Metal-free sp3 C–H functionalization: a novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

Metal-Free Preparation of Cycloalkyl Aryl SulfidesviaDi-tert-butyl Peroxide-Promoted Oxidative C(sp3)H Bond Thiolation of Cycloalkanes

(2014) Jincan Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Nickel-Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

(2014) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed CS Bond Coupling Reaction

(2014) Chin-Fa Lee et al.   Chemistry-An Asian Journal

Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

(2014) Jing-Wen Zeng et al.   GREEN CHEMISTRY

C(sp3)–C(sp3) bond formation via copper/Brønsted acid co-catalyzed C(sp3)–H bond oxidative cross-dehydrogenative-coupling (CDC) of azaarenes

(2014) Fang-Fang Wang et al.   GREEN CHEMISTRY

Iron-Catalyzed Synthesis of Thioesters from Thiols and Aldehydes in Water

(2014) Yu-Ting Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conformation-induced remote meta-C–H activation of amines

(2014) Ri-Yuan Tang et al.   NATURE

Palladium Catalyzed Aryl(alkyl)thiolation of Unactivated Arenes

(2014) Perumal Saravanan et al.   ORGANIC LETTERS

Syntheses of Sulfides and Selenides through Direct Oxidative Functionalization of C(sp3)–H Bond

(2014) Bingnan Du et al.   ORGANIC LETTERS

A Free Radical Cascade Cyclization of Isocyanides with Simple Alkanes and Alcohols

(2014) Zejiang Li et al.   ORGANIC LETTERS

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

(2013) Qicai Xue et al.   CHEMICAL COMMUNICATIONS

Transfer of Sulfur: From Simple to Diverse

(2013) Hui Liu et al.   Chemistry-An Asian Journal

Synthesis of thioesters through copper-catalyzed coupling of aldehydes with thiols in water

(2013) Chih-Lun Yi et al.   GREEN CHEMISTRY

Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Chalcogenides from Arenes and Diaryl Dichalcogenides

(2013) Ch Durga Prasad et al.   JOURNAL OF ORGANIC CHEMISTRY

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

(2013) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Metal free sulfenylation and bis-sulfenylation of indoles: persulfate mediated synthesis

(2013) Ch. Durga Prasad et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Free-Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C–H and (sp2)C–H Bond Functionalization

(2013) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

(2013) Sheng-rong Guo et al.   ORGANIC LETTERS

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Versatile Rhodium(I) Catalyst System for the Addition of Heteroarenes to both Alkenes and Alkynes by a CH Bond Activation

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed decarboxylative C(sp2)–C(sp3) coupling reactions via radical mechanism

(2012) Hailong Yang et al.   CHEMICAL COMMUNICATIONS

Experimental study of n-heptane ignition delay with carbon dioxide addition in a rapid compression machine under low-temperature conditions

(2012) HuanYu Guang et al.   CHINESE SCIENCE BULLETIN

Microwave-assisted reaction of aryl diazonium fluoroborate and diaryl dichalcogenides in dimethyl carbonate: a general procedure for the synthesis of unsymmetrical diaryl chalcogenides

(2012) Debasish Kundu et al.   GREEN CHEMISTRY

Palladium-Catalyzed Oxidative Carbonylation of Benzylic C–H Bonds via Nondirected C(sp3)–H Activation

(2012) Pan Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed decarboxylative alkenylation of sp3 C–H bonds with cinnamic acids via a radical process

(2012) Zili Cui et al.   Chemical Science

Organocatalytic Stereoselective Direct Aldol Reaction of Trifluoroethyl Thioesters

(2011) Sergio Rossi et al.   ADVANCED SYNTHESIS & CATALYSIS

Novel C–H functionalization of arenes: palladium-catalyzed synthesis of diaryl sulfides

(2011) Pazhamalai Anbarasan et al.   CHEMICAL COMMUNICATIONS

Synthesis of diaryl ketones via a phosphine-free Fukuyama reaction

(2011) Kamala Kunchithapatham et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

(2011) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Fe-Catalyzed Thioesterification of Carboxylic Esters

(2011) Silja Magens et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines

(2011) Ourida Saidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal Catalyzed Synthesis of Aryl Sulfides

(2011) Chad C. Eichman et al.   MOLECULES

Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C−H Bond with Disulfides

(2010) Shouhui Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Room Temperature Palladium-Catalyzed Decarboxylativeortho-Acylation of Acetanilides with α-Oxocarboxylic Acids

(2010) Ping Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Catalyzed Acylation by Thiol Esters Under Neutral Conditions: Tandem Acylation-Wittig Reaction Leading to a One-Pot Synthesis of Butenolides

(2010) Kazumasa Matsuo et al.   ORGANIC LETTERS

Expedient Drug Synthesis and Diversification via ortho-C−H Iodination using Recyclable PdI2as the Precatalyst

(2010) Tian-Sheng Mei et al.   ORGANIC LETTERS

Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant

(2010) Zhuangzhi Shi et al.   ORGANIC LETTERS

CuS/Fe: a novel and highly efficient catalyst system for coupling reaction of aryl halides with diaryl diselenides

(2010) Yaming Li et al.   TETRAHEDRON

Epimerization-Free Block Synthesis of Peptides from Thioacids and Amines with the Sanger and Mukaiyama Reagents

(2009) David Crich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

(2009) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Thioacids with Isocyanates and Isothiocyanates: A Convenient Amide Ligation Process

(2009) David Crich et al.   ORGANIC LETTERS

Towards Organocatalytic Polyketide Synthases with Diverse Electrophile Scope: Trifluoroethyl Thioesters as Nucleophiles in Organocatalytic Michael Reactions and Beyond

(2008) Diego A. Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Mediated Direct Arylation of Unactivated Arenes

(2008) Jun Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes

(2008) Guojun Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Direct Arylation through Directed C−H Bond Activation

(2008) Jakob Norinder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiol cofactors for selenoenzymes and their synthetic mimics

(2008) Bani Kanta Sarma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids

(2008) Ikuya Ban et al.   ORGANIC LETTERS

Organocatalytic Mannich-Type Reactions of Trifluoroethyl Thioesters

(2008) Naoto Utsumi et al.   ORGANIC LETTERS

Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester−Organostannane Cross-Coupling Using pH-Neutral Conditions

(2008) Hao Li et al.   ORGANIC LETTERS