Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst

Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation

(2013) Lukas B. Delvos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes

(2013) Virginie Cirriez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC–Cu(i) catalysed asymmetric conjugate silyl transfer to unsaturated lactones: application in kinetic resolution

(2013) Vittorio Pace et al.   CHEMICAL COMMUNICATIONS

Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile

(2013) Chinmoy K. Hazra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates

(2013) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(I)–NHC Catalyzed Asymmetric Silyl Transfer to Unsaturated Lactams and Amides

(2013) Vittorio Pace et al.   ORGANIC LETTERS

Efficient Routes to Carbon–Silicon Bond Formation for the Synthesis of Silicon-Containing Peptides and Azasilaheterocycles

(2012) Geanna K. Min et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iterative Asymmetric Allylic Substitutions: syn- and anti-1,2-Diols through Catalyst Control

(2012) Jin Kyoon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Efficient Synthesis of α-Tertiary α-Silylamines from Aryl Sulfonylimidates via One-Pot, Sequential C–Si/C–C Bond Formations

(2012) Xiao-Jun Han et al.   ORGANIC LETTERS

Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles

(2012) Eduard Hartmann et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes

(2012) Kang-sang Lee et al.   ORGANOMETALLICS

Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems

(2011) Christian Kleeberg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient, Enantioselective Assembly of Silanediol Protease Inhibitors

(2011) Yingjian Bo et al.   ORGANIC LETTERS

Reductive Lithiation of Methyl Substituted Diarylmethylsilanes: Application to Silanediol Peptide Precursors

(2011) Dácil Hernández et al.   ORGANIC LETTERS

Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines

(2011) Devendra J. Vyas et al.   ORGANIC LETTERS

Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide

(2010) Eduard Hartmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides

(2010) Devendra J. Vyas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Further Studies toward the Stereocontrolled Synthesis of Silicon-Containing Peptide Mimics

(2010) Dácil Hernández et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SmI2-Mediated Radical Cyclizations Directed by a C−Si Bond

(2010) Hassan Y. Harb et al.   ORGANIC LETTERS

Stereocontrolled Synthesis of 2-Substituted-1,3-Azasilaheterocycles

(2010) Dácil Hernández et al.   ORGANIC LETTERS

A Chiral 6-MemberedN-Heterocyclic Carbene Copper(I) Complex That Induces High Stereoselectivity

(2010) Jin Kyoon Park et al.   ORGANIC LETTERS

Synthesis and applications of silicon-containing α-amino acids

(2009) Matthew Mortensen et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon

(2009) Christian Walter et al.   TETRAHEDRON

Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage

(2008) Christian Walter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Alkylation of Imines with Dialkylzinc and Related Reactions

(2008) Ken-ichi Yamada et al.   CHEMICAL REVIEWS

Sequential C−Si Bond Formations from Diphenylsilane: Application to Silanediol Peptide Isostere Precursors

(2008) Lone Nielsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY