagents

(2014) Jeffrey M. Hammann et al.   ORGANIC LETTERS

Iron- and Cobalt-Catalyzed Arylation of Azetidines, Pyrrolidines, and Piperidines with Grignard Reagents

(2014) Baptiste Barré et al.   ORGANIC LETTERS

Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation

(2014) A. J. Martinez-Martinez et al.   SCIENCE

Negishi coupling reactions as a valuable tool for [11C]methyl-arene formation; first proof of principle

(2013) S. Kealey et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Diastereoselective Synthesis of C-Furanosides. Total Synthesis of (−)-Isoaltholactone

(2013) Lionel Nicolas et al.   JOURNAL OF ORGANIC CHEMISTRY

Selective Co/Ti Cooperatively Catalyzed Biaryl Couplings of Aryl Halides with Aryl Metal Reagents

(2013) Jing Zeng et al.   ORGANIC LETTERS

Diastereoselective Metal-Catalyzed Synthesis ofC-Aryl andC-Vinyl Glycosides

(2012) Lionel Nicolas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents

(2012) Jörg T. Binder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid-Triggered Selective Zincation of Chromones, Quinolones, and Thiochromones: Application to the Preparation of Natural Flavones and Isoflavones

(2012) Lydia Klier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereoselective Iron-Mediated C(sp2)C(sp3) Cross-Coupling Reactions between Aryl Grignard Reagents and Cyclic Iodohydrine Derivatives

(2011) Andreas K. Steib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6-Tetramethylpiperidyl Bases

(2011) Tomke Bresser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An overview of the key routes to the best selling 5-membered ring heterocyclic pharmaceuticals

(2011) Marcus Baumann et al.   Beilstein Journal of Organic Chemistry

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Negishi Cross-Coupling Reactions of Secondary Alkylzinc Halides and Aryl Iodides

(2011) Amruta Joshi-Pangu et al.   ORGANIC LETTERS

Cobalt-catalyzed C–SMe bond activation of heteroaromatic thioethers

(2010) Jeanne-Marie Begouin et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Cross-Coupling Reactions

(2010) Gérard Cahiez et al.   CHEMICAL REVIEWS

Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Halides

(2010) Corinne Gosmini et al.   ISRAEL JOURNAL OF CHEMISTRY

Regio- and Chemoselective Zincation of Sensitive and Moderately Activated Aromatics and Heteroaromatics Using TMPZnCl·LiCl

(2010) Tomke Bresser et al.   JOURNAL OF ORGANIC CHEMISTRY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Negishi Alkyl−Aryl Cross-Coupling Catalyzed by Rh: Efficiency of Novel Tripodal 3-Diphenylphosphino-2-(diphenylphosphino)methyl-2-methylpropyl Acetate Ligand

(2010) Syogo Ejiri et al.   ORGANIC LETTERS

Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl·LiCl

(2010) Tomke Bresser et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Scaleable Preparation of Functionalized OrganometallicsviaDirected Ortho Metalation Using Mg- and Zn-Amide Bases

(2010) Stefan H. Wunderlich et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

High temperature zincation of functionalized aromatics and heteroaromatics using TMPZnCl·LiCl and microwave irradiation

(2009) Marc Mosrin et al.   CHEMICAL COMMUNICATIONS

Regio- and Chemoselective Metalation of Chloropyrimidine Derivatives with TMPMgCl⋅LiCl and TMP2Zn⋅2 MgCl2⋅2 LiCl

(2009) Marc Mosrin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-Catalyzed Negishi Alkyl-Aryl Cross-Coupling Leading to α- or β-Phosphoryl-Substituted Alkylarenes

(2009) Hideki Takahashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Cross-Coupling Between In Situ Prepared Arylzinc Halides and 2-Chloropyrimidine or 2-Chloropyrazine

(2009) Jeanne-Marie Bégouin et al.   JOURNAL OF ORGANIC CHEMISTRY

TMPZnCl·LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics

(2009) Marc Mosrin et al.   ORGANIC LETTERS

Regio- and Chemoselective Multiple Functionalization of Chloropyrazine Derivatives. Application to the Synthesis of Coelenterazine

(2009) Marc Mosrin et al.   ORGANIC LETTERS

Efficient mono- and bis-functionalization of 3,6-dichloropyridazine using (tmp)2Zn·2MgCl2·2LiCl

(2008) Stefan Wunderlich et al.   CHEMICAL COMMUNICATIONS

Cobalt-catalyzed cross-coupling reactions

(2008) Corinne Gosmini et al.   CHEMICAL COMMUNICATIONS

Iron-catalysed Negishi coupling of benzylhalides and phosphates

(2008) Robin B. Bedford et al.   CHEMICAL COMMUNICATIONS

A New Efficient Catalytic System for the Chemoselective Cobalt-Catalyzed Cross-Coupling of Aryl Grignard Reagents with Primary and Secondary Alkyl Bromides

(2008) Gérard Cahiez et al.   ORGANIC LETTERS