Journal
ORGANIC LETTERS
Volume 17, Issue 3, Pages 576-579Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol503592n
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Funding
- Natural Science Foundation of China [21390400, 21025208, 21202171]
- National Basic Research Program of China [2011CB808600]
- National Program of Top-notch Young Professionals
- CAS Youth Innovation Promotion Association
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The direct asymmetric a-benzoyloxylation of beta-ketocarbonyls catalyzed by a chiral primary amine is described herein. This protocol demonstrates excellent enantioselectivity for a broad range of substrates, which allows convenient access to highly enantioenriched a-hydroxy-beta-ketocarbonyls.
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