4.7 Article

Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 17, Pages 5022-5024

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10741k

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Funding

  1. EC [CP-FP 211468-2-EUMET]

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An efficient synthetic protocol involving reactions between the free carbene and [RuCl2(PPh3)(2)(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl2(L)(Py)(Ind)] (L = SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.

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