Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of β-Ketocarbonyl Compounds with Allylic Alcohols

Pushing the Limits of Aminocatalysis: Enantioselective Transformations of α-Branched β-Ketocarbonyls and Vinyl Ketones by Chiral Primary Amines

(2015) Long Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

A New Class of Non-C2-Symmetric Ligands for Oxidative and Redox-Neutral Palladium-Catalyzed Asymmetric Allylic Alkylations of 1,3-Diketones

(2015) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric α-Benzoyloxylation of β-Ketocarbonyls by a Chiral Primary Amine Catalyst

(2015) Dehong Wang et al.   ORGANIC LETTERS

Dual Platinum and Pyrrolidine Catalysis in the Direct Alkylation of Allylic Alcohols: Selective Synthesis of Monoallylation Products

(2014) Ryozo Shibuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis by Palladium and a Chiral Phosphoric Acid: Enantioselective Amination of Racemic Allylic Alcohols

(2014) Debasis Banerjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

(2014) Xiaohong Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Merging Aerobic Oxidation and Enamine Catalysis in the Asymmetric α-Amination of β-Ketocarbonyls UsingN-Hydroxycarbamates as Nitrogen Sources

(2014) Changming Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic–cooperative combination of enamine catalysis with transition metal catalysis

(2014) Yongming Deng et al.   CHEMICAL COMMUNICATIONS

Asymmetric Enamine Catalysis with β-Ketoesters by Chiral Primary Amine: Divergent Stereocontrol Modes

(2014) Changming Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates

(2014) Wenyong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters

(2014) Yunbo Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Bond-Activated Palladium-Catalyzed Allylic Alkylation via Allylic Alkyl Ethers: Challenging Leaving Groups

(2014) Xiaohong Huo et al.   ORGANIC LETTERS

Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric Allylic Alkylation of Pyrazol-5-ones with Allylic Alcohols: The Role of the Chiral Phosphoric Acid in C–O Bond Cleavage and Stereocontrol

(2013) Zhong-Lin Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Palladium-Catalyzed Enantioselective Allylic Alkylations through C-H Activation

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species

(2012) Basker Sundararaju et al.   CHEMICAL SOCIETY REVIEWS

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Direct Regiospecific and Highly Enantioselective Intermolecular α-Allylic Alkylation of Aldehydes by a Combination of Transition-Metal and Chiral Amine Catalysts

(2012) Samson Afewerki et al.   CHEMISTRY-A EUROPEAN JOURNAL

FeCl3·6H2O and TfOH as Catalysts for Allylic Amination Reaction: A Comparative Study

(2012) Paz Trillo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Asymmetric α-Allylation of Ketones with Allylic Alcohols via Pd/Enamine Cooperative Function

(2012) Masakatsu Shibasaki et al.   HETEROCYCLES

Catalytic Enantioselective Alkylations with Allylic Alcohols

(2012) Marco Bandini et al.   SYNTHESIS-STUTTGART

Gold meets enamine catalysis in the enantioselective α-allylic alkylation of aldehydes with alcohols

(2012) Michel Chiarucci et al.   Chemical Science

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Allylic Alcohols: Sustainable Sources for Catalytic Enantioselective Alkylation Reactions

(2011) Marco Bandini   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts

(2011) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds

(2011) Xiaohu Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

(2010) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis

(2009) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation

(2009) Bai-Lin Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Palladium- and Proline-Catalyzed Allylic Alkylation of Enolizable Ketones and Aldehydes with Allylic Alcohols

(2009) Ippei Usui et al.   ORGANIC LETTERS

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION