4.8 Article

Intramolecular σ-Bond Metathesis Between Carbon-Carbon and Silicon-Silicon Bonds

Journal

ORGANIC LETTERS
Volume 14, Issue 12, Pages 3230-3232

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol301280u

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Funding

  1. MEXT
  2. Asahi Glass Foundation
  3. Grants-in-Aid for Scientific Research [22105005] Funding Source: KAKEN

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An intramolecular sigma-bond metathesis between carbon carbon and silicon silicon bonds took place on treatment of a disilane tethered to a cyclobutanone with a palladium(0) catalyst, furnishing a silaindane skeleton as well as an acylsilane functionality at once.

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