The use of the sterically demanding IPr* and related ligands in catalysis

Isolation of a Non-Heteroatom-Stabilized Gold-Carbene Complex

(2014) Matthias W. Hussong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalysed carboxylation of organoboronates

(2014) Yusuke Makida et al.   CHEMICAL COMMUNICATIONS

[(1,3-Bis{2,6-bis(diphenylmethyl)-4-methylphenyl}imidazole-2-ylidene)PdCl2(NEt3)]: “Throwing Away” a Different Ancillary Ligand to Enhance the Catalytic Activity at Room Temperature

(2014) Daniel Guest et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Efficient C-N and C-S Bond Formation Using the Highly Active [Ni(allyl)Cl(IPr*OMe)] Precatalyst

(2014) Anthony R. Martin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

[Pd(μ-Cl)Cl(IPr*)]2: a highly hindered pre-catalyst for the synthesis of tetra-ortho-substituted biaryls via Grignard reagent cross-coupling

(2014) Mathieu Lesieur et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

[Pd(IPr*OMe)(cin)Cl] (cin = Cinnamyl): A Versatile Catalyst for C–N and C–C Bond Formation

(2014) Gulluzar Bastug et al.   ORGANOMETALLICS

Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Isolation of a Stable Low-Coordinate T-Shaped Complex

(2014) Adrian B. Chaplin   ORGANOMETALLICS

IPr*(2-Np)—An Exceedingly Bulky N-Heterocyclic Carbene

(2014) Steve Dierick et al.   ORGANOMETALLICS

Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Preparation of Mono-, Bis-, and Tris-ligated NHC Complexes

(2014) Adrian B. Chaplin   ORGANOMETALLICS

Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes

(2013) David S. Weinberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Alba Collado et al.   CHEMICAL COMMUNICATIONS

Palladium-N-heterocyclic carbene (NHC) catalyzed C–N bond formation in a continuous flow microreactor. Effect of process parameters and comparison with batch operation

(2013) Angelo Pommella et al.   CHEMICAL ENGINEERING JOURNAL

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

How does the addition of steric hindrance to a typical N-heterocyclic carbene ligand affect catalytic activity in olefin metathesis?

(2013) Albert Poater et al.   DALTON TRANSACTIONS

Isolable, Copper(I) Dicarbonyl Complexes Supported by N-Heterocyclic Carbenes

(2013) Chandrakanta Dash et al.   INORGANIC CHEMISTRY

Carbon–Sulfur Bond Formation Catalyzed by [Pd(IPr*OMe)(cin)Cl] (cin = cinnamyl)

(2013) Gulluzar Bastug et al.   JOURNAL OF ORGANIC CHEMISTRY

[{Au(NHC)}2(μ-OH)][BF4]: Silver-Free and Acid-Free Catalysts for Water-Inclusive Gold-Mediated Organic Transformations

(2013) Adrián Gómez-Suárez et al.   ORGANOMETALLICS

Enhanced Activity of [Ni(NHC)CpCl] Complexes in Arylamination Catalysis

(2013) Anthony R. Martin et al.   ORGANOMETALLICS

Internal Catalytic Effect of Bulky NHC Ligands in Suzuki–Miyaura Cross-Coupling Reaction

(2013) Tibor Szilvási et al.   ACS Catalysis

Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

(2013) Frédéric Izquierdo et al.   ACS Catalysis

Solvent-free aryl amination catalysed by [Pd(NHC)] complexes

(2013) Anthony Chartoire et al.   RSC Advances

An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]

(2012) Anthony Chartoire et al.   ADVANCED SYNTHESIS & CATALYSIS

The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions

(2012) Cory Valente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts: Direct arylation of heterocycles

(2012) Anthony R Martin et al.   Beilstein Journal of Organic Chemistry

A cationic gold complex cleaves BArF24

(2012) Simone G. Weber et al.   CHEMICAL COMMUNICATIONS

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

(2012) Anthony Chartoire et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isolated Silver Intermediate of Gold Precatalyst Activation

(2012) Simone G. Weber et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Bulky N-Heterocyclic Carbene IPr* in Selected Organo- and Transition Metal-Mediated Catalytic Applications

(2012) János Balogh et al.   ORGANOMETALLICS

Effect of Ligand Bulk in Ruthenium-Catalyzed Olefin Metathesis: IPr* vs IPr

(2012) Simone Manzini et al.   ORGANOMETALLICS

C–H Bond Activation of Methane by PtII–N-Heterocyclic Carbene Complexes. The Importance of Having the Ligands in the Right Place at the Right Time

(2012) Bruce M. Prince et al.   ORGANOMETALLICS

[Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst

(2012) Anthony Chartoire et al.   ORGANOMETALLICS

[Pd(IPr*OMe)(acac)Cl]: Tuning the N-Heterocyclic Carbene in Catalytic C–N Bond Formation

(2012) Sebastien Meiries et al.   ORGANOMETALLICS

[Pd(IPr*)(acac)Cl]: An Easily Synthesized, Bulky Precatalyst for C–N Bond Formation

(2012) Sebastien Meiries et al.   ORGANOMETALLICS

Deactivation of Ru-benzylidene Grubbs catalysts active in olefin metathesis

(2012) Albert Poater et al.   THEORETICAL CHEMISTRY ACCOUNTS

Simple synthetic routes to ruthenium–indenylidene olefin metathesis catalysts

(2011) César A. Urbina-Blanco et al.   CHEMICAL COMMUNICATIONS

Rationalizing current strategies to protect N-heterocyclic carbene-based ruthenium catalysts active in olefin metathesis from C–H (de)activation

(2011) Albert Poater et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union

(2011) George C. Fortman et al.   CHEMICAL SOCIETY REVIEWS

Room-Temperature Synthesis of Tetra-ortho-Substituted Biaryls by NHC-Catalyzed Suzuki-Miyaura Couplings

(2011) Linglin Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Olefin Metathesis Featuring Ruthenium Indenylidene Complexes with a Sterically Demanding NHC Ligand

(2011) César A. Urbina-Blanco et al.   CHEMISTRY-A EUROPEAN JOURNAL

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

(2011) Adrián Gómez-Suárez et al.   ORGANOMETALLICS

Well-Defined Allylnickel Chloride/N-Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for CN and CS Cross-Coupling Reactions

(2010) María José Iglesias et al.   ADVANCED SYNTHESIS & CATALYSIS

Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]

(2010) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Serendipitous Discovery of the Catalytic Hydroammoniumation and Methylamination of Alkynes

(2010) Xiaoming Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

A Two-Coordinate Nickel Imido Complex That Effects C−H Amination

(2010) Carl A. Laskowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of N-heterocyclic carbene ligands and derived ruthenium olefin metathesis catalysts

(2010) Xavier Bantreil et al.   Nature Protocols

A Rhodium IBiox[(−)-menthyl] Complex as a Highly Selective Catalyst for the Asymmetric Hydroarylation of Azabicyles: An Alternative Route to Epibatidine

(2010) Jason Bexrud et al.   ORGANIC LETTERS

An escapade in the world of sulfenate anions: generation, reactivity and applications in domino processes

(2010) Guillaume Maitro et al.   TETRAHEDRON-ASYMMETRY

Pd-PEPPSI-IPent: An Active, Sterically Demanding Cross-Coupling Catalyst and Its Application in the Synthesis of Tetra-Ortho-Substituted Biaryls

(2009) Michael G. Organ et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

IPr* an easily accessible highly hindered N-heterocyclic carbene

(2009) Guillaume Berthon-Gelloz et al.   DALTON TRANSACTIONS

A New Class of Stable, Saturated N-Heterocyclic Carbenes withN-Naphthyl Substituents: Synthesis, Dynamic Behavior, and Catalytic Potential

(2009) Ludovic Vieille-Petit et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Gold-Catalyzed Intermolecular Markovnikov Hydroamination of Allenes with Secondary Amines

(2009) Xiaoming Zeng et al.   ORGANIC LETTERS

Aryl Sulfoxides from Allyl Sulfoxides via [2,3]-Sigmatropic Rearrangement and Domino Pd-Catalyzed Generation/Arylation of Sulfenate Anions

(2009) Elise Bernoud et al.   ORGANIC LETTERS

Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions

(2008) Sebastian Würtz et al.   ACCOUNTS OF CHEMICAL RESEARCH

Identification and Characterization of a New Family of Catalytically Highly Active Imidazolin-2-ylidenes

(2008) Xinjun Luan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Heck−Mizoroki Coupling Protocol for Challenging Substrates Mediated by an N-Heterocyclic Carbene-Ligated Palladacycle

(2008) Eric Assen B. Kantchev et al.   ORGANIC LETTERS