Benzylic C(sp3)–H bond sulfonylation of 4-methylphenols with the insertion of sulfur dioxide under photocatalysis

Generation of sulfonated 1-isoindolinones through a multicomponent reaction with the insertion of sulfur dioxide

(2018) Jun Zhang et al.   CHEMICAL COMMUNICATIONS

C–H bond sulfonylation of anilines with the insertion of sulfur dioxide under metal-free conditions

(2018) Kaida Zhou et al.   CHEMICAL COMMUNICATIONS

Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of β-alkynyl propenones

(2018) Zheng-Jia Shen et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Regioselective Cleavage of C−X and C−H Bonds: A Strategy for Sulfur Dioxide Fixation

(2018) Daoshan Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl-Containing Molecules

(2018) Kamil Hofman et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Copper-Catalyzed Three-Component Synthesis of Sulfonamides

(2018) Yiding Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photo-Driven Synthesis of C6-Polyfunctionalized Phenanthridines from Three-Component Reactions of Isocyanides, Alkynes, and Sulfinic Acids by Electron Donor–Acceptor Complex

(2018) Yang Li et al.   ORGANIC LETTERS

Photocatalytic Reaction of Potassium Alkyltrifluoroborates and Sulfur Dioxide with Alkenes

(2018) Tong Liu et al.   ORGANIC LETTERS

Synthesis of Aromatic Sulfonamides through a Copper-Catalyzed Coupling of Aryldiazonium Tetrafluoroborates, DABCO·(SO2)2, and N-Chloroamines

(2018) Feng Zhang et al.   ORGANIC LETTERS

Efficient SO2 Capture and Fixation to Cyclic Sulfites by Dual Ether-Functionalized Protic Ionic Liquids without Any Additives

(2018) Tianxiang Zhao et al.   ACS Sustainable Chemistry & Engineering

A copper-catalyzed sulfonylative C–H bond functionalization from sulfur dioxide and aryldiazonium tetrafluoroborates

(2018) Hongguang Xia et al.   Organic Chemistry Frontiers

Synthesis of sulfonated naphthols via C–H bond functionalization with the insertion of sulfur dioxide

(2018) Kaida Zhou et al.   Organic Chemistry Frontiers

Redox-neutral tri-/difluoromethylation of para-quinone methides with sodium sulfinates

(2018) Qing-Yan Wu et al.   Organic Chemistry Frontiers

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

(2018) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

Generation of sulfonated isobenzofuran-1(3H)-ones under photocatalysis through the insertion of sulfur dioxide

(2018) Jun Zhang et al.   Organic Chemistry Frontiers

A Versatile Reagent and Method for Direct Aliphatic Sulfonylation

(2018) Andre Shavnya et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-catalyzed S-methylation of sulfonyl hydrazides with TBHP for the synthesis of methyl sulfones in water

(2017) Yu Yang et al.   GREEN CHEMISTRY

Synthesis of Sulfonylated Lactones via Ag-Catalyzed Cascade Sulfonylation/Cyclization of 1,6-Enynes with Sodium Sulfinates

(2017) Wanqing Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Conversion of Aryl Iodides to Sulfonyl Fluorides Using SO2 Surrogate DABSO and Selectfluor

(2017) Ariana L. Tribby et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed tandem cyclization/sulfonylation of homoallenyl amides with sodium sulfinates

(2017) Yimei Wan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Construction of Functionalized Annulated Sulfone via SO2/I Exchange of Cyclic Diaryliodonium Salts

(2017) Ming Wang et al.   ORGANIC LETTERS

Pd-Catalyzed Selective Synthesis of Cyclic Sulfonamides and Sulfinamides Using K2S2O5 as a Sulfur Dioxide Surrogate

(2017) Hideyuki Konishi et al.   ORGANIC LETTERS

Copper-Catalyzed Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides Involving Desulfonative Arrangement toward Sulfonated Oxindoles

(2017) Hepan Wang et al.   ORGANIC LETTERS

N-Radical Initiated Aminosulfonylation of Unactivated C(sp3)–H Bond through Insertion of Sulfur Dioxide

(2017) Yuewen Li et al.   ORGANIC LETTERS

Electrooxidative Tandem Cyclization of Activated Alkynes with Sulfinic Acids To Access Sulfonated Indenones

(2017) Jiangwei Wen et al.   ORGANIC LETTERS

Synthesis of 3-(Arylsulfonyl)benzothiophenes and Benzoselenophenes via TBHP-Initiated Radical Cyclization of 2-Alkynylthioanisoles or -selenoanisoles with Sulfinic Acids

(2017) Jian Xu et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct C–H Functionalization of Indoles with the Insertion of Sulfur Dioxide: Synthesis of 2-Sulfonated Indoles

(2017) Tong Liu et al.   ORGANIC LETTERS

Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids

(2017) Yan Zhu et al.   Nature Communications

Cobalt(ii)-catalyzed remote C5-selective C–H sulfonylation of quinolines via insertion of sulfur dioxide

(2017) Kai Wang et al.   RSC Advances

Reductive insertion of sulfur dioxide for the synthesis of trifluoromethyl thiolsulphonates through a one-pot reaction of aniline and trifluoromethanesulfanylamide

(2017) Jie Sheng et al.   Organic Chemistry Frontiers

Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

(2017) Yang Wang et al.   Organic Chemistry Frontiers

Synthesis of Chiral Sulfonyl Lactones via Copper-Catalyzed Asymmetric Radical Reaction of DABCO⋅(SO2 )

(2017) Yang Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Iodide/tert-Butyl Hydroperoxide-Mediated Benzylic C-H Sulfonylation and Peroxidation of Phenol Derivatives

(2016) Wen-Chao Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3-Sulfonated Coumarins

(2016) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Csp3 −H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition

(2016) Chuanyong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iodine-promoted cyclization of N-propynyl amides and N-allyl amides via sulfonylation and sulfenylation

(2016) Gopal Chandru Senadi et al.   CHEMICAL COMMUNICATIONS

Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

(2016) Guoting Zhang et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed synthesis of arylsulfinates through radical coupling reaction

(2016) Weixi Zhang et al.   CHEMICAL COMMUNICATIONS

Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry

(2016) Minghao Feng et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Visible-light initiated direct oxysulfonylation of alkenes with sulfinic acids leading to β-ketosulfones

(2016) Daoshan Yang et al.   GREEN CHEMISTRY

Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts

(2016) Arantxa Rodríguez et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalysed transannular C–H functionalization of alicyclic amines

(2016) Joseph J. Topczewski et al.   NATURE

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Visible light-promoted synthesis of 4-(sulfonylmethyl)isoquinoline-1,3(2H,4H)-diones via a tandem radical cyclization and sulfonylation reaction

(2016) Xu Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Bu4NI-Catalyzed Cross-Coupling between Sulfonyl Hydrazides and Diazo Compounds To Construct β-Carbonyl Sulfones Using Molecular Oxygen

(2016) Yaxiong Wang et al.   ORGANIC LETTERS

I2/TBHP Mediated C–N and C–H Bond Cleavage of Tertiary Amines toward Selective Synthesis of Sulfonamides and β-Arylsulfonyl Enamines: The Solvent Effect on Reaction

(2016) Junyi Lai et al.   ORGANIC LETTERS

One-Step Synthesis of Sulfonamides from N-Tosylhydrazones

(2016) Andy S. Tsai et al.   ORGANIC LETTERS

Reaction of Alkyl Halides with Rongalite: One-Pot and Telescoped Syntheses of Aliphatic Sulfonamides, Sulfonyl Fluorides, and Unsymmetrical Sulfones

(2016) Andre Shavnya et al.   ORGANIC LETTERS

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis

(2016) Gang Liao et al.   Nature Communications

A general route to sulfones via insertion of sulfur dioxide promoted by cobalt oxide

(2016) Danqing Zheng et al.   Organic Chemistry Frontiers

Copper(i)-catalyzed sulfonylation of (2-alkynylaryl)boronic acids with DABSO

(2016) Runyu Mao et al.   Organic Chemistry Frontiers

Generation of (2-oxoindolin-3-yl)methanesulfonohydrazides via a photo-induced reaction of N-(2-iodoaryl)acrylamide, DABSO, and hydrazine

(2016) Kaida Zhou et al.   Organic Chemistry Frontiers

Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp3 )−H Functionalization under Mild Reaction Conditions

(2015) Jing Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox-Neutral, Phosphine-Free Transformation

(2015) Alex S. Deeming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis of (Hetero)Aryl Alkyl Sulfones from (Hetero)Aryl Boronic Acids, Unactivated Alkyl Halides, and Potassium Metabisulfite

(2015) Andre Shavnya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions (Angew. Chem. Int. Ed. 1/2016)

(2015) Stefan Haubenreisser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective remote C–H sulfonylation of aminoquinolines with arylsulfonyl chlorides via copper catalysis

(2015) Hong-Wen Liang et al.   CHEMICAL COMMUNICATIONS

H-phosphonate-mediated sulfonylation of heteroaromatic N-oxides: a mild and metal-free one-pot synthesis of 2-sulfonyl quinolines/pyridines

(2015) Kai Sun et al.   CHEMICAL COMMUNICATIONS

Benzylic C–H trifluoromethylation of phenol derivatives

(2015) Hiromichi Egami et al.   CHEMICAL COMMUNICATIONS

Iodine-Promoted Radical Cyclization in Water: A Selective Reaction of 1,6-Enynes with Sulfonyl Hydrazides

(2015) Lan Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron/Copper Co-Catalyzed Synthesis of Vinyl Sulfones from Sulfonyl Hydrazides and Alkyne Derivatives

(2015) Guangwei Rong et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium(III)-Catalyzed Direct Arylation of C–H Bonds with Diaryliodonium Salts

(2015) Pan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver-Cocatalyst

(2015) Jitan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fixation of sulfur dioxide into small molecules

(2015) Gang Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Nickel-catalyzed synthesis of diarylsulfides and sulfones via C–H bond functionalization of arylamides

(2015) Vutukuri Prakash Reddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed γ-Sulfonylation of α,β-Unsaturated Carbonyl Compounds by Means of Silyl Dienol Ethers

(2015) Xiaoguang Liu et al.   ORGANIC LETTERS

Visible-Light-Promoted Remote C(sp3)–H Amidation and Chlorination

(2015) Qixue Qin et al.   ORGANIC LETTERS

Catalytic Arylsulfonyl Radical Triggered 1,7-Enyne Bicyclizations

(2015) Yi-Long Zhu et al.   ORGANIC LETTERS

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Catalytic arylsulfonyl radical-triggered 1,5-enyne-bicyclizations and hydrosulfonylation of α,β-conjugates

(2015) Zhen-Zhen Chen et al.   Chemical Science

Copper catalyzed synthesis of unsymmetrical diaryl sulfones from an arenediazonium salt and sodium p-toluenesulfinate

(2015) Sitaram Haribhau Gund et al.   RSC Advances

The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

(2015) Edward J. Emmett et al.   Asian Journal of Organic Chemistry

Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

(2015) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

Chemoselective Synthesis of Unsymmetrical Internal Alkynes or Vinyl SulfonesviaPalladium-Catalyzed Cross-Coupling Reaction of Sodium Sulfinates with Alkynes

(2014) Yanli Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Aminosulfonylation of Arenes, Sulfur Dioxide, and Hydrazines Cocatalyzed by Gold(III) Chloride and Palladium Acetate

(2014) Shengqing Ye et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2and Hydrazines

(2014) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

(2014) Miles W. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Coupling of Oxime Acetates with Sodium Sulfinates: An Efficient Synthesis of Sulfone Derivatives

(2014) Xiaodong Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance

(2014) Qing Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic conversion of aryl triazenes into aryl sulfonamides using sulfur dioxide as the sulfonyl source

(2014) Wanfang Li et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed ortho-Sulfonylation of 2-Aryloxypyridines and Subsequent Formation of ortho-Sulfonylated Phenols

(2014) Yinfeng Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines

(2014) Adam Noble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes

(2014) Laura J. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Promoted Alkylation of C(sp3)–H and C(sp2)–H Bonds

(2014) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Copper-Catalyzed Three-Component Reaction of Triethoxysilanes, Sulfur Dioxide, and Hydrazines

(2014) Xianbo Wang et al.   ORGANIC LETTERS

Photoinduced sulfonylation of cyclic ethers

(2014) Shin Kamijo et al.   TETRAHEDRON LETTERS

Synthesis of arylsulfonyl-quinones and arylsulfonyl-1,4-diols as FabH inhibitors: Pd-catalyzed direct C-sulfone formation by CS coupling of quinones with arylsulfonyl chloride

(2014) Bingyang Ge et al.   TETRAHEDRON LETTERS

Copper/Silver-Mediated Cascade Reactions for the Construction of 2-Sulfonylbenzo[b]furans from trans-2-Hydroxycinnamic Acids and Sodium Sulfinates

(2013) Hong-Shuang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

(2013) Philippe Bisseret et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Sulfination of Aryl and Heteroaryl Halides: Direct Access to Sulfones and Sulfonamides

(2013) Andrei Shavnya et al.   ORGANIC LETTERS

Sulfonylation of Quinoline N-Oxides with Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation

(2013) Zhiyong Wu et al.   ORGANIC LETTERS

A palladium-catalyzed reaction of aryl halides, potassium metabisulfite, and hydrazines

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Synthesis, Properties, and Applications of Oligonucleotides Containing an RNA Dinucleotide Phosphorothiolate Linkage

(2011) Nan-Sheng Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Thienoacene-Based Organic Semiconductors

(2011) Kazuo Takimiya et al.   ADVANCED MATERIALS

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dihydronaphthyl-based [60]fullerene bisadducts for efficient and stable polymer solar cells

(2011) Xiangyue Meng et al.   CHEMICAL COMMUNICATIONS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Challenge and progress: palladium-catalyzed sp3 C–H activation

(2011) Hu Li et al.   Catalysis Science & Technology

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2and sp3Carbon−Hydrogen Bonds

(2010) Dmitry Shabashov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of arylsulfonyl chlorides by chlorosulfonylation of in situ generated diazonium salts using a continuous flow reactor

(2010) Laia Malet-Sanz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

(2009) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aqueous Process Chemistry: The Preparation of Aryl Sulfonyl Chlorides

(2009) Philip J. Hogan et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Selective benzylic C–C coupling catalyzed by a bioinspired dicopper complex

(2008) Angelina Prokofieva et al.   CHEMICAL COMMUNICATIONS

Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation

(2008) Song Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY