4.4 Article

Palladium-catalyzed carbonylative coupling reactions of aryl iodides with hexamethyldisilane (HMDS) to benzoyl silanes

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 5, Pages 582-584

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.11.104

Keywords

Palladium; Carbonylation; Aryl iodides; Acyl silane; HMDS

Funding

  1. state of Mecklenburg-Vorpommern
  2. Bundesministerium fur Bildung und Forschung (BMBF)
  3. DFG

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A novel procedure for the palladium-catalyzed carbonylative synthesis of acyl silanes has been developed. Starting from aryl iodides and hexamethyldisilane (HMDS) various benzoyl silanes are produced in moderate to good yields. (C) 2011 Elsevier Ltd. All rights reserved.

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