Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 696, Issue 1, Pages 37-41Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.06.017
Keywords
Homogeneous catalysis; Gold complexes; Hydroarylation; Cinnoline derivatives
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A study concerning the gold(I)-catalyzed hydroarylation of N-propargyl-N'-arylhydrazinecarboxylic acid methyl esters is described. The use of the gold complex [XPhosAu(NCCH(3))SbF(6)] as the catalyst in refluxing nitromethane allows the generally rapid and efficient synthesis of a range of functionalized 4-exo-methylene-1,2-dihydrocinnolines. (C) 2010 Elsevier B.V. All rights reserved.
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