Silver-Free Activation of Ligated Gold(I) Chlorides: The Use of [Me3NB12Cl11]−as a Weakly Coordinating Anion in Homogeneous Gold Catalysis

Dual Gold Catalysis

(2014) A. Stephen K. Hashmi   ACCOUNTS OF CHEMICAL RESEARCH

Molecular Complexity from Polyunsaturated Substrates: The Gold Catalysis Approach

(2014) Louis Fensterbank et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions

(2014) Anna Homs et al.   ADVANCED SYNTHESIS & CATALYSIS

Electrophilic activation of allenenes and allenynes: analogies and differences between Brønsted and Lewis acid activation

(2014) T. Cañeque et al.   CHEMICAL SOCIETY REVIEWS

Silver-Free Two-Component Approach in Gold Catalysis: Activation of [LAuCl] Complexes with Derivatives of Copper, Zinc, Indium, Bismuth, and Other Lewis Acids

(2014) Weizhen Fang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Oxidative Carbocyclization-Carbonylation of Allenynes and Enallenes

(2014) Chandra M. R. Volla et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed Cycloisomerization of Yne-Vinylidenecyclopropanes: A Three-Carbon Synthon for [3+2] Cycloadditions

(2014) Wei Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room-Temperature Hydrohydrazination of Terminal Alkynes Catalyzed by Saturated Abnormal N-Heterocyclic Carbene-Gold(I) Complexes

(2014) Rubén Manzano et al.   CHEMISTRY-A EUROPEAN JOURNAL

Inorganic-Organic Heteropolyacid-Gold(I) Hybrids: Structures and Catalytic Applications

(2014) Damien Hueber et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Properties of the Weakly Coordinating Anion [Me3NB12Cl11]−

(2014) Christoph Bolli et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Oxidation of the Three-Dimensional Aromatics [B12X12]2−(X=F, Cl, Br, I)

(2014) René T. Boeré et al.   CHEMISTRY-A EUROPEAN JOURNAL

From Understanding to Prediction: Gold- and Platinum-Based π-Acid Catalysis for Target Oriented Synthesis

(2013) Alois Fürstner   ACCOUNTS OF CHEMICAL RESEARCH

Development of Catalysts and Ligands for Enantioselective Gold Catalysis

(2013) Yi-Ming Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Optimizing P,N-Bidentate Ligands for Oxidative Gold Catalysis: Efficient Intermolecular Trapping of α-Oxo Gold Carbenes by Carboxylic Acids

(2013) Kegong Ji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Aerobic Domino Oxidative Carbocyclization-Alkynylation of Allenynes

(2013) Chandra M. R. Volla et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Salts as Additives in Gold(I)-Catalyzed Reactions

(2013) Amandine Guérinot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Propargyl vinyl ethers as heteroatom-tethered enyne surrogates: diversity-oriented strategies for heterocycle synthesis

(2013) Zhi-Bin Zhu et al.   CHEMICAL COMMUNICATIONS

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine

(2013) María J. López-Gómez et al.   CHEMICAL COMMUNICATIONS

Intermolecular Gold-Catalyzed Cycloaddition of Alkynes with Oxoalkenes

(2013) Carla Obradors et al.   CHEMISTRY-A EUROPEAN JOURNAL

NIS-Mediated Electrophilic Cyclization of 3-Silyloxy-1,n-enynes

(2013) Florian Huber et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Hydronickelation of Allenes and Its Application to the Hydrocyanative Carbocyclization Reaction of Allene–Ynes and Bis-Allenes

(2013) Yuka Amako et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-Catalyzed Macrocyclization of 1,n-Enynes

(2013) Carla Obradors et al.   ORGANIC LETTERS

On the Silver Effect and the Formation of Chloride-Bridged Digold Complexes

(2013) Anna Homs et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Arylating Carbocyclization of Allenynes

(2012) Youqian Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C sp 3H Bond Activation Triggered by Formation of Metallacycles: Rhodium(I)-Catalyzed Cyclopropanation/Cyclization of Allenynes

(2012) Yoshihiro Oonishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold for the Generation and Control of Fluxional Barbaralyl Cations

(2012) Paul R. McGonigal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinuclear Gold Catalysis: Are Two Gold Centers Better than One?

(2012) Adrián Gómez-Suárez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 1,2-bisalkylidenecyclopentanes from 1,6-allenynes via stereoselective addition of nucleophiles to ruthenacyclopentenes

(2012) Nozomi Saito et al.   CHEMICAL COMMUNICATIONS

From Propargylic Amides to Functionalized Oxazoles: Domino Gold Catalysis/Oxidation by Dioxygen

(2012) A. Stephen K. Hashmi et al.   JOURNAL OF ORGANIC CHEMISTRY

Tempering the Reactivities of Postulated α-Oxo Gold Carbenes Using Bidentate Ligands: Implication of Tricoordinated Gold Intermediates and the Development of an Expedient Bimolecular Assembly of 2,4-Disubstituted Oxazoles

(2012) Yingdong Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Silver Effect” in Gold(I) Catalysis: An Overlooked Important Factor

(2012) Dawei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-free Gold(I) Catalysts for Organic Transformations

(2012) H. Schmidbaur et al.   ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

Gold-Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine

(2011) Rei Kinjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

When gold can do what iodine cannot do: A critical comparison

(2011) Sara Hummel et al.   Beilstein Journal of Organic Chemistry

Electronic Fine-Tuning of Carbene Ligands and its Impact on Gold Catalysis

(2011) Philipp Klahn et al.   ChemCatChem

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

(2011) A. Corma et al.   CHEMICAL REVIEWS

Aurophilic interactions as a subject of current research: an up-date

(2011) Hubert Schmidbaur et al.   CHEMICAL SOCIETY REVIEWS

Gold-Catalyzed Synthesis of 3-Pyrrolidinones and Nitrones from N-Sulfonyl Hydroxylamines via Oxygen-Transfer Redox and 1,3-Sulfonyl Migration

(2011) Hyun-Suk Yeom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Efficient and Diastereoselective Gold(I)-Catalyzed Synthesis of Tertiary Amines from Secondary Amines and Alkynes: Substrate Scope and Mechanistic Insights

(2011) Xin-Yuan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Experimental and Theoretical Investigation of Hydrogenative Cyclization of Allenynes

(2011) Hyo-Tong Kim et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Stereoselective Synthesis of Azacyclic Compounds through a Redox/[2 + 2 + 1] Cycloaddition Cascade of Nitroalkyne Substrates

(2011) Appaso Mahadev Jadhav et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes

(2011) César R. Solorio-Alvarado et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenes

(2011) Patricia García-García et al.   ORGANIC LETTERS

Cationic Dialkyl Metal Compounds of Group 13 Elements (E = Al, Ga, In) Stabilized by the Weakly Coordinating Dianion [B12Cl12]2–

(2011) Mathias Kessler et al.   ORGANOMETALLICS

Gold(i)-catalyzed synthesis of furans and pyrroles via alkyne hydration

(2011) Pierrick Nun et al.   Catalysis Science & Technology

Oxidation of closo-[B12Cl12]2− to the Radical Anion [B12Cl12].− and to Neutral B12Cl12

(2010) René T. Boeré et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Crystal Structure, and Reactivity of the Strong Methylating Agent Me2B12Cl12

(2010) Christoph Bolli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

(2010) Colombe Gronnier et al.   CHEMICAL COMMUNICATIONS

Development of Versatile and Silver-Free Protocols for Gold(I) Catalysis

(2010) Sylvain Gaillard et al.   CHEMISTRY-A EUROPEAN JOURNAL

InI3- or ZnI2-Catalyzed Reaction of Hydroxylated 1,5-Allenynes with Thiols: A New Access to 3,5-Disubstituted Toluene Derivatives

(2010) Jie Ma et al.   Chemistry-An Asian Journal

Alkali metal-sulfur dioxide complexes stabilized by halogenated closo-dodecaborate anions

(2010) Janis Derendorf et al.   DALTON TRANSACTIONS

Synthesis, Characterization, and Crystal Structures of Silylium Compounds of the Weakly Coordinating Dianion [B12Cl12]2−

(2010) Mathias Kessler et al.   INORGANIC CHEMISTRY

Efficient silver-free gold(I)-catalyzed hydration of alkynes at low catalyst loading

(2010) Pierrick Nun et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X−Y] Reagents [X−Y = R3Si−SnR′3or (R2N)2B−SnR′3]: Synthesis and Properties of Atropisomeric 1,3-Dienes

(2010) Ramakrishna Reddy Singidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes

(2010) Verónica López-Carrillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Surprises in the Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes

(2009) Dieter Weber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How to overcome Coulomb explosions in labile dications by using the [B12Cl12]2− dianion

(2009) Carsten Knapp et al.   CHEMICAL COMMUNICATIONS

A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One-Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine

(2009) Xiaoming Zeng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and characterization of synthetically useful salts of the weakly-coordinating dianion [B12Cl12]2−

(2009) Vanessa Geis et al.   DALTON TRANSACTIONS

Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives

(2009) Xiaoming Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Intramolecular Hydroamination/Asymmetric Transfer Hydrogenation under Relay Catalysis of an Achiral Gold Complex/Chiral Brønsted Acid Binary System

(2009) Zhi-Yong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Perfluorination of K2B12H12in Acetonitrile Occurs at the Gas Bubble−Solution Interface and Is Inhibited by HF. Experimental and DFT Study of Inhibition by Protic Acids and Soft, Polarizable Anions

(2009) Dmitry V. Peryshkov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Borylative Cyclization of Allenynes and Enallenes

(2009) Virtudes Pardo-Rodríguez et al.   ORGANIC LETTERS

Gold-Catalyzed Intermolecular Markovnikov Hydroamination of Allenes with Secondary Amines

(2009) Xiaoming Zeng et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Cyclodimerization of Allenynes

(2009) Nozomi Saito et al.   ORGANOMETALLICS

Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Cycloisomerization of 3-Methoxy-1,6-enynes Featuring Tandem Cyclization and [3,3]-Sigmatropic Rearrangement

(2008) Hyo J. Bae et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

(2008) Tomoya Miura et al.   CHEMICAL COMMUNICATIONS

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

Gold catalysis in total synthesis

(2008) A. Stephen K. Hashmi et al.   CHEMICAL SOCIETY REVIEWS

1,2-Alkyl Migration as a Key Element in the Invention of Cascade Reactions Catalyzed by π-Acids

(2008) Benedikt Crone et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in Enantioselective Gold(I) Catalysis

(2008) Ross A. Widenhoefer   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed Hydrative Carbocyclization of 1,5- and 1,7-Allenynes Mediated by π-Allene Complex: Mechanistic Evidence Supported by the Chirality Transfer of Allenyne Substrates

(2008) Chun-Yao Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Cycloisomerization of 1,5-Allenynes via Dual Activation of an Ene Reaction

(2008) Paul Ha-Yeon Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(NHC)AuI]-Catalyzed Acid-Free Alkyne Hydration at Part-per-Million Catalyst Loadings

(2008) Nicolas Marion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Divergence in the Reactivity of 3-Silyloxy 1,6-Enynes: Pinacol-Terminated vs Claisen-Terminated Cyclization Cascades

(2008) Baburaj Baskar et al.   ORGANIC LETTERS

Construction of Heterocycles by the Strategic Use of Alkyne π-Activation in Catalyzed Cascade Reactions

(2008) Stefan Kirsch   SYNTHESIS-STUTTGART

Gold-catalyzed reactivity of 3-silyloxy-1,5-enynes: a synthetic tool for the synthesis of complex structures and its limitations

(2008) Helge Menz et al.   TETRAHEDRON

Alkyne versus Allene Activation in Platinum- and Gold-Catalyzed Cycloisomerization of Hydroxylated 1,5-Allenynes

(2007) Riadh Zriba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-catalyzed benzannulation of 3-hydroxy-1,5-enynes: an efficient synthesis of substituted tetrahydronaphthalenes and related compounds

(2007) Christiane M. Grisé et al.   TETRAHEDRON